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The Poisson-Boltzmann equation for a strongly charged plate inside a generic charge-asymmetric electrolyte is solved using the method of asymptotic matching. Both near field and far field asymptotic behaviors of the potential are…

Soft Condensed Matter · Physics 2015-06-05 Ming Han , Xiangjun Xing

Bertaut's equivalent electric density idea (E. F. Bertaut, Journal de Physique {\bf 39}, 1331 (1978)) is applied to the case of two dimensional periodic continuous charge density distributions. The following derivation differs from what was…

Materials Science · Physics 2007-05-23 F. Tasnadi

We consider a set of identical mobile point-like charges (counter-ions) confined to a domain with curved hard walls carrying a uniform fixed surface charge density, the system as a whole being electroneutral. Three domain geometries are…

Soft Condensed Matter · Physics 2016-03-24 Ladislav Samaj , E. Trizac

We consider two charged semipermeable membranes, which bound bulk electrolyte solutions and are separated by a thin film of salt-free liquid. Small counter-ions permeate into the gap, which leads to a steric charge separation in the system.…

Soft Condensed Matter · Physics 2016-11-23 Salim R. Maduar , Olga I. Vinogradova

With already demonstrated in previous work the equations that describe the space dependence of the electric potential are determined by the solution of the equation of Poisson-Boltzmann. In this work we consider these solutions for the…

Biological Physics · Physics 2008-09-30 M. A. G. Soares , F. A. O. Cruz , C. M. Cortez

The non-linear Poisson-Boltzmann equation for a circular, uniformly charged platelet, confined together with co- and counter-ions to a cylindrical cell, is solved semi-analytically by transforming it into an integral equation and solving…

Soft Condensed Matter · Physics 2009-10-31 R. J. F. Leote de Carvalho , E. Trizac , J. P Hansen

The properties of ionic solutions between charged surfaces are often studied within the Poisson-Boltzmann framework, by finding the electrostatic potential profile. For example, the osmotic pressure between two charged planar surfaces can…

Soft Condensed Matter · Physics 2022-08-04 Ram M. Adar , David Andelman

We consider equilibrium statistical mechanics of a simplified model for the ideal conductor electrode in an interface contact with a classical semi-infinite electrolyte, modeled by the two-dimensional Coulomb gas of pointlike $\pm$ unit…

Statistical Mechanics · Physics 2009-11-11 L. Samaj , Z. Bajnok

The description of a conducting medium in thermal equilibrium, such as an electrolyte solution or a plasma, involves nonlinear electrostatics, a subject rarely discussed in the standard electricity and magnetism textbooks. We consider in…

Chemical Physics · Physics 2018-08-01 C. G. Gray , P. J. Stiles

Electronic states near a square Fermi surface are mapped onto quantum chains. Using boson-fermion duality on the chains, the bosonic part of the interaction is isolated and diagonalized. These interactions destroy Fermi liquid behavior.…

Condensed Matter · Physics 2009-10-22 A. Luther

The behavior of electrolyte solutions close to a charged surface is studied theoretically. A modified Poisson-Boltzmann equation which takes into account the volume excluded by the ions in addition to the electrostatic interactions is…

Soft Condensed Matter · Physics 2007-05-23 I. Borukhov , D. Andelman , H. Orland

For multispecies ions, we study boundary layer solutions of charge conserving Poisson-Boltzmann (CCPB) equations [50] (with a small parameter \k{o}) over a finite one-dimensional (1D) spatial domain, subjected to Robin type boundary…

Analysis of PDEs · Mathematics 2015-04-28 Chiun-Chang Lee , Hijin Lee , YunKyong Hyon , Tai-Chia Lin , Chun Liu

The linear Boltzmann equation for elastic and/or inelastic scattering is applied to derive the distribution function of a spatially homogeneous system of charged particles spreading in a host medium of two-level atoms and subjected to…

Statistical Mechanics · Physics 2009-11-13 A. Rossani , A. M. Scarfone

A numerical method using implicit surface representations is proposed to solve the linearized Poisson-Boltzmann equations that arise in mathematical models for the electrostatics of molecules in solvent. The proposed method used an implicit…

Numerical Analysis · Mathematics 2018-04-04 Yimin Zhong , Kui Ren , Richard Tsai

Two point charges are placed in a spherical dielectric core-shell embedded in a dielectric environment, one of the charges being located in the core and the other in the shell. The core, shell, and environment are characterized by different…

Classical Physics · Physics 2022-11-22 A. Marin , O. Ianc , T. O. Cheche

In this paper, we consider a semiconducting device with an active zone made of a single-layer material. The associated Poisson equation for the electrostatic potential (to be solved in order to perform self-consistent computations) is…

Numerical Analysis · Mathematics 2023-02-01 Clément Jourdana , Paola Pietra

From a multiple scale analysis, we find an analytic solution of spherical and cylindrical Poisson-Boltzmann theory for both a 1:2 (monovalent co-ions, divalent counter-ions) and a 2:1 (reversed situation) electrolyte. Our approach consists…

Soft Condensed Matter · Physics 2007-05-23 Gabriel Tellez , Emmanuel Trizac

We study the potential and the charge distribution across the interface of a plasma and a dielectric wall. For this purpose, the charge bound to the wall is modelled as a quasi-stationary electron surface layer which satisfies Poisson's…

Plasma Physics · Physics 2015-05-30 Rafael L. Heinisch , Franz X. Bronold , Holger Fehske

Density functional theory is used to describe electrolyte solutions in contact with electrodes of planar or spherical shape. For the electrolyte solutions we consider the so-called civilized model, in which all species present are treated…

Soft Condensed Matter · Physics 2017-04-24 Andreas Reindl , Markus Bier , S. Dietrich

For the structure of the thin electrical double layer~(EDL) and the property related to the EDL capacitance, we analyze boundary layer solutions (corresponding to the electrostatic potential) of a non-local elliptic equation which is a…

Analysis of PDEs · Mathematics 2018-07-31 Chiun-Chang Lee