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We measured the temperature dependences of the capacity and dielectric losses of the tape-casted dense ferroelectric composites consisting of 28 vol.% BaTiO3 nanoparticles (average size 24 nm) in the polyvinyl butyral polymer and 35 vol.%…

We report inelastic neutron scattering measurements of the phonon spectra in a pure powder sample of the multiferroic material BiFeO3. A high-temperature range was covered to unravel the changes in the phonon dynamics across the Neel (T_N ~…

Materials Science · Physics 2015-03-19 M. Zbiri , H. Schober , N. Choudhury , R. Mittal , S. L. Chaplot , S. J. Patwe , S. N. Achary , A. K. Tyagi

Despite fascinating experimental results, the influence of defects and elastic strains on the physical state of nanosized ferroelectrics is still poorly explored theoretically. One of unresolved theoretical problems is the analytical…

Materials Science · Physics 2023-08-29 Eugene A. Eliseev , Anna N. Morozovska , Sergei V. Kalinin , Dean R. Evans

We study theoretically spectrum of radial vibrational modes in composite metal nanostructures such as bimetallic core-shell particles and metal nanoshells with dielectric core in an environment. We calculate frequencies and damping rates of…

Materials Science · Physics 2008-08-27 Arman S. Kirakosyan , Tigran V. Shahbazyan

We propose the synthesis of frequency dispersion of layered structures based on the design of multi-ordered optical filters using nanocircuit concepts. Following the well known insertion loss method commonly employed in the design of…

Optics · Physics 2017-04-05 Yue Li , Iñigo Liberal , Nader Engheta

Contrary to a paradigm of metal-enhanced fluorescence, unusually thick dielectric coatings can be very favorable to achieve extreme values of averaged fluorescence enhancement factor $\bar F\gtrsim 3000$ for emitters located on the surface,…

Optics · Physics 2021-09-24 Ilia L. Rasskazov , Alexander Moroz , P. Scott Carney

The structures, as building-blocks for designing functional nanomaterials, have fueled the development of versatile nanoprobes to understand local structures of noncrystalline specimens. Progresses in analyzing structures of individual…

Deciphering the three-dimensional atomic structure of solid-solid interfaces in core-shell nanomaterials is the key to understand their remarkable catalytical, optical and electronic properties. Here, we probe the three-dimensional atomic…

Materials Science · Physics 2023-06-21 Zezhou Li , Zhiheng Xie , Yao Zhang , Xilong Mu , Hai-jing Yin , Ya-wen Zhang , Colin Ophus , Jihan Zhou

We report far-infrared dielectric properties of powder form ferroelectric SrTiO3. Terahertz time-domain spectroscopy (THz-TDS) measurement reveals that the low-frequency dielectric response of SrTiO3 is a consequence of the lowest…

Materials Science · Physics 2008-02-08 Jiaguang Han , Fan Wan , Zhiyuan Zhu , Weili Zhang

A surface layer ("skin") that is functionally and structurally different from the bulk was found in single crystals of BiFeO3. Impedance analysis indicates that a previously reported anomaly at T* ~ 275 \pm 5 ^/circC corresponds to a phase…

Materials Science · Physics 2015-05-20 X. Marti , P. Ferrer , J. Herrero-Albillos , J. Narvaez , V. Holy , N. Barrett , M. Alexe , G. Catalan

Artificial metasurfaces are capable of completely manipulating the phase, amplitude, and polarization of light with high spatial resolutions. The emerging design based on high-index and low-loss dielectrics has led to the realization of…

Interdiffusion phenomena between adjacent materials are highly prevalent in semiconductor device architectures and can present a major reliability challenge for the industry. To fully capture and better understand these phenomena,…

We have carried out systematic temperature-dependent neutron diffraction measurements in conjunction with dielectric spectroscopy from 6 to 300 K for sodium niobate based compounds (1-x) NaNbO3 -xBaTiO3 (NNBTx). The dielectric constant is…

Materials Science · Physics 2018-05-23 S. K. Mishra , Mrinal Jauhari , R. Mittal , P. S. R. Krishna , V. R. Reddy , S. L. Chaplot

We investigate the thermoelastic response of a nanolayered sample composed of a metallic SrRuO3 (SRO) electrode sandwiched between a ferroelectric Pb(Zr0.2Ti0.8)O3 (PZT) film with negative thermal expansion and a SrTiO3 substrate. SRO is…

Mesoscale and Nanoscale Physics · Physics 2015-06-16 H. A. Navirian , D. Schick , P. Gaal , W. Leitenberger , R. Shayduk , M. Bargheer

In the present work the authors report results of broadband dielectric spectroscopy on various samples of CaCu3Ti4O12, including so far only rarely investigated single crystalline material. The measurements extend up to 1.3 GHz, covering…

Materials Science · Physics 2008-09-03 S. Krohns , P. Lunkenheimer , S. G. Ebbinghaus , A. Loidl

The spectral characteristics of near-field thermal emission from nanoparticle arrays are explained by comparison to the dispersions for propagating modes. Using the coupled dipole model, we analytically calculate the spectral emission from…

Mesoscale and Nanoscale Physics · Physics 2017-07-03 Eric Tervo , Zhuomin Zhang , Baratunde Cola

In this work the polarizability of a subwavelength core-shell sphere is considered, where the shell exhibits a radially inhomogeneous permittivity profile. A mathematical treatment of the elec- trostatic polarizability is formulated in…

Optics · Physics 2018-11-14 Dimitrios C. Tzarouchis , Ari Sihvola

The structural, dielectric and ferroelectric properties of lead-free (Na0.5-xKxBi0.5-xLax)TiO3 powders synthesized by sol-gel self-combustion method were investigated. Rietveld refinement of Synchrotron x-ray diffraction data confirms pure…

High-frequency dielectric studies of Bi_0.85Nd_0.15FeO_3 ceramics performed betweeen 100 and 900 K reveal hardening of most polar phonons on cooling below antiferroelectric phase transition, which occurs near 600 K. Moreover, a strong THz…

Materials Science · Physics 2011-10-18 V. Goian , S. Kamba , S. Greicius , D. Nuzhnyy , S. Karimi , I. M. Reaney

Composition-dependent structural and polar properties of epitaxial short-period CaTiO_3/SrTiO_3/BaTiO_3 superlattices grown on a SrTiO_3 substrate are investigated with first-principles density-functional theory computational techniques.…

Materials Science · Physics 2009-12-16 Serge M. Nakhmanson , K. M. Rabe , David Vanderbilt