Related papers: Anomalously small blackbody radiation shift in Tl+…

We perform calculations of electronic structure of Cm$^{15+}$ and Bk$^{16+}$ ions and demonstrate that they have transitions which combine the features of atomic optical clocks with the enhanced sensitivity to the variations of the fine…

In many of the high-precision optical frequency standards with trapped atoms or ions that are under development to date, the AC Stark shift induced by thermal radiation leads to a major contribution to the systematic uncertainty. We present…

We study the prospects of using transitions from the ytterbium ground state to metastable states $^3{\rm P}^{\rm o}_2$ at $E=19\,710.388~$cm$^{-1}$ and $4f^{13}5d6s^2\,(J=2)$ at $E=23\,188.518~$cm$^{-1}$ as clock transitions in an optical…

Despite extensive research interests in perovskite oxides, low energy consumption, non-destructive and maneuverable methods for phase transition in perovskite oxides are still the under its exploration, and the underlying mechanisms remain…

Quadrupole shifts for three prominent clock transitions, $[4f^{14} 6s] ^2S_{1/2} \rightarrow [4f^{14} 5d] ^2D_{3/2}$, $[4f^{14} 6s] ^2S_{1/2} \rightarrow [4f^{14} 5d] ^2D_{5/2}$ and $[4f^{14} 6s] ^2S_{1/2} \rightarrow [4f^{13} 6s^2]…

A viable qubit must have a long coherence time $T_2$. In molecular nanomagnets $T_2$ is often limited at low temperatures by the presence of dipole and hyperfine interactions, which are often mitigated through sample dilution, chemical…

The uncertainty of the ac Stark shift due to thermal radiation represents a major contribution to the systematic uncertainty budget of state-of-the-art optical atomic clocks. In the case of optical clocks based on trapped ions, the thermal…

We perform Ramsey-Bord\'e spectroscopy on laser-cooled magnesium atoms in free fall to measure the 1S0 \rightarrow 3P1 intercombination transition frequency. The measured value of 655 659 923 839 730 (48) Hz is consistent with our former…

We have performed ab initio calculations of the frequency shift induced by a static electric field on the cesium clock hyperfine transition. The calculations are used to find the frequency shifts due to blackbody radiation. Our result…

Frequency shifts of the ^199Hg^+ 5d^10 6s ^2S_1/2 (F=0, M_F=0) to 5d^9 6s^2 ^2D_5/2 (F=2, M_F=0) electric-quadrupole transition at 282 nm due to external fields are calculated, based on a combination of measured atomic parameters and ab…

We have completed a new measurement of the Stark shift in 115In within the 410 nm 5P1/2- 6S1/2 transition. We measure the Stark shift constant to be kS= - 122.92(33)kHz/(kV/cm)^2, corresponding to a difference in the 6S1/2 and 5P1/2 state…

The present work tests the suitability of the narrow transitions $7s \ ^2S_{1/2} \to 6d ^2D_{3/2}$ and $7s ^2S_{1/2} \to 6d ^2D_{5/2}$ in Ra$^+$ for optical frequency standard studies. Our calculations of the lifetimes of the metastable…

Quantum-state preparation of molecular ions is a prerequisite for precision spectroscopy and controlled studies of cold ion-molecule dynamics. While such control has been extensively developed for diatomic ions and proposed for linear…

Theories unifying gravity and other interactions suggest the possibility of spatial and temporal variation of physical ``constants''. Accuracy achieved for the atomic optical frequency standards (optical clocks) approaches the level when…

The hyperpolarizability of an atom is a property that describes the nonlinear interaction between an atom and an external electric field leading to a higher-order Stark shift. Accurate evaluations of these coefficients for various systems…

Dynamics of the main dielectric anomaly in Na1/2Bi1/2TiO3 (NBT) was studied by time-domain THz and microwave spectroscopy, using also previously published data and their new overall fits. Above the dielectric maximum temperature Tm ~ 600 K,…

Peik and Tamm [Europhys. Lett. 61, 181 (2003)] proposed a nuclear clock based on the isomeric transition between the ground state and the first excited state of thorium-229. This transition was recognized as a potentially sensitive probe of…

As relative systematic frequency uncertainties in trapped-ion spectroscopy are approaching the low $10^{-18}$ range, motional frequency shifts account for a considerable fraction of the uncertainty budget. Micromotion, a driven motion…

We report an observation of the weak $6^{1}$S$_{0}$-$6^3$P$_0$ transition in $^{171,173}$Yb as an important step to establish Yb as a primary candidate for future optical frequency standards, and to open up a new approach for qubits using…

Temperature dependence of the X-ray absorption near-edge structure (XANES) spectra at the Pr $L_{3}$- and Tb $L_{3}$-edges was measured for the (Pr$_{1-y}$Tb$_{y})_{0.7}$Ca$_{0.3}$CoO$_{3}$ system, in which a metal-insulator (MI) and…