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We report the coherent excitation of the highly forbidden $^2S_{1/2} \rightarrow {^2}F_{7/2}$ clock transition in the odd isotope $^{173}\mathrm{Yb}^+$ with nuclear spin $I = 5/2$, and reveal the hyperfine-state-dependent, nuclear spin…

We report a direct measurement of the $7s\ ^2S_{1/2}\rightarrow$ $7p\ ^2P_{3/2}$ electric dipole transition frequency in $^{226}$Ra$^{+}$. With a single laser-cooled radium ion we determine the transition frequency to be 785722.11(3) GHz by…

Atomic Physics · Physics 2020-11-10 C. A. Holliman , M. Fan , A. Contractor , M. W. Straus , A. M. Jayich

We report the direct excitation of the highly forbidden (6s^2) 1S0 - (6s6p) 3P0 optical transition in two odd isotopes of ytterbium. As the excitation laser frequency is scanned, absorption is detected by monitoring the depletion from an…

Atomic Physics · Physics 2009-11-11 C. W. Hoyt , Z. W. Barber , C. W. Oates , T. M. Fortier , S. A. Diddams , L. Hollberg

We report on an evaluation of an optical clock that uses the $\phantom{}^2S_{1/2} \rightarrow \phantom{}^2D_{5/2}$ transition of a single $^{88}$Sr$^+$ ion as the reference. In contrast to previous work, we estimate the effective…

Compared to other stable isotopes of $\rm{Yb}^+$, $^{173}\rm{Yb}^+$ has a richer hyperfine structure, which leads to more favorable clock transitions, spectroscopic techniques for probing new physics, and more sophisticated quantum…

We compare two optical clocks based on the $^2$S$_{1/2}(F=0)\to {}^2$D$_{3/2}(F=2)$ electric quadrupole (E2) and the $^2$S$_{1/2}(F=0)\to {}^2$F$_{7/2}(F=3)$ electric octupole (E3) transition of $^{171}$Yb$^{+}$ and measure the frequency…

Atomic Physics · Physics 2021-01-08 R. Lange , N. Huntemann , J. M. Rahm , C. Sanner , H. Shao , B. Lipphardt , Chr. Tamm , S. Weyers , E. Peik

We measured the absolute frequency of the optical clock transition 1S0 (F = 1/2) - 3P0 (F = 1/2) of 171Yb atoms confined in a one-dimensional optical lattice and it was determined to be 518 295 836 590 863.5(8.1) Hz. The frequency was…

Optical frequency standards, lasers stabilized to atomic or molecular transitions, are widely used in length metrology and laser ranging, provide a backbone for optical communications and lie at the heart of next-generation optical atomic…

Quadrupole shifts for three prominent clock transitions, $[4f^{14} 6s] ^2S_{1/2} \rightarrow [4f^{14} 5d] ^2D_{3/2}$, $[4f^{14} 6s] ^2S_{1/2} \rightarrow [4f^{14} 5d] ^2D_{5/2}$ and $[4f^{14} 6s] ^2S_{1/2} \rightarrow [4f^{13} 6s^2]…

Atomic Physics · Physics 2015-06-22 D. K. Nandy , B. K. Sahoo

We propose a new frequency standard based on a $4f^{14} 6s6p~ ^3\!P_0 - 4f^{13} 6s^2 5d ~(J=2)$ transition in neutral Yb. This transition has a potential for high stability and accuracy and the advantage of the highest sensitivity among…

Atomic Physics · Physics 2018-05-02 M. S. Safronova , S. G. Porsev , Christian Sanner , Jun Ye

Additional clock transitions of ytterbium atoms based on inner-shell orbital transition could benefit the search for new physics beyond the Standard Model. Observation of these transitions with high resolution is a prerequisite for making…

Atomic Physics · Physics 2026-01-21 Yao Yuan , Wang Congyu , Zou Jinpeng , Shi Haosen , Xin Yuqing , Ma Longsheng , Jiang Yanyi

We use advanced computational techniques to study the electronic structure of the Hf$^{12+}$ ion, with the goal of assessing its potential for use in highly accurate atomic optical clocks and search for new physics. Such clocks should…

Atomic Physics · Physics 2025-11-04 Saleh O. Allehabi , V. A. Dzuba , V. V. Flambaum

The electric dipole-forbidden, quadrupole 6S1/2 <-> 5D3/2 transition in Ba+ near 2051 nm, with a natural linewidth of 13 mHz, is attractive for potential observation of parity non-conservation, and also as a clock transition for a barium…

We report a measurement of the radiative lifetime of the $^2F_{7/2}$ level of $^{171}$Yb$^+$ that is coupled to the $^2S_{1/2}$ ground state via an electric octupole transition. The radiative lifetime is determined to be $9.96(50)\times…

Atomic Physics · Physics 2026-05-18 R. Lange , A. A. Peshkov , N. Huntemann , Chr. Tamm , A. Surzhykov , E. Peik

The paper describes the results achieved in the development of the compact transportable fully automated optical clock based on a single 171Yb+ ion in a radiofrequency (RF) quadrupole trap. The resulted measurements demonstrated the 4.9E-16…

Over a two-year duration, we have compared the frequency of the 199Hg+ 5d106s 2S 1/2 (F=0)<-> 5d9 6s2 2D 5/2 (F=2) electric-quadrupole transition at 282 nm with the frequency of the ground-state hyperfine splitting in neutral 133Cs. These…

We demonstrate a one-dimensional optical lattice clock with ultracold 171Yb atoms, which is free from the linear Zeeman effect. The absolute frequency of the 1S0(F = 1/2) - 3P0(F = 1/2) clock transition in 171Yb is determined to be 518 295…

We measured the absolute frequency of the $^1S_0$ - $^3P_0$ transition of $^{171}$Yb atoms confined in a one-dimensional optical lattice relative to the SI second. The determined frequency was 518 295 836 590 863.38(57) Hz. The uncertainty…

We report precision measurement of the unperturbed ${^{3}}D_1$ microwave transition frequencies in $^{176}\mathrm{Lu}^+$ to a fractional uncertainty of $4\times10^{-14}$. We find the $|F,m_F\rangle=|8,0\rangle$ to $|7,0\rangle$ hyperfine…

Atomic Physics · Physics 2025-10-09 M. D. K. Lee , Qi Zhao , Qin Qichen , Zhao Zhang , N. Jayjong , K. J. Arnold , M. D. Barrett

We report a frequency measurement of the 1S0-3P0 transition of 87Sr atoms in an optical lattice clock. The frequency is determined to be 429 228 004 229 879 (5) Hz with a fractional uncertainty that is comparable to state-of-the-art optical…