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We report on TmMnO3 far infrared emissivity and reflectivity spectra from 1910 K to 4 K. At the highest temperature the number of infrared bands is lower than that predicted for centrosymmetric P63/mmc (D6h4) (Z=2) space group due high…

We have carried out temperature-dependent inelastic neutron scattering measurements of YMnO3 over the temperature range 50 - 1303 K, covering both the antiferromagnetic to paramagnetic transition (70 K), as well as the ferroelectric to…

We provide a detailed study of the reflectivity of multiferroic TbMnO_3 for wave numbers from 40 cm^{-1} to 1000 cm^{-1} and temperatures 5 K < T < 300 K. Excitations are studied for polarization directions E || a, the polarization where…

Strongly Correlated Electrons · Physics 2010-01-22 M. Schmidt , Ch. Kant , T. Rudolf , F. Mayr , A. A. Mukhin , A. M. Balbashov , J. Deisenhofer , A. Loidl

We report on far- and mid-infrared reflectivity of NdMnO3 from 4 K to 300K. Two main features are distinguished in the infrared spectra: active phonons in agreement with the expected for orthorhombic D2h 16-Pbnm (Z=4) space group remaining…

We report an investigation of hexagonal Y_(1-x)Eu_xMnO_3 ceramics with x=0, 0.1 and 0.2 using infrared and THz spectroscopies in the temperature range between 5 and 900 K. The temperature dependence of the THz permittivity reveals a kink…

Materials Science · Physics 2012-02-13 V. Goian , S. Kamba , C. Kadlec , D. Nuzhnyy , P. Kuzel , J. Agostinho Moreira , A. Almeida , P. B. Tavares

We report the temperature dependent THz to mid-infrared response of hexagonal-ErMnO3 using absorption, reflectivity, and emissivity techniques from 2 K to 1700 K. At low temperatures, lowest frequency vibrational modes coexist with…

High-frequency dielectric studies of Bi_0.85Nd_0.15FeO_3 ceramics performed betweeen 100 and 900 K reveal hardening of most polar phonons on cooling below antiferroelectric phase transition, which occurs near 600 K. Moreover, a strong THz…

Materials Science · Physics 2011-10-18 V. Goian , S. Kamba , S. Greicius , D. Nuzhnyy , S. Karimi , I. M. Reaney

The lattice dynamics of the $\rm YMnO_3$ magneto-electric compound has been investigated using density functional calculations, both in the ferroelectric and the paraelectric phases. The coherence between the computed and experimental data…

Materials Science · Physics 2012-03-09 Julien Varignon , Sébastien Petit , Marie-Bernadette Lepetit

We have measured near normal incidence far infrared (FIR) reflectivity spectra of a single crystal of TbMnO3 from 10K to 300K in the spectral range of 50 cm$^{-1}$ to 700 cm$^{-1}$. Fifteen transverse optic (TO) and longitudinal optic (LO)…

Materials Science · Physics 2015-05-13 Pradeep Kumar , Surajit Saha , C. R. Serrao , A. K. Sood , C. N. R. Rao

A new effect originating from the crystal-field-excitation - phonon coupling was observed (in the far infrared spectra of a multiferroic PrFe3(BO3)4). The reststrahlen band corresponding to the A2 symmetry nondegenerate phonon mode near 50…

Materials Science · Physics 2014-11-05 K. N. Boldyrev , T. N. Stanislavchuk , A. A. Sirenko , L. N. Bezmaternykh , M. N. Popova

Compressively strained epitaxial (001) EuTiO3 thin films of tetragonal symmetry have been deposited on (001) (LaAlO3)_0.29-(SrAl_{1/2}Ta_{1/2}O3)_0.71 (LSAT) substrates by reactive molecular-beam epitaxy. Enhancement of the Neel temperature…

We report the spectra of magnetically induced electric dipole absorption in Eu$_{0.75}$Y$_{0.25}$MnO$_3$ from temperature dependent far infrared spectroscopy (10-250 cm$^{-1}$). These spectra, which occur only in the $e||a$ polarization,…

Materials Science · Physics 2007-10-23 R. Valdés Aguilar , A. B. Sushkov , C. L. Zhang , Y. J. Choi , S. -W. Cheong , H. D. Drew

Infrared reflectivity spectra of cubic SrMnO$_{3}$ ceramics reveal 18 % stiffening of the lowest-frequency phonon below the antiferromagnetic phase transition occurring at T$_{N}$ = 233 K. Such a large temperature change of the polar phonon…

We report on the high-temperature evolution of far- and mid- infrared reflectivity and emissivity spectra of ambient orthorhombic ErMnO3 from 12 K to sample decomposition above 1800 K. At low temperatures the number of phonons agrees with…

Strongly Correlated Electrons · Physics 2018-11-13 Néstor E. Massa , Leire del Campo , Karsten Holldack , Vinh Ta Phuoc , Patrick Echegut , Paula Kayser , José Antonio Alonso

The temperature dependence of phonon excitations and the presence of spin phonon coupling in polycrystalline Pr2NiMnO6 samples were studied using micro-Raman spectroscopy and magnetometry. Magnetic properties show a single…

Materials Science · Physics 2011-01-17 K. D. Truong , M. P. Singh , S. Jandl , P. Fournier

Spin and lattice dynamics of CaMn7O12 ceramics were investigated using infrared, THz and inelastic neutron scattering (INS) spectroscopies in the temperature range 2 to 590 K, and, at low temperatures, in applied magnetic fields of up to 12…

Hexagonal YMnO$_3$ is well known for the co-occurrence of ferroelectricity and antiferromagnetism at low temperatures. Using temperature-dependent spectroscopic ellipsometry at an $a$-plane oriented single crystal, we show how the…

Materials Science · Physics 2015-03-16 Steffen Richter , Stefan G. Ebbinghaus , Marius Grundmann , Rüdiger Schmidt-Grund

We report on the temperature dependent Raman spectroscopic studies of orthorombic distorted perovskite YCrO3 in the temperature range of 20-300K. Temperature dependence of DC-magnetization measurement under field cooled and zero field…

Materials Science · Physics 2013-09-30 Yogesh Sharma , Satyaprakash Sahoo , W. Perez , Ram S. Katiyar

Polarized infrared reflectivity spectra of a (110)-oriented TbScO3 single crystal plate were measured down to 10 K. The number of observed polar phonons active along the crystallographic c axis at low temperatures is much higher than…

The infrared and Terahertz properties of GdMnO_3 have been investigated as function of temperature and magnetic field, with special emphasis on the phase boundary between the incommensurate and the canted antiferromagnetic structures. The…

Strongly Correlated Electrons · Physics 2007-05-23 A. Pimenov , T. Rudolf , F. Mayr , A. Loidl , A. A. Mukhin , A. M. Balbashov
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