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The equation of state of liquid metallic hydrogen is solved numerically. Investigations are carried out at temperatures, which correspond both to the experimental conditions under which metallic hydrogen is produced on earth and the…

Chemical Physics · Physics 2016-02-25 V. T. Shvets

Metallic hydrogen, existing in remarkably extreme environments, was predicted to exhibit long-sought room-temperature superconductivity. Although the superconductivity of metallic hydrogen has not been confirmed experimentally,…

Superconductivity · Physics 2024-06-12 Zihan Zhang , Wendi Zhao , Defang Duan , Tian Cui

The low-pressure stabilization of superconducting hydrides with high critical temperatures ($T_c$s) remains a significant challenge, and experimentally verified superconducting hydrides are generally constrained to a limited number of…

We comment on a recent paper published by McWilliams et al claiming that high-pressure/high-temperature hydrogen is a semi-conductor or semi-metal, in conflict with all earlier measurements on this system which show that it is metallic. We…

Materials Science · Physics 2016-08-17 Isaac F. Silvera , Rachel Husband , Ashkan Salamat , Mohamed Zaghoo

Metallic hydrogen is capable of showing room temperature superconductivity, but its experimental syntheses are extremely hard. Therefore, it is desirable to reduce the synthesis pressure of metallic hydrogen by adding other chemical…

Superconductivity · Physics 2022-11-23 Zhongyu Wan , Ruiqin Zhang

The interplay between electron correlation and nuclear quantum effects makes our understanding of elemental hydrogen a formidable challenge. Here, we present the phase diagram of hydrogen and deuterium at low temperatures and high-pressure…

Materials Science · Physics 2023-06-28 Lorenzo Monacelli , Michele Casula , Kosuke Nakano , Sandro Sorella , Francesco Mauri

Recently, several research groups announced reaching the point of metallization of hydrogen above 400 GPa. Following the mainstream of extensive investigations of compressed polyhydrides, in this work we demonstrate that small (4 atom %)…

In recent years, metal hydride research has become one of the driving forces of the high-pressure community, as it is believed to hold the key to superconductivity close to ambient temperature. While numerous novel metal hydride compounds…

As the simplest element in nature, unraveling the phase diagram of hydrogen is a primary task for condensed matter physics. As conjectured many decades ago, in the low-temperature and high-pressure part of the phase diagram, solid hydrogen…

Superconductivity · Physics 2023-11-14 Mehmet Dogan , Sehoon Oh , Marvin L. Cohen

Instead of praises from colleagues, the claim of observation of metallic hydrogen at 495 GPa by Dias and Silvera was met with skeptism, and grew into a public debate at the International Conference on High-Pressure Science and Technology,…

Materials Science · Physics 2018-04-02 Hua Y. Geng

Evolutionary structure searches are used to predict stable phases with unique stoichiometries in the hydrogen-rich region of the magnesium/hydrogen phase diagram under pressure. MgH$_4$, MgH$_{12}$ and MgH$_{16}$ are found to be…

Materials Science · Physics 2015-06-12 David C. Lonie , James Hooper , Bahadir Altintas , Eva Zurek

We have performed quantum molecular-dynamics simulations for methane under shock compressions up to 80 GPa. We obtain good agreement with available experimental data for the principal Hugoniot, derived from the equation of state. A…

Materials Science · Physics 2015-05-20 Dafang Li , Ping Zhang , Jun Yan

Silane (SiH4) is found to (partially) decompose at pressures above 50 GPa at room temperature into pure Si and H2. The released hydrogen reacts with surrounding metals in the diamond anvil cell to form metal hydrides. A formation of rhenium…

Recent experimental developments in hydrogen-rich materials in high pressures have put this class of materials above others in the race toward room temperature superconductivity. As it is the basis of all the materials in this class, the…

Superconductivity · Physics 2022-02-03 Mehmet Dogan , Sehoon Oh , Marvin L. Cohen

Production of metallic hydrogen is one of the top three open quests of physics. Recent low-temperature experiments report different metallization pressures, varying from 360GPa to 490GPa. In this work, we simulate structural properties,…

Materials Science · Physics 2020-01-29 Lorenzo Monacelli , Ion Errea , Matteo Calandra , Francesco Mauri

In this work we show, that atomic metallic hydrogen (AMH) is formed inside of sintered oxide-nickel electrodes of nickel-cadmium battery over a long period of electrochemical hydrogenation (more than five years). It was established that…

Materials Science · Physics 2013-12-25 Nikolay E. Galushkin , Nataliya N. Yazvinskaya , Dmitriy N. Galushkin

Dynamic compression has been used to synthesize liquid metallic hydrogen at 140 GPa (1.4 million bar) and experimental data and theory predict Al2O3 might be a metallic glass at ~300 GPa. The mechanism of metallization in both cases is…

Disordered Systems and Neural Networks · Physics 2015-05-20 W. J. Nellis

Hydrogen sulfide (H2S) is a prototype molecular system and a sister molecule of water. The phase diagram of solid H2S at high pressures remains largely unexplored arising from the challenges in dealing with the looser S-H bond and larger…

Superconductivity · Physics 2015-03-26 Yinwei Li , Jian Hao , Yanling Li , Yanming Ma

Magnesium dihydride ($\mgh$) stores 7.7 weight % hydrogen, but it suffers from a high thermodynamic stability and slow (de)hydrogenation kinetics. Alloying Mg with lightweight transition metals (TM = Sc, Ti, V, Cr) aims at improving the…

Materials Science · Physics 2009-02-04 Suleyman Er , Dhirendra Tiwari , Gilles A. de Wijs , Geert Brocks

The search for room temperature superconductivity has accelerated dramatically in the last few years driven largely by theoretical predictions that first indicated alloying dense hydrogen with other elements could produce conventional…