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We describe experimental investigations on an optical frequency standard based on a laser cooled 171Yb+ ion confined in a radiofrequency Paul trap. The electric-quadrupole transition from the 2S1/2(F=0) ground state to the 2D3/2(F=2) state…

Atomic Physics · Physics 2017-08-23 Chr. Tamm , T. Schneider , E. Peik

The highly forbidden $^2$S$_{1/2} \rightarrow ^2$F$_{7/2}$ electric octupole transition in $^{171}$Yb$^+$ is a potential candidate for a redefinition of the SI second. We present a measurement of the absolute frequency of this optical…

We describe experiments with an optical frequency standard based on a laser cooled $^{171}$Yb$^+$ ion confined in a radiofrequency Paul trap. The electric-quadrupole transition from the $^2S_{1/2}(F=0)$ ground state to the $^2D_{3/2}(F=2)$…

Atomic Physics · Physics 2007-05-23 E. Peik , B. Lipphardt , H. Schnatz , T. Schneider , Chr. Tamm , S. G. Karshenboim

We have measured the frequency of the $6s^2S_{1/2} - 5d^2D_{3/2}$ electric-quadrupole transition of $^{171}$Yb$^+$ with a relative uncertainty of $1\times 10^{-14}$, $\nu_{Yb}$ = 688 358 979 309 312 Hz $\pm$ 6 Hz. A femtosecond frequency…

We report direct measurements of the frequency ratio of the 642 THz ${}^2S_{1/2} (F=0)$--${}^2F_{7/2} (F=3)$ electric octupole transition in ${}^{171}\mathrm{Yb}^+$ and the 429 THz ${}^1S_0$--${}^3P_0$ transition in ${}^{87}\mathrm{Sr}$. A…

Accurate measurements of different transition frequencies between atomic levels of the electronic and hyperfine structure over time are used to investigate temporal variations of the fine structure constant $\alpha$ and the…

Atomic Physics · Physics 2014-12-01 N. Huntemann , B. Lipphardt , Chr. Tamm , V. Gerginov , S. Weyers , E. Peik

Optical clocks have extremely attractive applications in many fields, including time-frequency metrology, validation of fundamental physical principles, and relativistic geodesy. The 467 nm octupole transition in 171Yb+ ion exhibits…

Atomic Physics · Physics 2025-10-14 Xuanjian Wang , Jian Cao , Hualin Shu , Yi Yuan , Zehao Li , Pengcheng Fang , Qunfeng Chen , Xueren Huang

We experimentally investigate an optical frequency standard based on the $^2S_{1/2} (F=0)\to {}^2F_{7/2} (F=3)$ electric octupole (\textit{E}3) transition of a single trapped $^{171}$Yb$^+$ ion. For the spectroscopy of this strongly…

Atomic and Molecular Clusters · Physics 2016-02-15 N. Huntemann , C. Sanner , B. Lipphardt , Chr. Tamm , E. Peik

We report on the first coherent excitation of the highly forbidden $^2S_{1/2}\rightarrow{}^2F_{7/2}$ electric octupole (E3) transition in a single trapped ${}^{172}$Yb$^+$ ion, an isotope without nuclear spin. Using the transition in…

The frequency ratio of the 1S0(F=1/2)-3P0(F=1/2) clock transition in 171Yb and the 1S0(F=9/2)-3P0(F=9/2) clock transition in 87Sr is measured by an optical-optical direct frequency link between two optical lattice clocks. We determined the…

We report on the observation of the $4f^{14}6s^{2}~^1S_0- 4f^{13}5d6s^{2}(J=2)$ transition at 431 nm in $^{171}$Yb by depleting atoms in a magneto-optical trap formed by the $6s^{2}~^1S_0-6s6p~^3P_1$ intercombination transition. The…

Atomic Physics · Physics 2024-03-26 Akio Kawasaki , Takumi Kobayashi , Akiko Nishiyama , Takehiko Tanabe , Masami Yasuda

Singly-ionized ytterbium, with ultra-narrow optical clock transitions at 467 nm and 436 nm, is a convenient system for the realization of optical atomic clocks and tests of present-day variation of fundamental constants. We present the…

A full evaluation of the uncertainty budget for the ytterbium ion optical clock at the National Physical Laboratory (NPL) was performed on the electric octupole (E3) $^2\mathrm{S}_{1/2}\,\rightarrow\, ^2\mathrm{F}_{7/2}$ transition. The…

Demands from several areas of science and technology have lead to a worldwide search for accurate optical clocks with an uncertainty of 1 part in $10^{18}$, which is $10^{3}$ times more accurate than the present day cesium atomic clocks…

Atomic Physics · Physics 2017-08-23 Chiranjib Sur , K. V. P. Latha , Rajat K. Chaudhuri , B. P. Das , D. Mukherjee

The projected systematic uncertainties of single trapped Ytterbium-ion optical frequency standards are estimated for the quadrupole and octupole transitions which are at wavelengths 435.5 nm and 467 nm, respectively. Finite temperature of…

Atomic Physics · Physics 2014-05-22 N. Batra , S. De , A. Sen Gupta , Sukhjit Singh , Amisha Arora , Bindiya Arora

Frequency shifts of the ^199Hg^+ 5d^10 6s ^2S_1/2 (F=0, M_F=0) to 5d^9 6s^2 ^2D_5/2 (F=2, M_F=0) electric-quadrupole transition at 282 nm due to external fields are calculated, based on a combination of measured atomic parameters and ab…

Atomic Physics · Physics 2007-05-23 W. M. Itano

We describe a measurement of the frequency of the 2S1/2(F = 0) - 2D3/2(F' = 2) transition of 171Yb+ at the wavelength 436 nm (frequency 688 THz), using a single Yb+ ion confined in a Paul trap and two caesium fountains as references. In one…

Atomic Physics · Physics 2014-02-21 Chr. Tamm , N. Huntemann , B. Lipphardt , V. Gerginov , N. Nemitz , M. Kazda , S. Weyers , E. Peik

We experimentally investigate an optical clock based on $^{171}$Yb ($I=1/2$) atoms confined in an optical lattice. We have evaluated all known frequency shifts to the clock transition, including a density-dependent collision shift, with a…

An atom exposed to an electric field will experience Stark shifts of its internal energy levels, proportional to their polarizabilities. In optical frequency metrology, the Stark shift due to background black-body radiation (BBR) modifies…

We explore the potential of the electric quadrupole transitions $7s\,^2S_{1/2}$ - $6d\,^2D_{3/2}$, $6d\,^2D_{5/2}$ in radium isotopes as single-ion optical frequency standards. The frequency shifts of the clock transitions due to external…

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