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Electronic structure calculations using the augmented spherical wave method have been performed for CuRhO2. For this semiconductor crystallizing in the delafossite structure, it is found that the valence band maximum is mainly due to the 4d…

Strongly Correlated Electrons · Physics 2009-09-03 Antoine Maignan , Volker Eyert , Christine Martin , Stefan Kremer , Raymond Fresard , Denis Pelloquin

We report on the physical properties of the series Ce_(1-x)La_xIr_2B_2 (x D 0-0.9), obtained by means of magnetization, heat capacity and electrical resistivity measurements as a function of temperature (down to 0.7 K for the latter two…

Strongly Correlated Electrons · Physics 2015-06-05 K Mukherjee , Kartik K Iyer , E V Sampathkumaran

CuLa$_2$Ge$_2$O$_8$ forms a distorted triangular lattice of quantum spin-1/2 Cu$^{2+}$ ions. A crystal growth method was developed using the traveling-solvent floating zone technique resulting in the synthesis of a large single crystal (4…

Strongly Correlated Electrons · Physics 2026-04-17 S. Thamban , C. Aguilar-Maldonado , S. Chillal , R. Feyerherm , K. Prokeš , A. J. Studer , D. Abou-Ras , K. Karmakar , A. T. M. N. Islam , B. Lake

We report on the quasi-two-dimensional magnetism of the natural mineral diaboleite Pb2Cu(OH)4Cl2 with a tetragonal crystal structure, which is closely related to that of the frustrated spin-1/2 magnet PbVO3. Magnetic susceptibility of…

Materials Science · Physics 2013-02-15 Alexander A. Tsirlin , Oleg Janson , Stefan Lebernegg , Helge Rosner

A model involving competing short-range isotropic Heisenberg interactions is developed to explain the "double-q" magnetic structure of CeAl$_2$. For suitably chosen interactions, terms in the Landau expansion quadratic in the order…

Materials Science · Physics 2009-11-11 A. B. Harris , J. Schweizer

The properties of epitaxial Bi2FeCrO6 thin films, recently synthesized by pulsed laser deposition, have partially confirmed the theoretical predictions (i.e. a magnetic moment of 2 muB per formula unit and a polarization of ~80 microC/cm2…

Materials Science · Physics 2007-10-19 R. Nechache , C. Harnagea , L. Gunawan , L. -P. Carignan , C. Maunders , D. Menard , G. A. Botton , A. Pignolet

CsO2 is a member of the family of alkali superoxides (formula AO2 with A= Na, K, Rb and Cs) that exhibit magnetic behavior arising from open $p$-shell electrons residing on O2- molecules. We use neutron diffraction to solve the crystal and…

Strongly Correlated Electrons · Physics 2023-11-10 R. A. Ewings , M. Reehuis , F. Orlandi , P. Manuel , D. D. Khalyavin , A. S. Gibbs , A. D. Fortes , A. Hoser , A. J. Princep , M. Jansen

Layered delafossite-type compounds and related transition metal dichalcogenides, characterized by their triangular net structures, serve as prototypical systems for exploring the intricate interplay between crystal structure and magnetic…

Materials Science · Physics 2025-02-11 Felix Eder , Catherine Witteveen , Enrico Giannini , Fabian O. von Rohr

We report low temperature specific heat, C, magnetization, M, susceptibility, chi, and electrical resistivity, rho, measurements on high-quality single crystals of the heavy-fermion system YbRh_2(Si_{1-x} Ge_x)_2 (x=0 and 0.05). The undoped…

Strongly Correlated Electrons · Physics 2007-05-23 P. Gegenwart , J. Custers , T. Tayama , K. Tenya , C. Geibel , O. Trovarelli , F. Steglich

We report comprehensive studies of the crystallographic,magnetic, and thermal properties of a spinel-type magnetically frustrated compound, CoAl2O4, and a magnetically diluted system,Co1-xZnxAl2O4. These studies revealed the effects of…

We investigated complex magnetic properties of multifunctional LaCrO3-LaFeO3 system. The magnetic measurements substantiate the presence of competing complex magnetic ordering against temperature, showing paramagnetic to ferrimagnetic…

Strongly Correlated Electrons · Physics 2019-08-20 Brajesh Tiwari , Ambesh Dixit , M. S. Ramachandra Rao

The magnetic structure of the edge sharing cuprate compound Li2CuO2 has been investigated by means of ab initio electronic structure calculations. The first and second neighbor in-chain magnetic interactions are calculated to be -142 K and…

Materials Science · Physics 2007-05-23 Coen de Graaf , Iberio de P. R. Moreira , Francesc Illas , Oscar Iglesias , Amilcar Labarta

Magnetism of a very thin antiferromagnetic (AFM) surface CuO has been investigated with the partially oxidized nanocomposites of Cu-CuCl, ~ 200 nm. The samples are characterized by X-ray diffraction, X-ray photoelectron spectroscopy,…

Materials Science · Physics 2009-11-11 Qi Li , Shi-Wei Zhang , Yan Zhang , Chinping Chen

We report the results of ac and dc magnetization (M) and heat-capacity (C) measurements on the solid solution, Sr$_3$Cu$_{1-x}$Zn$_x$IrO$_6$. While the Zn end member is known to form in a rhombohedral pseudo one-dimensional K$_4$CdCl$_6$…

Strongly Correlated Electrons · Physics 2009-11-07 Asad Niazi , E. V. Sampathkumaran , P. L. Paulose , D. Eckert , A. Handstein , K. -H. Müller

Weak bond disorder disrupts the expected spin-liquid ground-state of the ideal $S$ = 1/2 Heisenberg pyrochlore antiferromagnet. Here we introduce a single crystal study of the structural and magnetic properties of the bond-disordered…

Strongly Correlated Electrons · Physics 2023-07-12 Andrej Kancko , Gerald Giester , Ross H. Colman

We report on a comprehensive characterization of the newly synthesized Cu$^{2+}$-based molecular magnet [Cu(pz)$_2$(2-HOpy)$_2$](PF$_6$)$_2$ (CuPOF), where pz = C$_4$H$_4$N$_2$ and 2-HOpy = C$_5$H$_4$NHO. From a comparison of theoretical…

KCrF3 represents another prototypical orbital-ordered perovskite, where Cr2+ possesses the same electronic configuration of 3d4 as that of strongly Jahn-Teller distorted Mn3+ in many CMR manganites. The crystal and magnetic structures of…

Strongly Correlated Electrons · Physics 2013-09-30 Y. Xiao , Y. Su , H. -F. Li , C. M. N. Kumar , R. Mittal , J. Persson , A. Senyshyn , K. Gross , Th. Brueckel

Electronic band structure calculations using the augmented spherical wave method have been performed for CuCrO2. For this antiferromagnetic (T_N = 24 K) semiconductor crystallizing in the delafossite structure, it is found that the valence…

Realisation of the tetragonal phase of $Cs_2CuCl_4$ is possible using specific crystal growth conditions at a temperature below $281K$. This work deals with the comparison of the magnetic susceptibility and the magnetization of this new…

The magnetism of the double perovskite compounds \SLFCOx\ ($x$ = 0, 1, 2) are contrasted using magnetization, neutron diffraction and electron paramagnetic resonance with the support from density functional theory calculations. \LFCO\ is…