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We present a real-space formulation and higher-order finite-difference implementation of periodic Orbital-free Density Functional Theory (OF-DFT). Specifically, utilizing a local reformulation of the electrostatic and kernel terms, we…

Computational Physics · Physics 2015-12-23 Swarnava Ghosh , Phanish Suryanarayana

Due to their diverse nature, the faithful description of excited states within electronic structure theory methods remains one of the grand challenges of modern theoretical chemistry. Quantum Monte Carlo (QMC) methods have been applied very…

Chemical Physics · Physics 2020-06-05 Anthony Scemama , Michel Caffarel , Anouar Benali , Denis Jacquemin , Pierre-François Loos

Realizing the potential for predictive density functional calculations of matter under extreme conditions depends crucially upon having an exchange-correlation (XC) free energy functional accurate over a wide range of state conditions.…

Materials Science · Physics 2018-02-21 Valentin V. Karasiev , James W. Dufty , S. B. Trickey

Generalized theory of the normal properties of the metal in the case of the electron-phonon (EP) systems with not constant density of electronic states is used to examine the normal state of the SH3 and SH2 phase of the hydrogen sulfide at…

Superconductivity · Physics 2017-04-05 Nikolay A. Kudryashov , Alexander A. Kutukov , Evgeny A. Mazur

We investigate an energy flow in an extended Holstein model describing electron systems coupled to hot-phonons and heat-bath phonons. To analyze the relaxation process after the photo-excitation of electrons, we employ the nonequilibrium…

Strongly Correlated Electrons · Physics 2023-11-07 Ken Inayoshi , Akihisa Koga , Yuta Murakami

Energy functionals serve as the basis for different models and methods in quantum and classical many-particle physics. Arguably, one of the most successful and widely used approaches in material science at both ambient and extreme…

Plasma Physics · Physics 2024-10-22 Z. Moldabekov , J. Vorberger , T. Dornheim

The energy differences between the face-centered cubic (FCC) and hexagonal closed packed (HCP) structures of the argon (Ar) crystal are studied using the first-principles electronic-structure approach at the level of random phase…

Materials Science · Physics 2022-04-13 Sixian Yang , Xinguo Ren

A metastable state, characterized by a low degree of mass localization is identified using Density Functional Theory. This free energy minimum, located through the proper evaluation of the competing terms in the free energy functional, is…

Statistical Mechanics · Physics 2009-10-31 Charanbir Kaur , Shankar P. Das

We present a comprehensive first-principles investigation of the structural, electronic, optical, and thermodynamic properties of BeX compounds (X = S, Se, Te) under hydrostatic pressures ranging from 0 to 10 GPa. Calculations were…

Materials Science · Physics 2025-10-02 Muhammad Shahzad , Sikander Azam , Syed Awais Ahmad , Ming Li

We study the one-band Hubbard model on the honeycomb lattice using a combination of quantum Monte Carlo (QMC) simulations and static as well as dynamical mean-field theory (DMFT). This model is known to show a quantum phase transition…

Strongly Correlated Electrons · Physics 2020-03-09 Marcin Raczkowski , Robert Peters , Th\d{i} Thu Phùng , Nayuta Takemori , Fakher F. Assaad , Andreas Honecker , Javad Vahedi

We show that the magnetic properties of high-entropy alloys (HEAs) can be captured by \textit{ab initio} calculations within the coherent potential approximation, where the atomic details of the high-entropy mixing are considered as an…

Materials Science · Physics 2025-12-30 Dinesh Bista , Willie B. Beeson , Turbasu Sengupta , Jerome Jackson , Shiv N Khanna , Kai Liu , Gen Yin

In order to investigate the phase stability of equiatomic FeN compounds and the structure-dependent magnetic properties, the electronic structure and total energy of FeN with NaCl, ZnS and CsCl structures and various magnetic configurations…

Materials Science · Physics 2009-10-31 Yong Kong

Uranium is considered as a very important nuclear energy material because of the huge amount of energy released. As the main products of spontaneous decay of uranium, helium is difficult to react with uranium for its chemical inertness.…

Materials Science · Physics 2024-07-23 Ye Cao , Hongxing Song , Xiaozhen Yan , Hao Wang , Yufeng Wang , Fengchao Wu , Leilei Zhang , Qiang Wu , Hua Y. Geng

Solid-solid phase transitions in metals are traditionally driven by changes in density or external pressure. Here we show that, under strong electronic excitation, structural stability is governed by the interplay between electronic effects…

Materials Science · Physics 2026-04-27 S. Azadi , S. M. Vinko , A. Principi , T. D. Kuehne , M. S. Bahramy

Realistic prediction of the superconducting transition temperature (Tc) for PdH is a long-standing challenge, because it depends on robust calculations of the electron and phonon band structures to obtain the electron-phonon scattering…

Materials Science · Physics 2022-08-08 Samaneh Sadat Setayandeh , Tim Gould , Toktam Morshedloo , Evan Gray

We report new accurate mesasurements of the mobility of excess electrons in high density Helium gas in extended ranges of temperature $[(26\leq T\leq 77) K ]$ and density $[ (0.05\leq N\leq 12.0) {atoms} \cdot {nm}^{-3}]$ to ascertain the…

Plasma Physics · Physics 2016-09-08 A. F. Borghesani , M. Santini

Using first-principles variable-composition evolutionary methodology, we explored the high-pressure structures of beryllium hydrides between 0 and 400 GPa. We found that BeH$_2$ remains the only stable compound in this pressure range. The…

Materials Science · Physics 2014-07-15 Shuyin Yu , Qingfeng Zeng , Artem R. Oganov , Chaohao Hu , Gilles Frapper , Litong Zhang

Kohn-Sham (KS) density functional theory (DFT) is a very efficient method for calculating various properties of solids as, for instance, the total energy, the electron density, or the electronic band structure. The KS-DFT method leads to…

Materials Science · Physics 2019-09-20 Fabien Tran , Jan Doumont , Leila Kalantari , Ahmad W. Huran , Miguel A. L. Marques , Peter Blaha

The effect of pressure on the hexagonal close-packed structure of titanium is investigated. The lattice parameters of the equilibrium structure were determined in terms of the Gibbs free energy using the Epitaxial Bain Path method. When…

Materials Science · Physics 2011-07-21 M. Jafari , A. Jahandoost , Me. Vaezzadeh , N. Zarifi

The consistency between the exchange-correlation functional used in pseudopotential construction and in the actual density functional theory calculation is essential for the accurate prediction of fundamental properties of materials.…

Chemical Physics · Physics 2018-02-21 Jing Yang , Liang Z. Tan , Andrew M. Rappe
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