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The electronic structure of the $(2\sqrt{2}\times\sqrt{2})R45^{\circ}$ O/Cu(001) system has been calculated using locally self-consistent, real space multiple scattering technique based on first principles. Oxygen atoms are found to perturb…

Materials Science · Physics 2009-11-07 S. Stolbov , T. S. Rahman

The occurence of spin-polarization at ZrO$_{2}$, Al$_{2}$O$_{3}$ and MgO surfaces is proved by means of \textit{ab-initio} calculations within the density functional theory. Large spin moments, as high as 1.56 $\mu_B$, develop at O-ended…

Materials Science · Physics 2009-11-11 S. Gallego , J. I. Beltran , J. Cerda , M. C. Munoz

Magnetite ferrite (Fe3O4) nanoparticles have attracted considerable interest due to their tunable physico-chemical properties and relevance in functional materials. In this work, uncoated Fe3O4 nanoparticles and surface-modified Fe3O4…

Materials Science · Physics 2026-01-13 Arif Iqbal Sheikh , Radha Srinivasan

Although strong modulation of interfacial electron concentrations by the relative acidity of surface additives has been suggested, direct observation of corresponding changes in surface conductivity, crucial for understanding the role of…

Materials Science · Physics 2025-05-21 Gyu Rac Lee , Thomas Defferriere , Jinwook Kim , Han Gil Seo , Yeon Sik Jung , Harry L. Tuller

The application of modern layer-by-layer growth techniques to transition-metal oxide materials raises the possibility of creating new classes of materials with rationally designed correlated electron properties. An important step toward…

Materials Science · Physics 2010-10-07 Myung Joon Han , Chris A. Marianetti , Andrew J. Millis

We have performed non-resonant x-ray diffraction, resonant soft and hard x-ray magnetic diffraction, soft x-ray absorption and x-ray magnetic circular dichroism measurements to clarify the electronic and magnetic states of the Co3+ ions in…

YBaCo4O7 belongs to a new class of geometrically frustrated magnets like the pyrochlores, in which Co-spins occupy corners of tetrahedra. The structure can be viewed as an alternating stacking of Kagome and triangular layers. Exactly half…

Materials Science · Physics 2009-11-11 L. C. Chapon , P. G. Radaelli , H. Zheng , J. F. Mitchell

We present a detailed atomistic picture of the oxidation mechanism of Co nanoparticles and its impact on magnetism by experimentally following the evolution of the structure, chemical composition, and magnetism of individual, gas-phase…

The effect of substituting iron and zinc for cobalt in CaBaCo$_4$O$_7$ has been investigated using neutron diffraction and x-ray absorption spectroscopy. The orthorhombic distortion present in the parent compound CaBaCo$_4$O$_7$ decreases…

Materials Science · Physics 2020-09-01 V. Cuartero , J. Blasco , G. Subías , J. García , J. A. Rodríguez-Velamazán , C. Ritter

We report on structural, magnetic and electronic properties of Co-implanted TiO2 rutile single crystals for different implantation doses. Strong ferromagnetism at room temperature and above is observed in TiO2 rutile plates after cobalt ion…

To harness the true potential of topological insulators as quantum materials for information processing, it is imperative to maximise topological surface state conduction, while simulateneously improving their quantum coherence. However,…

Mesoscale and Nanoscale Physics · Physics 2018-08-21 Abhishek Banerjee , R. Ganesan , P. S. Anil Kumar

It is shown that in rather strong magnetic field the interlayer electron conductivity is exponentially damped by the Coulomb barrier arising from the formation of polaron around each localized electron state. The theoretical model is…

Mesoscale and Nanoscale Physics · Physics 2015-06-03 Pavel D. Grigoriev

We investigate the electronic structure of the c(4 x 2) reconstructed Ge(001) surface using band structure calculations based on density functional theory and the generalized gradient approximation. In particular, we take into account the…

Materials Science · Physics 2009-11-13 Udo Schwingenschloegl , Cosima Schuster

KCoO2 has been found in 1975 to exist in a unique structure with P4/nmm spacegroup with Co in a square pyramidal coordination with the Co atoms in the plane linked by O in a square arrangement reminiscent of the cuprates but its electronic…

Strongly Correlated Electrons · Physics 2024-02-20 Ozan Dernek , Santosh Kumar Radha , Jerome Jackson , Walter R. L. Lambrecht

The van der Waals (vdW) layered multiferroics, which host simultaneous ferroelectric and magnetic orders, have attracted attention not only for their potentials to be utilized in nanoelectric devices and spintronics, but also offer…

Silicon oxide (SiOx) has been widely used in many electronic systems as a supportive and insulating medium. Here we demonstrate various electrical phenomena such as negative differential resistance, resistive switching and current…

Materials Science · Physics 2011-02-17 Jun Yao , Lin Zhong , Douglas Natelson , James M. Tour

SrTiO3 plays a central role in oxide electronics. It is the substrate of choice for functional oxide heterostructures based on perovskite-structure thin-film stacks, and its surface or interface with a polar oxide such as LaAlO3 can become…

Materials Science · Physics 2016-10-12 J. M. D. Coey , M Venkatesan , P Stamenov

Electronic structure and magnetic properties for iron deficient TlFe$_{2-x}$Se$_2$ compounds are studied by first-principles calculations. We find that for the case of $x=0.5$ with a Fe-vacancy ordered orthorhombic superstructure, the…

Superconductivity · Physics 2011-05-23 Chao Cao , Jianhui Dai

We use a combination of density functional theory and Monte Carlo calculations to calculate the surface magnetization in magnetoelectric $\mathrm{Cr_2O_3}$ at finite temperatures. Such antiferromagnets, lacking both inversion and…

Materials Science · Physics 2023-04-19 Sophie F. Weber , Nicola A. Spaldin

We analyze the electrostatic stability of insulating surfaces in the framework of the bulk modern theory of polarization. We show that heuristic arguments based on a fully ionic limit find formal justification at the microscopic level, even…

Materials Science · Physics 2015-05-30 Massimiliano Stengel