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We study the properties of convex functionals which have been proposed for the simulation of charged molecular systems within the Poisson-Boltzmann approximation. We consider the extent to which the functionals reproduce the true…

Statistical Mechanics · Physics 2015-01-12 Justine S. Pujos , A. C. Maggs

We study the phase diagram of a system of spherical particles interacting in three dimensions through a potential consisting of a strict hard core plus a linear repulsive shoulder at larger distances. The phase diagram (obtained…

Statistical Mechanics · Physics 2009-10-31 E. A. Jagla

We derive, from the dimensional cross-over criterion, a fundamental-measure density functional for parallel hard curved rectangles moving on a cylindrical surface. We derive it from the density functional of circular arcs of length $\sigma$…

Soft Condensed Matter · Physics 2015-06-16 Yuri Martinez-Raton , Enrique Velasco

This article considers fluid structure interaction describing the motion of a fluid contained in a porous medium. The fluid is modelled by Navier-Stokes equations and the coupling between fluid and the porous medium is described by the…

Analysis of PDEs · Mathematics 2025-01-17 Tim Binz , Matthias Hieber , Arnab Roy

We derive an exact equation for density changes induced by a general external field that corrects the hydrostatic approximation where the local value of the field is adsorbed into a modified chemical potential. Using linear response theory…

Statistical Mechanics · Physics 2009-10-31 Kirill Katsov , John D. Weeks

We study a fluid of two-dimensional parallel hard squares in bulk and under confinement in channels, with the aim of evaluating the performance of Fundamental-Measure Theory (FMT). To this purpose, we first analyse the phase behaviour of…

Soft Condensed Matter · Physics 2016-08-05 Miguel Gonzalez-Pinto , Yuri Martinez-Raton , Szabolcs Varga , Peter Gurin , Enrique Velasco

Ubiquitous van der Waals (vdW) interactions play a subtle yet crucial role in determining the precise atomic arrangements in solids, particularly in molecular crystals where these weak forces are the primary link between constituent…

We argue that recently proposed [Melnyk et al., Fluid Phase Equilibr., 2009, Vol. 279, 1] a criterion to split the pair interaction energy into two parts, one of which is forced to be responsible the most accurate as possible for excluded…

Soft Condensed Matter · Physics 2015-04-06 A. Trokhymchuk , R. Melnyk , I. Nezbeda

Fluid flow past one or more solid bodies is a fundamental problem of much practical importance. Standard solutions of simplified problems involving incompressible inviscid irrotational flow past common geometries such as circular cylinders…

Fluid Dynamics · Physics 2026-01-01 Ankur Jain

We propose an improved effective-medium theory to obtain the concentration dependence of the viscosity of particle suspensions at arbitrary volume fractions. Our methodology can be applied, in principle, to any particle shape as long as the…

Soft Condensed Matter · Physics 2010-06-01 I. Santamaria-Holek , Carlos I. Mendoza

In a series of publications the Cummings-Stell model (CSM), for a binary mixture of associative fluids with steric effects, has been solved analytically using the Percus-Yevick approximation (PYA). The solution consists in a square well…

Statistical Mechanics · Physics 2009-03-24 J. F. Rojas

It has been known for a long time that many simple liquids have surprisingly similar structure as quantified, e.g., by the radial distribution function. A much more recent realization is that the dynamics are also very similar for a number…

Statistical Mechanics · Physics 2017-01-04 Andreas K. Bacher , Thomas B. Schrøder , Jeppe C. Dyre

The direct correlation function of a fluid mixture of parallel hard cubes is obtained by using Rosenfeld's fundamental measure approximation. This approximation is thermodynamically consistent (compressibility and virial equations of state…

Condensed Matter · Physics 2009-10-28 Jose A. Cuesta

We introduce fractal liquids by generalizing classical liquids of integer dimensions $d = 1, 2, 3$ to a fractal dimension $d_f$. The particles composing the liquid are fractal objects and their configuration space is also fractal, with the…

Statistical Mechanics · Physics 2015-08-31 Marco Heinen , Simon K. Schnyder , John F. Brady , Hartmut Löwen

The integral equations for the correlation functions of an inhomogeneous fluid mixture are derived using a functional Taylor expansion of the free energy around an inhomogeneous equilibrium distribution. The system of equations is closed by…

Soft Condensed Matter · Physics 2007-05-23 M. Oettel

Quasi-two-dimensional fluids can be generated by confining a fluid between two parallel walls with narrow separation. Such fluids exhibit an inhomogeneous structure perpendicular to the walls due to the loss of translational symmetry.…

Soft Condensed Matter · Physics 2014-03-13 Simon Lang , Thomas Franosch , Rolf Schilling

A particle-based model for mesoscopic fluid dynamics is used to simulate steady and unsteady flows around a circular and a square cylinder in a two-dimensional channel for a range of Reynolds number between 10 and 130. Numerical results for…

Soft Condensed Matter · Physics 2009-11-07 A. Lamura , G. Gompper , T. Ihle , D. M. Kroll

A brief review is presented of the scaling of complex fluids, polymers and polyelectrolytes in solution and in confined geometry, in thermodynamical, structural and rheology properties using equilibrium and nonequilibrium dissipative…

Soft Condensed Matter · Physics 2016-12-06 Armando Gama Goicochea

We use molecular dynamics simulation results on viscous binary Lennard-Jones mixtures to examine the correlation between the potential energy and the virial. In accord with a recent proposal [U. R. Pedersen et. al. Phys. Rev. Lett. 100,…

Statistical Mechanics · Physics 2009-01-08 D. Coslovich , C. M. Roland

Discrete mechanics makes it possible to formulate any problem of fluid mechanics or fluid-structure interaction in velocity and potentials of acceleration; the equation system consists of a single vector equation and potentials updates. The…

Fluid Dynamics · Physics 2020-04-02 Jean-Paul Caltagirone , Stephane Vincent
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