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Motivated by the disagreement between recent diffusion Monte Carlo calculations and experiments on the phase transition pressure between the ambient and beta-Sn phases of silicon, we present a study of the HCP to BCC phase transition in…

Chemical Physics · Physics 2015-01-19 Luke Shulenburger , Thomas R. Mattsson , M. P. Desjarlais

This is a follow-up of our recently proposed work on pseudopotential calculation (Ref. [21]) of atoms and molecules within DFT framework, using cartesian coordinate grid. Detailed results are presented to demonstrate the usefulness,…

Chemical Physics · Physics 2015-05-18 Amlan K. Roy

By using the diffusion Monte Carlo method, we obtained the full phase diagram of $^3$He on top of graphite preplated with a solid layer of $^4$He. All the $^4$He atoms of the substrate were explicitly considered and allowed to move during…

Other Condensed Matter · Physics 2016-11-23 M. C. Gordillo , J. Boronat

The package fhi98PP allows one to generate norm-conserving pseudopotentials adapted to density-functional theory total-energy calculations for a multitude of elements throughout the periodic table, including first-row and transition metal…

Materials Science · Physics 2009-10-31 Martin Fuchs , Matthias Scheffler

An accurate understanding of the phase diagram of dense hydrogen and helium mixtures is a crucial component in the construction of accurate models of Jupiter, Saturn, and Jovian extrasolar planets. Though DFT based first principles methods…

Materials Science · Physics 2016-01-27 Raymond C. Clay , Markus Holzmann , David M. Ceperley , Miguel A. Morales

In the near future, material and drug design may be aided by quantum computer assisted simulations. These have the potential to target chemical systems intractable by the most powerful classical computers. However, the resources offered by…

The behavior of metals at high pressure is of great importance to the fields of shock physics, geophysics, astrophysics, and nuclear materials. In order to further understand the properties of metals at high pressures we studied the…

Materials Science · Physics 2009-11-13 Michael J. Tambe , Nicola Bonini , Nicola Marzari

High-throughput DFT calculations are key to screening existing/novel materials, sampling potential energy surfaces, and generating quantum mechanical data for machine learning. By including a fraction of exact exchange (EXX), hybrid…

Crystalline structures, zone-center phonon modes, and the related dielectric response of the three low-pressure phases of HfO2 have been investigated in density-functional theory using ultrasoft pseudopotentials and a plane-wave basis. The…

Materials Science · Physics 2009-11-07 Xinyuan Zhao , David Vanderbilt

Understanding planetary interiors is directly linked to our ability of simulating exotic quantum mechanical systems such as hydrogen (H) and hydrogen-helium (H-He) mixtures at high pressures and temperatures. Equations of State (EOSs)…

Strongly Correlated Electrons · Physics 2018-01-17 Guglielmo Mazzola , Ravit Helled , Sandro Sorella

In this paper, we propose an efficient implementation of combining Dynamical Mean field theory (DMFT) with electronic structure calculation based on the local density approximation (LDA). The pseudo-potential-plane-wave method is used in…

Strongly Correlated Electrons · Physics 2015-06-03 Jian-Zhou Zhao , Jia-Ning Zhuang , Xiao-Yu Deng , Yan Bi , Ling-Cang Cai , Zhong Fang , Xi Dai

We have carried out a comparative study of the electronic specific heat and electronic structure of $\alpha$ and $\delta$-plutonium using dynmical mean field theory (DMFT). We use the perturbative T-matrix and fluctuating exchange (T-matrix…

Strongly Correlated Electrons · Physics 2009-11-13 L. V. Pourovskii , G. Kotliar , M. I. Katsnelson , A. I. Lichtenstein

We have used a Hartree-type electron-helium potential together with a density functional description of liquid $^4$He and $^3$He to study the explosion of electron bubbles submitted to a negative pressure. The critical pressure at which…

Other Condensed Matter · Physics 2009-11-11 M. Pi , M. Barranco , R. Mayol , V. Grau

Exploratory variational pseudopotential density functional calculations are performed for the electronic properties of many-electron systems in the 3D cartesian coordinate grid (CCG). The atom-centered localized gaussian basis set,…

Chemical Physics · Physics 2015-05-18 Amlan K Roy

The increasing use of high-throughput density-functional theory (DFT) calculations in the computational design and optimization of materials requires the availability of a comprehensive set of soft and transferable pseudopotentials. Here we…

Materials Science · Physics 2013-12-10 Kevin F. Garrity , Joseph W. Bennett , Karin M. Rabe , David Vanderbilt

Plutonium dioxide is of high technological importance in nuclear fuel cycle and is particularly crucial in long-term storage of Pu-based radioactive waste. Using first-principles density-functional theory, in this paper we systematically…

Materials Science · Physics 2011-09-29 Ping Zhang , Bao-Tian Wang , Xian-Geng Zhao

The observation of superconductivity in hydride-based materials under ultrahigh pressures (for example, H$_3$S and LaH$_{10}$) has fueled the interest in a more data-driven approach to discovering new high-pressure hydride superconductors.…

Materials Science · Physics 2024-06-04 Daniel Wines , Kamal Choudhary

Simple cubic (SC) phase has been long experimentally determined as the high-pressure phase III of elemental calcium (Ca) since 1984. However, recent density functional calculations within semi-local approximation showed that this SC phase…

Materials Science · Physics 2015-06-11 Hanyu Liu , Wenwen Cui , Yanming Ma

We investigate the electronic structure of americium (Am) across its four experimentally confirmed high-pressure phases Am-I (P63/mmc), Am-II (Fm-3m), Am-III (Fddd), and Am-IV (Pnma) up to 100 GPa, using density functional theory combined…

Strongly Correlated Electrons · Physics 2026-04-15 Haiyan Lu

We use the Gutzwiller Density Functional Theory to calculate ground-state properties and bandstructures of iron in its body-centered-cubic (bcc) and hexagonal-close-packed (hcp) phases. For a Hubbard interaction $U=9\, {\rm eV}$ and…

Strongly Correlated Electrons · Physics 2016-06-02 Tobias Schickling , Jörg Bünemann , Florian Gebhard , Lilia Boeri