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We demonstrate optical cycling and sub-Doppler laser cooling of a cryogenic buffer-gas beam of calcium monohydride (CaH) molecules. We measure vibrational branching ratios for laser cooling transitions for both excited electronic states A…

Atomic Physics · Physics 2022-08-24 S. F. Vázquez-Carson , Q. Sun , J. Dai , D. Mitra , T. Zelevinsky

We report on the direct conversion of laser-cooled 41K and 87Rb atoms into ultracold 41K87Rb molecules in the rovibrational ground state via photoassociation followed by stimulated Raman adiabatic passage. High-resolution spectroscopy based…

Atomic Physics · Physics 2015-05-19 K. Aikawa , D. Akamatsu , M. Hayashi , K. Oasa , J. Kobayashi , P. Naidon , T. Kishimoto , M. Ueda , S. Inouye

Understanding collisions between ultracold molecules is crucial for making stable molecular quantum gases and harnessing their rich internal degrees of freedom for quantum engineering. Transient complexes can strongly influence collisional…

We present a method for producing three-dimensional Bose-Einstein condensates using only laser cooling. The phase transition to condensation is crossed with $2.5 {\times} 10^{4}$ $^{87}\mathrm{Rb}$ atoms at a temperature of $T_{\mathrm{c}}…

Atomic Physics · Physics 2019-05-27 Alban Urvoy , Zachary Vendeiro , Joshua Ramette , Albert Adiyatullin , Vladan Vuletić

Spin crossover molecules have recently emerged as a family of compounds potentially useful for implementing molecular spintronics devices. The calculations of the electronic properties of such molecules is a formidable theoretical challenge…

Materials Science · Physics 2015-06-04 Andrea Droghetti , Dario Alfe' , Stefano Sanvito

We produce Bose-Einstein condensates of 6Li2 molecules in a low power (22 W) crossed optical dipole trap. Fermionic 6Li atoms are collected in a magneto-optical trap from a Zeeman slowed atomic beam, then loaded into the optical dipole trap…

Other Condensed Matter · Physics 2009-11-13 J. Fuchs , G. J. Duffy , G. Veeravalli , P. Dyke , M. Bartenstein , C. J. Vale , P. Hannaford , W. J. Rowlands

We report magneto-optical trapping (MOT) of a polyatomic molecule, calcium monohydroxide (CaOH). The MOT contains $2.0(5)\times 10^4$ CaOH molecules at a peak density of $3.0(8)\times10^{6}$ cm$^{-3}$. CaOH molecules are further sub-Doppler…

We report the realisation of Bose-Einstein condensation (BEC) of metastable helium atoms using an in-vacuum coil magnetic trap and a crossed beam optical dipole trap. A novel quadrupole-Ioffe configuration (QUIC) magnetic trap made from…

Quantum Gases · Physics 2021-05-26 A. H. Abbas , X. Meng , R. S. Patil , J. A. Ross , A. G. Truscott , S. S. Hodgman

We study by computer simulations the coupled rotational and translational dynamics of three important linear diatomic molecules, namely, carbon monoxide (CO), nitric oxide (NO) and cyanide ion (CN-) in water. Translational diffusion of…

Soft Condensed Matter · Physics 2019-01-28 Anjali S Nair , Puja Banerjee , Sarmistha Sarkar , Biman Bagchi

Recently a number of diatomic and polyatomics molecules has been identified as a prospective systems for Doppler/Sisyphus cooling. Doppler/Sisyphus cooling allows to decrease the kinetic energy of molecules down to microkelvin temperatures…

Chemical Physics · Physics 2017-11-22 T. A. Isaev , A. V. Zaitsevskii , E. Eliav

An alternating gradient electric guide provides a way to transport a wide variety of polar molecules, including those in high-field seeking states. We investigate the motion of polar molecules in such a guide by measuring the transmission…

Atomic Physics · Physics 2015-05-13 T. E. Wall , S. Armitage , J. J. Hudson , B. E. Sauer , J. M. Dyne , E. A. Hinds , M. R. Tarbutt

We propose a scheme that allows to coherently extract cold atoms from a reservoir in a deterministic way. The transfer is achieved by means of radiation pulses coupling two atomic states which are object to different trapping conditions. A…

We report the creation of a sample of over 1000 ultracold $^{87}$RbCs molecules in the lowest rovibrational ground state, from an atomic mixture of $^{87}$Rb and Cs, by magnetoassociation on an interspecies Feshbach resonance followed by…

The last few years have seen rapid progress in the application of laser cooling to molecules. In this review, we examine what kinds of molecules can be laser cooled, how to design a suitable cooling scheme, and how the cooling can be…

Atomic Physics · Physics 2021-12-14 N. J. Fitch , M. R. Tarbutt

We investigate single ions of $^{40}Ca^+$ in Paul traps for quantum information processing. Superpositions of the S$_{1/2}$ electronic ground state and the metastable D$_{5/2}$ state are used to implement a qubit. Laser light on the…

We present a protocol to produce a class of non-thermal Fock state mixtures in trapped ions. This class of states features a clear metrological advantage with respect to the ground state, thus overcoming the standard quantum limit without…

Quantum Physics · Physics 2024-03-20 Antonis Delakouras , Daniel Rodríguez , Javier Cerrillo

Control over all internal and external degrees of freedom of molecules at the level of single quantum states will enable a series of fundamental studies in physics and chemistry. In particular, samples of ground-state molecules at ultralow…

We demonstrate that the long-lived bound states (super-molecules) can exist in the dilute limit when we tune the shape of effective potential between polar molecules by an external microwave field. Binding energies, average sizes, and phase…

Quantum Gases · Physics 2012-06-04 S. -J. Huang , Y. -T. Hsu , H. Lee , Y. -C. Chen , A. G. Volosniev , N. T. Zinner , D. -W. Wang

We demonstrate the deceleration of heavy polar molecules in low-field seeking states by combining a cryogenic source and a travelling-wave Stark decelerator. The cryogenic source provides a high intensity beam with low speed and…

Carbon monoxide is a simple molecule present in many astrophysical environments, and collisional excitation rate coefficients due to the dominant collision partners are necessary to accurately predict spectral line intensities and extract…

Astrophysics of Galaxies · Physics 2015-11-17 Kyle M. Walker , L. Song , B. H. Yang , G. C. Groenenboom , A. van der Avoird , N. Balakrishnan , R. C. Forrey , P. C. Stancil
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