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Single crystals of BaFe$_2$As$_2$ and (Ba$_{0.55}$K$_{0.45}$)Fe$_2$As$_2$ have been grown out of excess Sn with 1% or less incorporation of solvent. The crystals are exceptionally micaceous, are easily exfoliated and can have dimensions as…

Single crystals of undoped CaFe2As2 were grown by a FeAs self-flux method, and the crystals were quenched in ice-water rapidly after high temperature growth. The quenched crystal undergoes a collapsed tetragonal structural phase transition…

Superconductivity · Physics 2017-08-22 Dong-Yun Chen , Jia Yu , Bin-Bin Ruan , Qi Guo , Lei Zhang , Qing-Ge Mu , Xiao-Chuan Wang , Bo-Jin Pan , Gen-Fu Chen , Zhi-An Ren

We report the growth of mm-sized Pmnb-Li2FeSiO4 single crystals by means of the optical floating-zone method at high argon pressure and describe the conditions required for a stable growth process. The crystal structure is determined and…

We successfully grew the high-quality single crystal of Rb$_{0.78}$Fe$_2$Se$_{1.78}$, which shows sharp superconducting transition in magnetic susceptibility and electrical resistivity. Resistivity measurements show the onset…

Superconductivity · Physics 2011-03-02 A. F. Wang , J. J. Ying , Y. J. Yan , R. H. Liu , X. G. Luo , Z. Y. Li , X. F. Wang , M. Zhang , G. J. Ye , P. Cheng , Z. J. Xiang , X. H. Chen

Single crystals of Ba_{1-x}Rb_{x}Fe_2As_2 with x=0.05-0.1 have been grown from Sn flux and are bulk superconductors with T_c up to 23 K. The crystal structure was determined by X-ray diffraction analysis, and Sn is found to be incorporated…

Superconductivity · Physics 2009-04-07 Z. Bukowski , S. Weyeneth , R. Puzniak , P. Moll , S. Katrych , N. D. Zhigadlo , J. Karpinski , H. Keller , B. Batlogg

Single crystals of K$_x$Fe$_{2-y}$Se$_2$ are prepared by quenching at various temperatures. The crystals obtained at higher quenching temperatures have a surface morphology with mesh-like texture. They show a sharp superconducting…

F-substituted LaOBiSe2 single crystals were grown using CsCl flux. The obtained single crystals showed a plate-like shape with a size of about 1.0 mm square. The c-axis lattice constant of the grown crystals was determined to be 14.114(3)…

Superconductivity · Physics 2014-10-29 Masanori Nagao , Masashi Tanaka , Satoshi Watauchi , Isao Tanaka , Yoshihiko Takano

Single crystals of FeSe_1-x_Te_x_ (0.5=<x=<1) have been grown by the Bridgman method. After annealing them at 400 deg for 100 h in vacuum, single crystals of x=0.5-0.9 have exhibited bulk superconductivity. Anisotropic properties of the…

Superconductivity · Physics 2010-08-23 Takashi Noji , Takumi Suzuki , Haruki Abe , Tadashi Adachi , Masatsune Kato , Yoji Koike

A flux-free solution to the growth of large and composition homogeneous superconducting FeSe crystal is reported for the first time, which is based on the traveling-solvent floating-zone technique. The size of the crystal samples prepared…

Superconductivity · Physics 2015-06-23 Mingwei Ma , Dongna Yuan , Yue Wu , Huaxue Zhou , Xiaoli Dong , Fang Zhou

CuFeO$_2$ single crystals up to 50 mm in length and up to 10 mm in diameter were grown by the optical floating-zone method. Stoichiometric polycrystalline rods with a diameter of 6-12 mm were used as feed materials to produce crystals of…

Materials Science · Physics 2020-01-07 Nora Wolff , Tobias Schwaigert , Dietmar Siche , Darrell G. Schlom , Detlef Klimm

High-quality and sizable single crystals are crucial for studying the intrinsic properties of unconventional superconductors, which are lacking in the 1111 phase of the Fe-based superconductors. Here we report the successful growth of…

Superconductivity · Physics 2015-07-03 Yonghui Ma , Hui Zhang , Bo Gao , Kangkang Hu , Qiucheng Ji , Gang Mu , Fuqiang Huang , Xiaoming Xie

Superconducting single crystals of SmFeAsO$_{1-x}$ without fluorine doping were grown at a pressure of 3.3 GPa and a temperature of 1350-1450 $^\circ$C by using the self-flux method. Plate-like single crystals of a few-150 $\mu$m in their…

We report successful growth of flux free large single crystals of superconducting FeSe1/2Te1/2 with typical dimensions of up to few cm. The AC and DC magnetic measurements revealed the superconducting transition temperature (Tc) value of…

Superconductivity · Physics 2015-09-08 Rajveer Jha , P. K. Maheshwari , Bhasker Gahtori , V. P. S. Awana

Co-doped iron arsenic single crystal of BaFe1.87Co0.13As2 with dimension up to 20 x 10 x 2 mm3 were grown by a nucleation pole: an alumina stick served as nucleation center during growth. The high quality of crystalline was illustrated by…

Superconductivity · Physics 2015-05-13 D. L. Sun , Y. Liu , J. T. Park , C. T. Lin

We report on the synthesis of large single crystals of a new FeSe-layer superconductor Cs0.8(FeSe0.98)2. X-ray powder diffraction, neutron powder-diffraction and magnetization measurements have been used to compare the crystal structure and…

F-substituted NdOBiS2 superconducting single crystals were grown using CsCl/KCl flux. This is the first example of the single-crystal growth of a BiS2-based superconductor. The obtained single crystals had a plate-like shape with a size of…

Single crystals of SrFe2As2 grown using a self-flux solution method were characterized via x-ray, transport and magnetization studies, revealing a superconducting phase below T_c = 21 K characterized by a full electrical resistivity…

Superconductivity · Physics 2009-07-21 S. R. Saha , N. P. Butch , K. Kirshenbaum , J. Paglione

Here we report the growth of sub-millimeter MgB2 single crystals of various shapes under high pressure in Mg-B-N system. Structure refinement using a single-crystal X-ray diffraction analysis gives lattice parameters a=3.0851(5) A and…

Superconductivity · Physics 2009-11-07 S. Lee , H. Mori , T. Masui , Yu. Eltsev , A. Yamamoto , S. Tajima

An eutectic AlCl$_3$/KCl molten salt method in a horizontal configuration was employed to grow millimeter-sized and composition homogeneous CuFeSe$_2$ single crystals due to the continuous growth process in a temperature gradient induced…

We measured resistivity and specific heat of high-quality CsFe$_2$As$_2$ single crystals, which were grown by using a self-flux method. The CsFe$_2$As$_2$ crystal shows sharp superconducting transition at 1.8 K with the transition width of…

Superconductivity · Physics 2013-06-17 A. F. Wang , B. Y. Pan , X. G. Luo , F. Chen , Y. J. Yan , J. J. Ying , G. J. Ye , P. Cheng , X. C. Hong , S. Y. Li , X. H. Chen