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We briefly introduce the quantum Jarzynski and Bochkov-Kuzovlev equalities in isolated quantum Hamiltonian systems, which includes the origin of the equalities, their derivations using a quantum Feynman-Kac formula, the quantum Crooks…

Statistical Mechanics · Physics 2015-06-19 Fei Liu , Zhong-can Ou-Yang

We present a unified and simple method for deriving work theorems for classical and quantum Hamiltonian systems, both under equilibrium conditions and in a steady state. Throughout the paper, we adopt the partitioning of the total…

Statistical Mechanics · Physics 2008-07-30 M. F. Gelin , D. S. Kosov

The quantum version of the Bochkov-Kuzovlev identity is derived on the basis of the appropriate definition of work as the difference of the measured internal energies of a quantum system at the beginning and at the end of an external action…

Statistical Mechanics · Physics 2010-12-14 Michele Campisi , Peter Talkner , Peter Hänggi

The classical Jarzynski equality establishes an exact relation between the stochastic work performed on a system driven out of thermal equilibrium and the free energy difference in a corresponding quasi-static process. This fluctuation…

Quantum Physics · Physics 2025-08-21 Konstantin Beyer , Walter T. Strunz

We obtain the Crooks and the Jarzynski non-equilibrium fluctuation relations using a direct quantum-mechanical approach for a finite system that is either isolated or coupled not too strongly to a heat bath. These results were hitherto…

Statistical Mechanics · Physics 2012-07-11 Doron Cohen , Yoseph Imry

The fluctuation theorems, and in particular, the Jarzynski equality, are the most important pillars of modern non-equilibrium statistical mechanics. We extend the quantum Jarzynski equality together with the Two-Time Measurement Formalism…

Statistical Mechanics · Physics 2018-03-01 Anthony Bartolotta , Sebastian Deffner

Using the Feynman-Kac formula, a work fluctuation theorem for a Brownian particle in a nonconfining potential, e.g., a potential well with finite depth, is derived. The theorem yields aninequality that puts a lower bound on the average work…

Statistical Mechanics · Physics 2021-02-12 Christoph Streißnig , Holger Kantz

Jarzynski equality and related fluctuation theorems can be formulated for various setups. Such an equality was recently derived for nonunitary quantum evolutions described by unital quantum operations, i.e., for completely positive,…

Quantum Physics · Physics 2014-01-24 Alexey E. Rastegin , Karol Życzkowski

Five previously unknown inequalities relating equilibrium free energy differences and non-equilibrium work fluctuations are derived, and lucid path to derivation of many similar inequalities is presented. These results are based upon…

Statistical Mechanics · Physics 2011-05-24 Alexander Davydov

We theoretically explore the Bochkov-Kuzovlev-Jarzynski-Crooks work theorems in a finite system subject to external control, which is coupled to a heat reservoir. We first elaborate the mechanical energy-balance between the system and the…

Statistical Mechanics · Physics 2015-09-02 Chang Sub Kim

Although nonequilibrium work and fluctuation relations have been studied in detail within classical statistical physics, extending these results to open quantum systems has proven to be conceptually difficult. For systems that undergo…

Non-equilibrium quantum thermodynamics is essential to describe new devices that operate far from the regime where the usual thermodynamical laws are obeyed. When quantum fluctuations dominate, defining and measuring work and heat, two…

The Jarzynski equality, which relates equilibrium free-energy difference to an average of non-equilibrium work, plays a central role in modern non-equilibrium statistical thermodynamics. In this paper, we study a weaker consequence of this…

Statistical Mechanics · Physics 2026-01-06 Dani R. Castellanos , Petr Jizba

Research on the out-of-equilibrium dynamics of quantum systems has so far produced important statements on the thermodynamics of small systems undergoing quantum mechanical evolutions. Key examples are provided by the Crooks and Jarzynski…

Work is a process-based quantity, and its measurement typically requires interaction with a measuring device multiple times. While classical systems allow for non-invasive and accurate measurements, quantum systems present unique challenges…

Quantum Physics · Physics 2025-06-17 Giulia Rubino , Karen V. Hovhannisyan , Paul Skrzypczyk

In recent years a quantum information theoretic framework has emerged for incorporating non-classical phenomena into fluctuation relations. Here we elucidate this framework by exploring deviations from classical fluctuation relations…

Quantum Physics · Physics 2021-12-09 Zoe Holmes , Erick Hinds Mingo , Calvin Y. -R. Chen , Florian Mintert

We investigate quantum corrections to the classical work characteristic function (CF) as a semiclassical approximation to the full quantum work CF. In addition to explicitly establishing the quantum-classical correspondence of the…

Statistical Mechanics · Physics 2018-08-03 Zhaoyu Fei , H. T. Quan , Fei Liu

Many studies of quantum-size heat engines assume that the dynamics of an internal system is unitary and that the extracted work is equal to the energy loss of the internal system. Both assumptions, however, should be under scrutiny. In the…

Statistical Mechanics · Physics 2017-04-05 Yohei Morikuni , Hiroyasu Tajima , Naomichi Hatano

We present a generalization of Jarzynski's Equality, applicable to quantum systems, relating discretized mechanical work and free-energy changes. The theory is based on a step-wise pulling protocol. We find that work distribution functions…

Quantum Physics · Physics 2012-09-21 Van A. Ngo , Stephan Haas

We derive Feynman-Kac formulas for Dirichlet realizations of Pauli-Fierz operators generating the dynamics of nonrelativistic quantum mechanical matter particles, which are minimally coupled to both classical and quantized radiation fields…

Mathematical Physics · Physics 2021-11-30 Oliver Matte
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