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The quantum Jarzynski equality is an important theorem of modern quantum thermodynamics. We show that the Jarzynski equality readily generalizes to relativistic quantum mechanics described by the Dirac equation. After establishing the…

Statistical Mechanics · Physics 2015-09-30 Sebastian Deffner , Avadh Saxena

A quantum analogue of the Jarzynski equality is constructed. This equality connects an ensemble average of exponentiated work with the Helmholtz free-energy difference in a nonequilibrium switching process subject to a thermal heat bath. To…

Statistical Mechanics · Physics 2009-10-31 Satoshi Yukawa

Quantum annealing is a generic solver of classical optimization problems that makes full use of quantum fluctuations. We consider work statistics given by a repetition of quantum annealing processes by employing the Jarzynski equality…

Disordered Systems and Neural Networks · Physics 2015-05-27 Masayuki Ohzeki , Hidestoshi Nishimori

Recent theoretical predictions and experimental measurements have demonstrated that equilibrium free energy differences can be obtained from exponential averages of nonequilibrium work values. These results are similar in structure, but not…

Statistical Mechanics · Physics 2009-11-11 Christopher Jarzynski

The quantum dynamics of fermionic or bosonic many-body systems following external excitation can be successfully studied using two-time nonequilibrium Green's functions (NEGF) or single-time reduced density matrix methods. Approximations…

Strongly Correlated Electrons · Physics 2022-07-12 Erik Schroedter , Jan-Philip Joost , Michael Bonitz

Fluctuations of the work performed on a driven quantum system can be characterized by the so-called fluctuation theorems. The Jarzynski relation and the Crooks theorem are famous examples of exact equalities characterizing non-equilibrium…

Quantum Physics · Physics 2018-04-12 Alexey E. Rastegin

Firstly the fluctuation theorems (FT) for expended work in a driven nonequilibrium system, isolated or thermostatted, together with the ensuing Jarzynski work-energy (W-E) relationships, will be discussed and reobtained. Secondly, the…

Statistical Mechanics · Physics 2016-10-31 Carolyne M. Van Vliet

We present two kinds of Bochkov-Kuzovlev work equalities in a two-level system that is described by a quantum Markovian master equation. One is based on multiple time correlation functions and the other is based on the quantum trajectory…

Statistical Mechanics · Physics 2015-06-18 Fei Liu

This is a brief review of recently derived relations describing the behaviour of systems far from equilibrium. They include the Fluctuation Theorem, Jarzynski's and Crooks' equalities, and an extended form of the Second Principle for…

Statistical Mechanics · Physics 2009-11-11 Jorge Kurchan

In a reasonably self-contained and explicit presentation we illustrate the efficiency of the Feynman-Kac formula for the rigorous derivation of three inequalities of interest in non-relativistic quantum mechanics.

Quantum Physics · Physics 2017-08-23 Hajo Leschke , Rainer Ruder

The theory of phenomenological Non-equilibrium Thermodynamics is extended by includimg stochastic processes in order to account for recently derived thermodynamical relations such as the Jarzynski equality. Four phenomenological axioms are…

Chaotic Dynamics · Physics 2016-07-20 Wolfgang Muschik

Quantum thermodynamics allows for the interconversion of quantum coherence and mechanical work. Quantum coherence is thus a potential physical resource for quantum machines. However, formulating a general nonequilibrium thermodynamics of…

Quantum Physics · Physics 2025-11-05 Franklin L. S. Rodrigues , Eric Lutz

It has been established that the inclusive work for classical, Hamiltonian dynamics is equivalent to the two-time energy measurement paradigm in isolated quantum systems. However, a plethora of other notions of quantum work has emerged, and…

Statistical Mechanics · Physics 2021-04-08 Akira Sone , Sebastian Deffner

A universal quantum work relation is proved for isolated time-dependent Hamiltonian systems in a magnetic field as the consequence of microreversibility. This relation involves a functional of an arbitrary observable. The quantum Jarzynski…

Statistical Mechanics · Physics 2009-11-13 David Andrieux , Pierre Gaspard

We study nonequilibrium work relations for a space-dependent field with stochastic dynamics (Model A). Jarzynski's equality is obtained through symmetries of the dynamical action in the path integral representation. We derive a set of exact…

Statistical Mechanics · Physics 2011-02-18 Kirone Mallick , Moshe Moshe , Henri Orland

Fluctuation relations allow for the computation of equilibrium properties, like free energy, from an ensemble of non-equilibrium dynamics simulations. Computing them for quantum systems, however, can be difficult, as performing dynamic…

Quantum Physics · Physics 2021-09-07 Lindsay Bassman , Katherine Klymko , Diyi Liu , Norman M. Tubman , Wibe A. de Jong

The characteristic function for the joint measurement of the changes of two commuting observables upon an external forcing of a quantum system is derived. In particular, the statistics of the internal energy, the exchanged heat and the work…

Statistical Mechanics · Physics 2009-02-18 Peter Talkner , Michele Campisi , Peter Hänggi

A result of great theoretical and experimental interest, Jarzynski equality predicts a free energy change $\Delta F$ of a system at inverse temperature $\beta$ from an ensemble average of non-equilibrium exponential work, i.e., $\langle…

Statistical Mechanics · Physics 2017-10-18 Juan D. Jaramillo , Jiawen Deng , Jiangbin Gong

We develop fully noncommutative Feynman-Kac formulae by employing quantum stochastic processes. To this end we establish some theory for perturbing quantum stochastic flows on von Neumann algebras by multiplier cocycles. Multiplier cocycles…

Functional Analysis · Mathematics 2018-01-18 Alexander C. R. Belton , J. Martin Lindsay , Adam G. Skalski

The standard definition of quantum fluctuating work is based on the two-projective energy measurement, which however does not apply to systems with initial quantum coherence because the first projective energy measurement destroys the…

Quantum Physics · Physics 2019-04-12 Rui Pan , Zhaoyu Fei , Tian Qiu , Jing-Ning Zhang , H. T. Quan