Related papers: The Excess Heat Capacity in Glass-forming Liquid S…
Conventional heat carrier liquids have demonstrated remarkable enhancement in heat and mass transfer when nanoparticles were suspended in them. These liquid-nanoparticle suspensions are now known as Nanofluids. However the relationship…
The metallic compound NaRh2O4 forms a full range solid solution to the insulating phase CaRh2O4. At a Na concentration of 0.25 moles per formula unit, we found an unexpected contribution to the specific heat at low temperature [K. Yamaura…
Comprehensive studies of the low-temperature specific heat C(T,H) in NaxCoO2-yH2O are presented. At H=0, a very sharp anomaly was observed at T=4.7 K indicating the existence of bulk superconductivity. There exists the T^2 term in C(T,H=0)…
Three liquid crystalline equimolar mixtures are formulated, each containing the MHPOBC compound and the homolog from the 3FmHPhF6 series with m = 4, 5, and 6. The properties of the mixtures are investigated by differential scanning…
The liquid-gas spinodal and the glass transition define ultimate boundaries beyond which substances cannot exist as (stable or metastable) liquids. The relation between these limits is analyzed {\it via} computer simulations of a model…
The range of the magnitude of the liquid viscosity as a function of the temperature (T) is one of the most impressive of any physical property, changing by approximately 17 orders of magnitude from its extrapolated value at infinite…
We study theoretically the non-linear response properties of glass formers. We establish several general results which, together with the assumption of Time-Temperature Superposition, lead to a relation between the non-linear response and…
The electrocaloric (EC) effect is calculated for Gd-substituted PMN (x = 0 to 0.1) relaxors from temperature dependent heat capacity and polarization measurements, using a thermodynamic Maxwell equation. Polarization change with temperature…
It is shown that measured heat capacity depends on the rate of the temperature variation and on the initial state of a system. It is calculated here in the framework of two-level model. Fenomenological approach gives the same results.
We consider the Mode Coupling Theory (MCT) of Glass transition for a Binary fluid. The Equations of Nonlinear Fluctuating Hydrodynamics are obtained with a proper choice of the slow variables corresponding to the conservation laws. The…
Comprehensive low-temperature specific heat data C(T,H) of Na_0.35CoO2-1.3H_2O with temperature T down to 0.6 K and the magnetic field H up to 8 T are presented. For the normal state, the values of gamma_n=13.94 mJ/mol K2, and Debye…
Super-cooled liquids are characterized by their fragility: the slowing down of the dynamics under cooling is more sudden and the jump of specific heat at the glass transition is generally larger in fragile liquids than in strong ones.…
Quantum effects in material systems are often pronounced at low energies and become insignificant at high temperatures. We find that, perhaps counterintuitively, certain quantum effects may follow the opposite route and become sharp when…
Heat Capacity of needle-like [length=5mm, diameter=1 mm] $\beta$-FeSi$_{2}$ single crystal, grown by chemical vapor transport has been measured. Two anomalies are found, a broad deviation centered around 160 K and a clear deviation at a…
The possibility of observing a glass transition in water before crystallisation occurs has been debated vigorously but inconclusively over five decades [1,2]. For two decades a glass transition at 136K [2,3] was accepted but this transition…
Understanding thermodynamics in liquids at the atomic level is challenging because of strong atomic interactions and lack of symmetry. Recent prior theoretical works have focused on describing heat capacity of liquids in terms of…
We describe a model for the thermodynamics and dynamics of glass-forming liquids in terms of excitations from an ideal glass state to a Gaussian manifold of configurationally excited states. The quantitative fit of this three parameter…
Thin layers of water on biomolecular and other nanostructured surfaces can be supercooled to temperatures not accessible with bulk water. Chen et al. [PNAS 103, 9012 (2006)] suggested that anomalies near 220 K observed by quasi-elastic…
Heat transport in glasses across a wide range of temperature is vital for applications in gate dielectrics and heat insulator. However, it remains poorly understood due to the challenges of modeling vibrational anharmonicity below glass…
Dynamics near the surface of glasses is generally much faster than in the bulk. Neglecting static perturbations of structure at the surface, we use random first order transition theory to show the free energy barrier for activated motion…