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Photoionization of the I$^+$ ion in the energy range of the 4d giant resonance has been studied using our recently developed random-phase approximation with exchange (RPAE) method. Photoionization cross sections for the I$^+$ $4d-\epsilon…

Atomic Physics · Physics 2008-11-18 Zhifan Chen , Alfred Z. Msezane

Triple photoionization of Xe3+, Xe4+ and Xe5+ ions has been studied in the energy range 670-750 eV, including the 3d ionization threshold. The photon-ion merged-beam technique was used at a synchrotron light source to measure the absolute…

Considering the photoionization of Ar@C60, we predict resonant femtosecond decays of both Ar and C60 vacancies through the continua of atom-fullerene hybrid final states. The resulting resonances emerge from the interference between…

Atomic and Molecular Clusters · Physics 2021-06-08 Mohammad H. Javani , Jacob B. Wise , Ruma De , Mohamed E. Madjet , Steven T. Manson , Himadri S. Chakraborty

We concentrate here on photon absorption as well as electron and positron scattering upon endohedrals that consist of a fullerenes shell and an inner atom A. The aim is to understand the effect of fullerene electron shell in formation of…

Atomic and Molecular Clusters · Physics 2018-02-12 M. Ya. Amusia , A. F. Ioffe

The noble-gas atom xenon can bind fluorine atoms and form several stable compounds. We study the electronic structure of the xenon fluorides (XeFn, n = 2,4,6) by calculating their ionization spectra using a Green's function method, which…

Chemical Physics · Physics 2007-05-23 Christian Buth , Robin Santra , Lorenz S. Cederbaum

Li4C60, one of the best representatives of lithium intercalated fullerides, features a novel type of 2D polymerization. Extensive investigations, including laboratory x-ray and synchrotron radiation diffraction, 13C NMR, MAS and Raman…

Materials Science · Physics 2007-05-23 M. Ricco , T. Shiroka , M. Belli , D. Pontiroli , M. Pagliari , G. Ruani , D. Palles , S. Margadonna , M. Tomaselli

We have calculated photoionization cross-section of endohedral atoms A@CN. We took into account the polarizability of the fullerene electron shell CN that modifies the incoming photon beam and the one-electron wave functions of the caged…

Atomic and Molecular Clusters · Physics 2019-03-27 M. Ya. Amusia , L. V. Chernysheva

The creation of superpositions of hole states via single-photon ionization using attosecond extreme-ultraviolet pulses is studied with the time-dependent configuration interaction singles (TDCIS) method. Specifically, the degree of…

Atomic Physics · Physics 2011-02-04 Stefan Pabst , Loren Greenman , Phay J. Ho , David A. Mazziotti , Robin Santra

The photon-ion merged-beams technique has been employed at the new Photon-Ion spectrometer at PETRA III (PIPE) for measuring multiple photoionization of Xe$^{q+}$ (q=1-5) ions. Total ionization cross sections have been obtained on an…

The absolute differential oscillator strengths (DOS's) for the photoabsorption of the Ne, Ar, and Xe atoms encapsulated in the C$_{60}$ have been evaluated using the time-dependent-density-functional-theory, which solves the quantum…

Atomic and Molecular Clusters · Physics 2015-06-11 Zhifan Chen , Alfred Z. Msezane

The nondipole parameters that characterize the angular disribution of the photoelectrons from the 3d subshell of Cs are found to be altered qualitatively by the inclusion of correlation in the form of interchannel coupling between the…

Atomic Physics · Physics 2009-11-10 M. Ya. Amusia , A. S. Baltenkov , L. V. Chernysheva , Z. Felfli , S. T. Manson , A. Z. Msezane

A detailed theoretical analysis of the 1s photoionization of neon is presented. It is found that the most significant many-electron correlation in computing photoionization of inner shells is the rearrangement of the outer shells caused by…

The x-ray absorption near edge structure (XANES), developed in these last 40 years using synchrotron radiation, is a unique tool probing electronic correlations in complex systems via quantum many body final state effects. Multi electron…

Strongly Correlated Electrons · Physics 2017-11-27 Antonio Bianconi

The dependency on the excitation energy of ultrafast multi-photon ionization of xenon by intense, short extreme ultraviolet pulses (XUV) was investigated in the vicinity of the 4$d$ 'giant' resonance using ion time-of-flight spectroscopy.…

Inelastic x-ray scattering (IXS) with very high (meV) energy resolution has become a valuable spectroscopic tool, complementing the well established coherent inelastic neutron scattering (INS) technique for phonon dispersion investigations.…

Strongly Correlated Electrons · Physics 2009-11-07 M. d'Astuto , P. K. Mang , P. Giura , A. Shukla , A. Mirone , M. Krisch , F. Sette , P. Ghigna , M. Braden , M. Greven

The electron-phonon and Coulomb interactions inC$_{60}$, and larger fullerene spheres are analyzed. The coupling between electrons and intramolecular vibrations give corrections $\sim 1 - 10$ meV to the electronic energies for C$_{60}$, and…

Condensed Matter · Physics 2009-10-22 F. Guinea , J. Gonzalez , M. A. H. Vozmediano

A theoretical model is presented describing the confinement-induced resonances observed in the recent loss experiment of Haller et al. [Phys. Rev. Lett. 104, 153203 (2010)]. These resonances originate from possible molecule formation due to…

Atomic Physics · Physics 2013-05-30 Simon Sala , Philipp-Immanuel Schneider , Alejandro Saenz

It was recently discovered that molecular ionization at high x-ray intensity is enhanced, in comparison with that of isolated atoms, through a phenomenon called CREXIM (charge-rearrangement-enhanced x-ray ionization of molecules). X-ray…

Chemical Physics · Physics 2019-07-10 Yajiang Hao , Ludger Inhester , Sang-Kil Son , Robin Santra

We present the main features of the electronic structure of the heavy atoms that is best of all seen in photoionization. We acknowledge how important was and still is investigation of the interaction between low- and high frequency lasers…

Atomic Physics · Physics 2015-06-03 M. Ya. Amusia

Fullerenes have unique physical and chemical properties that are associated with their delocalized conjugated electronic structure. Among them, there is a giant ultra-broadband - and therefore ultrafast - plasmon resonance, which for…