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We investigate the electronic structures of some defective boron nitride nanotubes (BNNTs) under transverse electric fields within density-functional theory. (16,0) BNNTs with antisite, carbon substitution, single vacancy, and Stone-Wales…

Materials Science · Physics 2008-07-11 Shuanglin Hu , Zhenyu Li , X. C. Zeng , Jinlong Yang

Density functional theory is applied to study the mechanism of the Stone-Wales defect formation in pure and nitrogen-doped dodecahedral C$_{20}$ fullerenes. The molecular structures of initial and defected cages as well as transition states…

Mesoscale and Nanoscale Physics · Physics 2016-12-01 Konstantin Katin , Mikhail Maslov

In this paper, structural and electronic properties and stability of (10, 0) born nitride nanotube (BNNT) are considered within density functional theory by doping group IV elements of the periodic table. The HOMO-LUMO gap has been strongly…

Materials Science · Physics 2017-09-05 Ali Bahari , Amir Jalalinejad , Mosahhar Bagheri , Masoud Amiri

Stone-Wales transformation is a key mechanism responsible for growth, transformation, and fusion in fullerene, carbon nanotube and other carbon nanostructures. These topological defects also substantially alter the physical and chemical…

Mesoscale and Nanoscale Physics · Physics 2011-11-11 Mukul Kabir , Swarnakamal Mukherjee , Tanusri Saha-Dasgupta

Boron (B)/phosphorus (P) doped single wall carbon nanotubes (B-PSWNTs) are studied by using the First- Principle method based on density function theory (DFT). Mayer bond order, band structure, electrons density and density of states are…

Mesoscale and Nanoscale Physics · Physics 2011-08-15 AQing Chen , QingYi Shao , Zhen Li

Point defects, including atom vacancy, add atom and Stone-Wale defect, close to a (5, 5) single-walled carbon nanotube (SWNT) end were studied by DFT, semi-empirical PM3 method and empirical Brenner Potential. It is found that closer to the…

Materials Science · Physics 2009-11-11 Feng Ding

Recently experiments showed that nodal structural defects are readily formed in the synthesis of single-walled carbon nanotubes (SWNTs) and consequently, SWNTs are likely to deviate from well-defined seamless tubular structures. Here, using…

Mesoscale and Nanoscale Physics · Physics 2014-10-02 Young I. Jhon , Woonjo Cho , Seok Lee , Young Min Jhon

Carbon nanotubes (CNTs) have recently attracted attention as materials for flexible thermoelectric devices. To provide theoretical guideline of how defects influence the thermoelectric performance of CNTs, we theoretically studied the…

Mesoscale and Nanoscale Physics · Physics 2017-04-12 Masato Ohnishi , Takuma Shiga , Junichiro Shiomi

While CNTs are found to have ultra high stiffness and strength, an enormous scatter is also observed in available laboratory results. This paper studies the effects of randomly distributed Stone Wales (SW or 5 7 7 5) defects on the…

Materials Science · Physics 2015-07-29 Qiang Lu , Baidurya Bhattacharya

It has been shown that the two different orientations of Stone-Wales (SW) defects, i.e. longitudinal and circumferential SW defects, on carbon nanotubes (CNTs) result in two different electronic structures. Based on density functional…

Mesoscale and Nanoscale Physics · Physics 2013-01-18 P. Partovi-Azar , A. Namiranian

First-principles calculations reveal that the adsorption of representative first-row atoms with different electronegativity, such as lithium (Li), carbon (C) and fluorine (F), on zigzag single-walled boron nitride nanotubes (BNNTs) exhibits…

Materials Science · Physics 2007-05-23 Jia Li , Gang Zhou , Haitao Liu , Wenhui Duan

The electronic properties of boron-nitride nanoribbons (BNNRs) doped with a line of carbon atoms are investigated by using density functional calculations. Three different configurations are possible: the carbon atoms may replace a line of…

Mesoscale and Nanoscale Physics · Physics 2015-06-04 J. Beheshtian , A. Sadeghi , M. Neek-Amal , K. H. Michel , F. M. Peeters

Carbon nanotubes (CNT) have been recently proposed as stabilizers against grain growth that can happen even at low temperature inputs in nano-crystalline and ultrafine-grained materials obtained by severe plastic deformation. In this study,…

Substitutional carbon defects in hexagonal boron nitride (hBN) are prominent single photon emitters (SPEs), and their potential for spin activity ($S\geq1$) is particularly intriguing. While studies have largely focused on intra-layer…

Materials Science · Physics 2025-06-03 Ignacio Chacon , Andrea Echeverri , Carlos Cardenas , Francisco Munoz

We perform first-principles calculations to investigate the structural and electronic properties of metal-doped (10, 0) carbon nanotubes (CNTs) on a single hexagonal boron nitride (hBN) sheet in the presence of an external electric field.…

Mesoscale and Nanoscale Physics · Physics 2015-07-22 Seoung-Hun Kang , Gunn Kim , Young-Kyun Kwon

We present a first-principles computational study of the thermodynamics of carbon defects in hexagonal boron nitride (hBN). The defects considered are carbon monomers, dimers, trimers, and larger carbon clusters, as well as complexes of…

Materials Science · Physics 2022-01-28 Marek Maciaszek , Lukas Razinkovas , Audrius Alkauskas

We have made a systematic theoretical study to determine which are the most stable structures for substitutional nitrogen defects in carbon nanotubes, by making total energy calculations via DFT. These calculations were made for a (5,5) and…

Other Condensed Matter · Physics 2007-05-23 Mariana Rossi , Adalberto Fazzio , Antonio J. R. da Silva

The phosphorus-doped single wall carbon nanotube (PSWCNT) is studied by using First-Principle methods based on Density Function Theory (DFT). The formation energy, total energy, band structure, geometry structure and density of states are…

Mesoscale and Nanoscale Physics · Physics 2011-08-10 AQing Chen , QingYi Shao , ZhiCheng Lin

The Stone-Wales defect is a well-known and significant defective structure in carbon materials, impacting their mechanical, chemical, and electronic properties. Recently, a novel metal-carbon nanomaterial named Volleyballene has been…

Materials Science · Physics 2023-06-21 Peng-Bo Liu , Jing-Jing Guo , Hui-Yan Zhao , Hong-Man Ma , Jing Wang , Ying Liu

Having access to the chemical environment at the atomic level of a dopant in a nanostructure is crucial for the understanding of its properties. We have performed atomically-resolved electron energy-loss spectroscopy to detect individual…

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