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Legendre transform between thermodynamic quantities such as the Helmholtz free energy and entropy plays a key role in the formulation of the canonical ensemble. In the standard treatment, the transform exchanges the independent variable…

Statistical Mechanics · Physics 2025-01-24 Ramandeep S. Johal

The extended gaussian ensemble (EGE) is introduced as a generalization of the canonical ensemble. The new ensemble is a further extension of the Gaussian ensemble introduced by J. H. Hetherington [J. Low Temp. Phys. {\bf 66}, 145 (1987)].…

Statistical Mechanics · Physics 2009-11-10 Ramandeep S. Johal , Antoni Planes , Eduard Vives

The physical significance of the stochastic processes associated to the generalized Gibbs ensembles is scrutinized here with special attention to the thermodynamic fluctuations of small systems. The contact with the environment produces an…

Statistical Mechanics · Physics 2024-09-04 Amilcare Porporato , Salvatore Calabrese , Lamberto Rondoni

Stochastic field theories are often constructed phenomenologically, without a systematic assessment of thermodynamic consistency or local detailed balance. This may hinder a physical description of irreversibility at the field-theoretic…

Statistical Mechanics · Physics 2026-04-29 Héctor Vaquero del Pino , François Gay-Balmaz , Hiroaki Yoshimura , Lock Yue Chew

A statistical system is classically defined on a set of microstates $E$ by a global energy function $H : E \to \mathbb{R}$, yielding Gibbs probability measures (softmins) $\rho^\beta(H)$ for every inverse temperature $\beta = T^{-1}$. Gibbs…

Statistical Mechanics · Physics 2022-07-05 Olivier Peltre

We connect the rare fluctuations of an Equilibrium (EQ) process and the typical fluctuations of a nonequilibrium (NE) stationary process. In the framework of large deviation theory, this observation allows us to introduce NE thermodynamic…

Statistical Mechanics · Physics 2016-01-20 Gatien Verley

In this paper, we suppose a possible extension of Gibbs ensemble theory so that it can provide a reasonable description to phase transitions and spontaneous symmetry breaking. The extension is founded on three hypotheses, and can be…

Statistical Mechanics · Physics 2008-11-26 Ming-wen Xiao

We consider stochastic thermodynamics as a theory of statistical inference for experimentally observed fluctuating time-series. To that end, we introduce a general framework for quantifying the knowledge about the dynamical state of the…

Statistical Mechanics · Physics 2015-05-19 Bernhard Altaner , Jürgen Vollmer

Starting at the mesoscopic level with a general formulation of stochastic thermodynamics in terms of Markov jump processes, we identify the scaling conditions that ensure the emergence of a (typically nonlinear) deterministic dynamics and…

Statistical Mechanics · Physics 2025-05-26 Gianmaria Falasco , Massimiliano Esposito

The present paper studies a large class of temperature dependent probability distributions and shows that entropy and energy can be defined in such a way that these probability distributions are the equilibrium states of a generalized…

Statistical Mechanics · Physics 2015-06-24 Jan Naudts

We brief{}ly review the connection between statistical mechanics and thermodynamics. We show that, in order to satisfy thermodynamics and its Legendre transformation mathematical frame, the celebrated Boltzmann-Gibbs~(BG) statistical…

Statistical Mechanics · Physics 2014-11-03 Constantino Tsallis , Leonardo J. L. Cirto

Counting ad infinitum is the holographic observable to a statistical dynamics with finite states under independent repeated sampling. Entropy provides the infinitesimal probability for an observed frequency $\hat{\boldsymbol{\nu}}$ w.r.t. a…

Statistical Mechanics · Physics 2025-01-14 Hong Qian

We extend a generic class of systems which have previously been shown to spontaneously develop scaling (power law) distributions of their elementary degrees of freedom. While the previous systems were linear and exploded exponentially for…

adap-org · Physics 2009-10-28 S. Solomon , M. Levy

We consider stochastic energy balance and entropy production (EP) in a generalized Langevin dynamics of macrospins, allowing for both amplitude and direction fluctuations, under external magnetic field. EP is calculated using Fokker-Planck…

Statistical Mechanics · Physics 2015-10-09 Swarnali Bandopadhyay , Debasish Chaudhuri , A. M. Jayannavar

We show how the Legendre transforms of the fundamental thermodynamic relation can be used to introduce different statistical ensembles.

Statistical Mechanics · Physics 2014-10-16 S. Stepanow

For a quantum system in a macroscopically large volume $V$, prepared in a pure state and subject to maximally noisy or ergodic unitary dynamics, the reduced density matrix of any sub-system $v\ll V$ is almost surely totally mixed. We show…

Statistical Mechanics · Physics 2020-01-15 Michel Bauer , Denis Bernard , Tony Jin

A change in a stochastic system has three representations: Probabilistic, statistical, and informational: (i) is based on random variable $u(\omega)\to\tilde{u}(\omega)$; this induces (ii) the probability distributions $F_u(x)\to…

Statistical Mechanics · Physics 2019-02-27 Hong Qian , Yu-Chen Cheng , Lowell F. Thompson

Fluctuation theorems make use of time reversal to make predictions about entropy production in many-body systems far from thermal equilibrium. Here we review the wide variety of distinct, but interconnected, relations that have been derived…

Statistical Mechanics · Physics 2007-08-02 R. J. Harris , G. M. Schütz

We discuss the quantum statistical fluctuations of energy in subsystems of hot relativistic gas for both spin-zero and spin half particles. We explicitly show the system size dependence of the quantum statistical fluctuation of energy. Our…

Nuclear Theory · Physics 2022-06-15 Arpan Das

Relaxation dynamics of complex quantum systems with strong interactions towards the steady state is a fundamental problem in statistical mechanics. The steady state of subsystems weakly interacting with their environment is described by the…

Statistical Mechanics · Physics 2016-06-22 Alexey M. Shakirov , Yulia E. Shchadilova , Alexey N. Rubtsov
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