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We propose to create ultracold ground state molecules in an atomic Bose-Einstein condensate by adiabatic crossing of an optical Feshbach resonance. We envision a scheme where the laser intensity and possibly also frequency are linearly…

Quantum Physics · Physics 2007-05-23 Christiane P. Koch Françoise Masnou-Seeuws Ronnie Kosloff

We have demonstrated a new, accessible and economical technique, dubbed photostop, for producing high densities of trappable molecules. Direct measurements are presented of NO molecules produced with a narrow velocity distribution centered…

Chemical Physics · Physics 2013-08-12 Alexandre Trottier , David Carty , Eckart Wrede

We produce SO_2 molecules with a centre of mass velocity near zero using a Stark decelerator. Since the initial kinetic energy of the supersonic SO_2 molecular beam is high, and the removed kinetic energy per stage is small, 326…

Atomic Physics · Physics 2009-11-13 O. Bucicov , M. Nowak , S. Jung , G. Meijer , E. Tiemann , Ch. Lisdat

Several diatomic transition metal oxides, rare-earth metal oxides and fluorides have the unusual property that their bond dissociation energy is larger than their ionization energy. In these molecules, bound levels above the ionization…

Atomic and Molecular Clusters · Physics 2024-06-06 Sascha Schaller , Johannes Seifert , Giacomo Valtolina , André Fielicke , Boris G. Sartakov , Gerard Meijer

Selection of "magic" trapping conditions with ultracold atoms or molecules, where pairs of internal states experience identical trapping potentials, brings substantial benefits to precision measurements and quantum computing schemes.…

Quantum Physics · Physics 2011-01-04 Svetlana Kotochigova , David DeMille

We present a new method for the generation of rotationally and vibrationally state-selected, translationally cold molecular ions in ion traps. Our technique is based on the state-selective threshold photoionization of neutral molecules…

Chemical Physics · Physics 2010-06-30 Xin Tong , Alexander H. Winney , Stefan Willitsch

Cold and ultracold polar molecules with nonzero electronic angular momentum are of great interest for studies in quantum chemistry and control, investigations of novel quantum systems, and precision measurement. However, in mixed electric…

Atomic Physics · Physics 2015-05-30 Benjamin K. Stuhl , Mark Yeo , Brian C. Sawyer , Matt Hummon , Jun Ye

The formation of ultracold metastable RbCs molecules is observed in a double species magneto-optical trap through photoassociation below the ^85Rb(5S_1/2)+^133Cs(6P_3/2) dissociation limit followed by spontaneous emission. The molecules are…

Atomic Physics · Physics 2015-06-03 N. Bouloufa-Maafa , M. Aymar , O. Dulieu , C. Gabbanini

Polar molecules in selected quantum states can be guided, decelerated and trapped using electric fields created by microstructured electrodes on a chip. Here we explore how non-adiabatic transitions between levels in which the molecules are…

We report on the Stark deceleration and electrostatic trapping of $^{14}$NH ($a ^1\Delta$) radicals. In the trap, the molecules are excited on the spin-forbidden $A ^3\Pi \leftarrow a ^1\Delta$ transition and detected via their subsequent…

The electronic energy level structure of yttrium monoxide (YO) provides a long-lived, low-lying $^{2}\Delta$ state ideal for high-precision molecular spectroscopy, narrowline laser cooling at the single photon-recoil limit, and studying…

We report the creation of a confined slow beam of heavy-water (D2O) molecules with a translational temperature around 1 kelvin. This is achieved by filtering slow D2O from a thermal ensemble with inhomogeneous static electric fields…

Chemical Physics · Physics 2009-11-11 T. Rieger , T. Junglen , S. A. Rangwala , G. Rempe , P. W. H. Pinkse , J. Bulthuis

We predict that it is possible to cool rotational, vibrational and translational degrees of freedom of molecules by coupling a molecular dipole transition to an optical cavity. The dynamics is numerically simulated for a realistic set of…

Quantum Physics · Physics 2007-08-13 Giovanna Morigi , Pepijn W. H. Pinkse , Markus Kowalewski , Regina de Vivie-Riedle

Using resonance-enhanced two-photon ionization, we detect ultracold, ground-state RbCs molecules formed via photoassociation in a laser-cooled mixture of 85Rb and 133Cs atoms. We obtain extensive bound-bound excitation spectra of these…

Atomic Physics · Physics 2009-11-10 Andrew J. Kerman , Jeremy M. Sage , Sunil Sainis , Thomas Bergeman , David DeMille

We propose a process to convert ultracold metastable Cs$_2$ molecules in their lowest triplet state into (singlet) ground state molecules in their lowest vibrational levels. Molecules are first pumped into an excited triplet state, and the…

Quantum Physics · Physics 2015-05-20 Nadia Bouloufa , Marin Pichler , Mireille Aymar , Olivier Dulieu

The formation of ultracold molecules via stimulated emission followed by a radiative deexcitation cascade in the presence of a static electric field is investigated. By analyzing the corresponding cross sections, we demonstrate the…

Quantum Physics · Physics 2007-06-06 Rosario González-Férez , Michael Mayle , Peter Schmelcher

We investigate theoretically the application of tailored incoherent far-infrared fields in combination with laser excitation of a single rovibrational transition for rotational cooling of translationally cold polar diatomic molecules. The…

Atomic Physics · Physics 2009-11-10 I. S. Vogelius , L. B. Madsen , M. Drewsen

The methods producing cold molecules from cold atoms tend to leave molecular ensembles with substantial residual internal energy. For instance, Cs2 molecules initially formed via photoassociation of cold Cs atoms are in several vibrational…

We present spectra of ultracold $^7$Li$^{85}$Rb molecules in their electronic ground state formed by spontaneous decay of weakly bound photoassociated molecules. Beginning with atoms in a dual species magneto-optical trap (MOT), weakly…

Atomic Physics · Physics 2014-12-24 John Lorenz , Adeel Altaf , Sourav Dutta , Yong P. Chen , D. S. Elliott

A new type of decelerator is presented where polar neutral molecules are guided and decelerated using the principle of traveling electric potential wells, such that molecules are confined in stable three-dimensional traps throughout. This…

Atomic Physics · Physics 2010-05-24 Andreas Osterwalder , Samuel A. Meek , Georg Hammer , Henrik Haak , Gerard Meijer