Related papers: Revisiting the Chlorine Abundance in Diffuse Inter…
We used archival data acquired with the Copernicus satellite to reexamine CO column densities because self-consistent oscillator strengths are now available. Our focus is on lines of sight containing modest amounts of molecular species. Our…
We present a comprehensive examination of interstellar P and Cl abundances based on an analysis of archival spectra acquired with the Space Telescope Imaging Spectrograph of the Hubble Space Telescope and the Far Ultraviolet Spectroscopic…
Cl I is the atomic species most directly coupled to molecular hydrogen due to its chemistry. Its weakest lines are thereby probably the best tracer of optically thick H2 components in diffuse clouds. We report on the empirical determination…
We have revisited the chemistry of chlorine-bearing species in the diffuse interstellar medium with new observations of the HCl$^+$ molecular ion and new astrochemical models. Using the GREAT instrument on board SOFIA, we observed the…
We present high-resolution (FWHM ~ 0.3-1.5 km/s) spectra of interstellar Ca I absorption toward 30 Galactic stars. Comparisons of the column densities of Ca I, Ca II, K I, and other species -- for individual components identified in the…
High quality archival spectra of interstellar absorption from C I toward 9 stars, taken with the Goddard High Resolution Spectrograph on the Hubble Space Telescope, were analyzed. Our sample was supplemented by two sight lines, 23 Ori and…
We report the first detection of chloronium, H$_2$Cl$^+$, in the interstellar medium, using the HIFI instrument aboard the \emph{Herschel} Space Observatory. The $2_{12}-1_{01}$ lines of ortho-H$_2^{35}$Cl$^+$ and ortho-H$_2^{37}$Cl$^+$ are…
Chlorine (Cl) is a chemical element of the group of the halogens and is between the 17th and the 20th most abundant elements in the Solar System. It is thought to be produced from the capture of a proton or neutron by specific alpha-element…
We report the detection of hydrogen chloride, HCl, in diffuse molecular clouds on the line of sight towards the star-forming region W31C (G10.6-0.4). The J = 1-0 lines of the two stable HCl isotopologues, H35Cl and H37Cl, are observed using…
We measured $^{35}$Cl abundances in 52 M giants with metallicities between -0.5 $<$ [Fe/H] $<$ 0.12. Abundances and atmospheric parameters were derived using infrared spectra from CSHELL on the IRTF and from optical echelle spectra. We…
Chlorine and molecular hydrogen are known to be tightly linked together in the cold phase of the local interstellar medium through rapid chemical reactions. We present here the first systematic study of this relation at high redshifts using…
Although they are only minor constituents of the interstellar medium, halogen-containing molecules are of special interest because of their unique thermochemistry. Here, we present a theoretical study of the chemistry of interstellar…
Using the Herschel Space Observatory's Heterodyne Instrument for the Far-Infrared (HIFI), we have observed para-chloronium (H2Cl+) toward six sources in the Galaxy. We detected interstellar chloronium absorption in foreground molecular…
We report additional detections of the chloronium molecular ion, H$_2$Cl$^+$, toward four bright submillimeter continuum sources: G29.96, W49N, W51, and W3(OH). With the use of the HIFI instrument on the Herschel Space Observatory, we…
The chemical composition of diffuse interstellar clouds is not fully established. They host an active chemistry despite their relatively low density and the ubiquitous presence of far-UV radiation. To further explore the chemical…
Using the Plateau de Bure interferometer, we observed the 3mm absorption lines of CN, HCN and HNC from some of the diffuse clouds which lie toward our well-studied sample of compact extragalactic mm-wave continuum sources. The column…
Aims. We study the behaviour of Cl abundance and its ratios with respect to O, S and Ar abundances in a sample of more than 200 spectra of Galactic and extragalactic H ii regions and star-forming galaxies (SFGs) of the local Universe.…
The nature of the Local Interstellar Cloud (LIC) is highly constrained by the combination of in situ heliospheric and line-of-sight data towards nearby stars. We present a new interpretation of the LIC components of the absorption line data…
We derive the chlorine abundances in a sample of nearby planetary nebulae (PNe) and H II regions that have some of the best available spectra. We use a nearly homogeneous procedure to derive the abundance in each object and find that the…
We present three-dimensional astrochemical simulations and synthetic observations of magnetised, turbulent, self-gravitating molecular clouds. We explore various galactic interstellar medium environments, including cosmic-ray ionization…