Related papers: A quantum solution to Gibbs Paradox with few parti…
As no heat effect and mechanical work are observed, we have a simple experimental resolution of the Gibbs paradox: both the thermodynamic entropy of mixing and the Gibbs free energy change are zero during the formation of any ideal…
The paper wishes to demonstrate that, in quantum systems with boundaries, different boundary conditions can lead to remarkably different physical behaviour. Our seemingly innocent setting is a one dimensional potential well that is divided…
A Gedanken experiment is described to explore a counter-intuitive property of quantum mechanics. A particle is placed in a one-dimensional infinite well. The barrier on one side of the well is suddenly removed and the chamber dramatically…
It is shown that the Gibbs paradox is actually paralogism, viz. an erroneous statement sounding credible due to the statistic-mechanical interpretation of entropy as a measure of "any and all" irreversibility. As an alternative, the…
In statistical mechanics Gibbs' paradox is avoided if the particles of a gas are assumed to be indistinguishable. The resulting entropy then agrees with the empirically tested thermodynamic entropy up to a term proportional to the logarithm…
The analysis of the arguments within the limits of the classical thermodynamics that lead to the Gibbs paradox was made. Features of preconditions used in the derivation of the entropy of mixing of ideal gases that caused the appearance of…
The formulas for the entropy of ideal gases mixture and the entropy change in mixing of ideal gases on the basis of the third law of thermodynamics were obtained. It is shown that when using these formulas, the Gibbs paradox within the…
In this work the non-additive entropy is examined. It appears in isolated particle systems composed of few components. Therefore, the mixing of isolated particle systems S=S1+S2 has been studied. Two cases are considered T1=T2 and T1\leqT2,…
The suggestion that particles of the same kind may be indistinguishable in a fundamental sense, even so that challenges to traditional notions of individuality and identity may arise, has first come up in the context of classical…
In this work, we examine the entanglement dynamics of two massive particles confined within their respective infinite square potential wells induced by gravity. Assuming that each particle is initially in the ground state of its infinite…
We investigate a non-interacting many-particle bosonic system, placed in an asymmetric double-well potential. We first consider the dynamics of a single particle and determine its time-dependent probabilities to be in the left or the right…
The Gibbs Mixing Paradox is a conceptual touchstone for understanding mixtures in statistical mechanics. While debates over the theoretical subtleties of particle distinguishability continue to this day, we seek to extend the discussion in…
We study the propagation of entanglement after quantum quenches in the non-integrable para-magnetic quantum Ising spin chain. Tuning the parameters of the system, we observe a sudden increase in the entanglement production rate, which we…
We consider the Statistical Mechanics of systems of particles satisfying the $q$-commutation relations recently proposed by Greenberg and others. We show that although the commutation relations approach Bose (resp.\ Fermi) relations for…
We consider a quantum quench in a non-interacting fermionic one-dimensional field-theory. The system of size $L$ is initially prepared into two halves $\mathcal{L}$ ($[-L/2,0]$) and $\mathcal{R}$ ($[0,L/2]$), each of them thermalized at two…
We construct the Gibbs state for $\nu$-dimensional quantum crystal with site displacements from $\R^d$, $d\geq 1$, and with a one-site \textit{non-polynomial} double-well potential, which has \textit{harmonic} asymptotic growth at infinity.…
Defining the entropy of classical particles raises a number of paradoxes and ambiguities, some of which have been known for over a century. Several, such as Gibbs' paradox, involve the fact that classical particles are distinguishable, and…
The standard theory of ideal gases ignores the interaction of the gas particles with the thermal radiation (photon gas) that fills the otherwise vacuum space between them. This is an unphysical feature of the theory since every material in…
Here we investigate how local properties of particles in a thermal bath influence the thermodynamics of the bath. We utilize nanothermodynamics, based on two postulates: that small systems can be treated self-consistently by coupling to an…
A two-body quantum correlation is calculated for a particle and an infinite potential well in which it is trapped or either a barrier or finite well over which it traverses. Correlated interference results when the incident and reflected…