Related papers: The Excess Heat Capacity in Glass-forming Liquid S…
Ca2-xNaxCuO2Cl2 is a structural analogue to the La2-xSrxCuO4 superconductor. By substituting Na+ for Ca2+ mobile holes are introduced into the CuO2 planes. A series of experiments shows that the Na content x depends not only on the pressure…
We report for the first time real time in situ and quantitative measurements of the mutarotation reaction of lactose in the solid state. The experiments have been performed by 13C NMR. We show that mutarotation is initiated on heating the…
The present study deals with the anomalous heat capacity peak and thermal conductivity of BaVS$_3$ near the metal-insulator transition present at $69$ K. The transition is related to a structural transition from an orthorhombic to…
We have measured the heat capacity of YBa2Cu3O6+d for 0.7<d<0.8 between 1.8 and 300K. It was found that doping dependences of specific heat jump and temperature of heat capacity jump contradict to the assumption of spatially homogeneous…
The use of oxide glasses is pervasive throughout everyday amenities and commodities. Such glasses are typically electrical insulators, and endowing them with electrical conductivity without changing their salutary mechanical properties,…
The heat capacity Cm of polycrystalline fullerite C60 doped with nitrogen has been measured in the temperature interval 2 - 13 K. The contributions to heat capacity from translational lattice vibrations (Debye contribution), orientational…
The phenomenon of the glass transition is an unresolved problem of condensed matter physics. Its prominent feature, the super-Arrhenius temperature dependence of the transport coefficients remains a challenge to be described over the full…
We give a brief introduction to the mode-coupling theory of the glass transition, a theory which was proposed a while ago to describe the dynamics of supercooled liquids. After presenting the basic equations of the theory, we review some of…
Key aspects of glasses are controlled by the presence of excitations in which a group of particles can rearrange. Surprisingly, recent observations indicate that their density is dramatically reduced and their size decreases as the…
In a preceding paper, Mukhopadhyay and I studied the diffusive motion of a tagged molecule in a heterogeneous glass-forming liquid at temperatures just above a glass transition. Among other features of this system, we postulated a relation…
Single Crystals of Nd$_{1-x}$Ca$_{1+x}$MnO$_{4}$ have been prepared by the traveling floating-zone method, and possible evidence of a charge -orbital density wave in this material presented earlier [PRB68,092405 (2003)] using High…
We have obtained effective medium theory (EMT) interatomic potential parameters suitable for studying Cu-Mg metallic glasses. We present thermodynamic and structural results from simulations of such glasses over a range of compositions. We…
The Arrhenius crossover temperature, $T_{A}$, corresponds to a thermodynamic state wherein the atomistic dynamics of a liquid becomes heterogeneous and cooperative; and the activation barrier of diffusion dynamics becomes…
We first present a comparative analysis of temperature evolution of the excess thermodynamic potentials (state functions), the enthalpy $\Delta H$, entropy $\Delta S$ and Gibbs free energy $\Delta \Phi$, determined for \textit{i})…
Boiling crisis is the rapid formation of the quasi-continuous vapor film between the heater and the liquid when the heat supply exceeds a critical value. We propose a mechanism for the boiling crisis that is based on the spreading of the…
We report specific heat measurements down to 0.4 K on the layered oxide Na$_x$CoO$_2\cdot\it{y}$H$_2$O/D$_2$O with 0 $\le$ $\it{x}$ $\le$ 0.74 and $\it{y}$ = 0 and 1.4. For the nonhydrated system ($\it{y}$ = 0), the electronic specific heat…
Simple statistical agglomeration models can provide a universal link between the local structure and the glass transition temperature in network glasses. We first stress the physical features of the models and the hypothesis made, and then…
Motivated by an experimental finding on the density of supercooled water at high pressure [O. Mishima, J. Chem. Phys. 133, 144503 (2010)] we performed atomistic molecular dynamics simulations study of bulk water in the isothermal-isobaric…
The dynamic structure factor of glassy and liquid glycerol has been measured by inelastic X-ray scattering in the exchanged momentum ($Q$) region $Q$=2$\div$23 nm$^{-1}$ and in the temperature range 80$\div$570 K. Beside the propagating…
The glass transition GT is usually thought of as a structural arrest that occurs during the cooling of a liquid, or sometimes a plastic crystal, trapping a metastable state of the system before it can recrystallize to stabler forms1. This…