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We report a structural transition found in Ca10(Ir4As8)(Fe2-xIrxAs2)5, which exhibits superconductivity at 16 K. The c-axis parameter is doubled below a structural transition temperature of approximately 100 K, while the tetragonal symmetry…

The structure of Na0.5CoO2, the low temperature insulator that separates the magnetic and superconducting regions in the NaxCoO2.yH2O phase diagram, is studied by high resolution powder neutron diffraction at temperatures between 10 and 300…

Strongly Correlated Electrons · Physics 2007-05-23 A. J. Williams , J. P. Attfield , M. L. Foo , R. J. Cava

In this paper we report an extensive neutron diffraction investigation at high temperature on the BaCe0.80Y0.20O2.9 proton conducting material. Our results precisely define the structural evolution of the compound as a function of…

Materials Science · Physics 2007-11-19 Lorenzo Malavasi , Clemens Ritter , Gaetano Chiodelli

In this work, a comprehensive research coupling experiment and computation has been performed to understand the phase transition of Na3SbS4 and to synthesize cubic Na3SbS4 (c-Na3SbS4), a high temperature phase of Na3SbS4 that is difficult…

Materials Science · Physics 2017-07-18 Dechao Zhang , Xiaoting Cao , Di Xu , Chuang Yu , Wentao Hu , Xinlin Yan , Jianli Mi , Bin Wen , Limin Wang , Long Zhang

Given the unique optical properties of LiF, it is often used as an observation window in high-temperature and pressure experiments; and, hence, estimates of its transmission properties are necessary to interpret observations. Since direct…

Materials Science · Physics 2016-07-27 R. E. Jones , D. K. Ward

Na-ion conduction, and correlations between Na-ion conduction pathways and crystal structure have been investigated as a function of temperature in the layered battery material Na2Ni2TeO6 by impedance spectroscopy and neutron diffraction,…

Materials Science · Physics 2020-07-15 A. K. Bera , S. M. Yusuf

We report crystal growth and below 2.5K superconductivity of Nb0.25Bi2Se3. These crystals are grown by self flux method. The X-ray diffraction (XRD) pattern of as grown crystal flake shows (00l) plane (c-orientation) growth. The Rietveld…

Superconductivity · Physics 2019-11-20 M. M. Sharma , P. Rani , Lina Sang , X. L. Wang , V. P. S. Awana

The layered compound LaOBiSSe was successfully synthesized by a two-step solid-state reaction method, which is isostructural with the quaternary compound LaOBiS2 indicated by the powder X-ray diffraction characterization, and the crystal…

Superconductivity · Physics 2014-05-01 Xiao-Chuan Wang , Dong-Yun Chen , Qi Guo , Jia Yu , Bin-Bin Ruan , Qing-Ge Mu , Gen-Fu Chen , Zhi-An Ren

As an A-site-vacant perovskite-type oxide, ReO3 undergoes sequential pressure-driven structural transitions associated with the rotation of ReO6 octahedra. The rhombohedral-I phase in the pressure range of 12-39 GPa is featured by a lattice…

Superconductivity · Physics 2025-04-03 P. F. Shan , T. L. Lu , Z. Y. Liu , Y. Y. Jiao , P. T. Yang , J. Hou , L. Ma , Y. Uwatoko , X. L. Dong , B. S. Wang , M. Liu , J. P. Sun , J. -G. Cheng

The structure of the material responsible for the room temperature and near ambient pressure superconductivity reported in an N-doped lutetium hydride [Nature, 615, 244 (2023)] has not been conclusively determined. Herein, density…

Superconductivity · Physics 2023-08-09 Katerina P. Hilleke , Xiaoyu Wang , Dongbao Luo , Nisha Geng , Busheng Wang , Eva Zurek

Full pattern Le-Bail refinement using x-ray powder diffraction profiles of Sr1-xCaxTiO3 for x=0.02, 0.04 in the temperature range 12 to 300 K reveals anomalies in the unit cell parameters at 170, 225 K due to an antiferrodistortive (cubic…

Materials Science · Physics 2015-05-13 Sanjay Kumar Mishra , Dhananjai Pandey

A new and known barium cerates doped by In and Ga were synthesized in air at 1700 K. The synthesis was performed by solid state reactions from BaCO3, CeO2, In2O3 or Ga2O3. X-ray diffraction profiles of the powdered samples were obtained…

Materials Science · Physics 2007-05-23 N. I. Matskevich , T. I. Chupahina , G. V. Bazuev , F. A. Kuznetsov

La1.8-xEu0.2SrxCuO4 (LESCO) is the member of the 214 family which exhibits the largest intervals among the structural, charge ordering (CO), magnetic, and superconducting transition temperatures. By using new dc transport measurements and…

Strongly Correlated Electrons · Physics 2015-06-17 M. Autore , P. Di Pietro , P. Calvani , U. Schade , S. Pyon , T. Takayama , H. Takagi , S. Lupi

The Ru0.9Sr2YCu2.1O7.9 sample being synthesized by high-pressure high-temperature solid-state reaction underwent (weak) ferromagnetic transition at 150 K followed by superconducting transition at 30 K. It showed clear Meissner signal in the…

Superconductivity · Physics 2007-05-23 V. P. S. Awana , T. Kawashima , E. Takayama-Muromachi

We report the synthesis of single phase Bi3O2S3 sample and confirm the occurrence of bulk superconductivity with transition temperature at 5.8 K. The Bi3O2S3 super-conductor is categorized as the typical type-II supercon-ductor based on the…

Superconductivity · Physics 2014-11-06 Jifeng Shao , Zhongheng Liu , Xiong Yao , Li Pi , Shun Tan , Changjin Zhang , Yuheng Zhang

Here we report the synthesis and superconductivity of a novel ternary compound LaPd2Bi2. Shiny plate-like single crystals of LaPd2Bi2 were first synthesized by high-temperature solution method with PdBi flux. X-ray diffraction analysis…

Superconductivity · Physics 2018-09-14 Qing-Ge Mu , Bo-Jin Pan , Bin-Bin Ruan , Tong Liu , Kang Zhao , Lei Shan , Gen-Fu Chen , Zhi-An Ren

In this work, the potential to exploit Aurivillius higher order composition (n=6) given by Bi4Ti3O12-3BiFeO3 as single phase and high temperature magnetoelectric materials are well explored by elaborately studying the concerned structure…

Materials Science · Physics 2022-12-20 K. R. S. Preethi Meher , K. B. R. Varma

LiNi0.5Mn1.5O4, which has a spinel framework structure, is a promising candidate for the cathode material of next-generation lithium-ion batteries with high energy density. We investigate the structural transition in LixNi0.5Mn1.5O4 (0 <= x…

Materials Science · Physics 2013-02-05 Ippei Kishida , Kengo Orita , Atsutomo Nakamura , Yoshiyuki Yokogawa

The superconducting properties and structural parameters, including the Gr\"uneisen parameter ({\gamma}G), of the BiCh2-based (Ch: S, Se) layered superconductor LaO0.5F0.5BiS2-xSex were investigated. The superconducting transition…

The investigation of the structural phase transition in the vicinity of the Curie temperature $T_c$ of LiNb$_{1-x}$Ta$_x$O$_3$ crystals is motivated by the expected combination of advantageous high-temperature properties of LiNbO$_3$ and…