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In this chapter we summarize recent developments in the study of kinetically constrained models (KCMs) as models for glass formers. After recalling the definition of the KCMs which we cover we study the possible occurrence of ergodicity…

Statistical Mechanics · Physics 2010-10-01 Juan P. Garrahan , Peter Sollich , Cristina Toninelli

We study dynamic heterogeneities in a model glass-former whose overlap with a reference configuration is constrained to a fixed value. The system phase-separates into regions of small and large overlap, so that dynamical correlations remain…

Disordered Systems and Neural Networks · Physics 2012-07-19 C. Cammarota , A. Cavagna , I. Giardina , G. Gradenigo , T. S. Grigera , G. Parisi , P. Verrocchio

We study the dynamics of a one-dimensional fluid of orientable hard rectangles with a non-coarse-grained microscopic mechanism of facilitation. The length occupied by a rectangle depends on its orientation, which is coupled to an external…

Disordered Systems and Neural Networks · Physics 2011-12-09 Jeferson J. Arenzon , Deepak Dhar , Ronald Dickman

We present time-dependent dielectric loss data at different frequencies for a variety of glass formers after cooling below the glass temperature. The observed aging dynamics is described using a modified Kohlrausch-Williams-Watts law, which…

Disordered Systems and Neural Networks · Physics 2007-05-23 P. Lunkenheimer , R. Wehn , U. Schneider , A. Loidl

We study supercooled dynamics in quantum hard-sphere liquid using quantum mode-coupling formulation. In the moderate quantum regime, classical cage effects lead to slower dynamics compared to strongly quantum regime, where tunneling…

Statistical Mechanics · Physics 2021-02-03 Ankita Das , Eran Rabani , Kunimasa Miyazaki , Upendra Harbola

We show that the dynamics of kinetically constrained models of glass formers takes place at a first-order coexistence line between active and inactive dynamical phases. We prove this by computing the large-deviation functions of suitable…

Statistical Mechanics · Physics 2009-11-13 J. P. Garrahan , R. L. Jack , V. Lecomte , E. Pitard , K. van Duijvendijk , F. van Wijland

It has been demonstrated recently that supercooled liquids sharing simple structural features (e.g. pair distribution functions) may exhibit strikingly distinct dynamical behavior. Here we show that a more subtle structural feature…

Statistical Mechanics · Physics 2012-06-04 Glen M. Hocky , Thomas E. Markland , David R. Reichman

We use molecular dynamics computer simulations to investigate the relaxation dynamics of a simple model for a colloidal gel at a low volume fraction. We find that due to the presence of the open spanning network this dynamics shows at low…

Soft Condensed Matter · Physics 2015-06-25 E. Del Gado , W. Kob

In these four lectures I describe basic ideas and methods applicable to both classical and quantum systems displaying slow relaxation and non-equilibrium dynamics. The first half of these notes considers classical systems, and the second…

Statistical Mechanics · Physics 2018-05-30 Juan P. Garrahan

Employing wide-angle neutron spin echo spectroscopy, we measured the Q-dependent coherent intermediate scattering function of the prototypical ionic glass former Ca0.4K0.6(NO3)1.4, in the equilibrium and supercooled liquid states beyond the…

A wide range of glassy and disordered materials exhibit complex, non-exponential, structural relaxation (aging). We propose a simple nonlinear rate equation d\delta/dt = a [1-exp (b\delta)], where '\delta' is the normalized deviation of a…

Disordered Systems and Neural Networks · Physics 2012-07-31 Itamar Kolvin , Eran Bouchbinder

Glass-forming liquids are broadly classified as being fragile or strong, depending on the deviation from Arrhenius behavior of their relaxation times. A fragile to strong crossover is observed or inferred in liquids like water and silica,…

Soft Condensed Matter · Physics 2022-04-12 Pallai Das , Srikanth Sastry

We use event driven simulations to analyze glassy dynamics as a function of density and energy dissipation in a two-dimensional bidisperse granular fluid under stationary conditions. Clear signatures of a glass transition are identified,…

Statistical Mechanics · Physics 2011-10-05 Iraj Gholami , Andrea Fiege , Annette Zippelius

When a liquid is cooled below its melting temperature, if crystallization is avoided, it forms a glass. This phenomenon, called glass transition, is characterized by a marked increase of viscosity, about 14 orders of magnitude, in a narrow…

Disordered Systems and Neural Networks · Physics 2008-08-23 Simone Capaccioli , Giancarlo Ruocco , Francesco Zamponi

Kinetic lattice-gas models display fragile glass behavior, in spite of their trivial Gibbs-Boltzmann measure. This suggests that the nature of glass transition might be, at least in some cases, understood in purely kinetic or dynamical…

Statistical Mechanics · Physics 2009-10-31 Mauro Sellitto

Glasses are out-of-equilibrium systems aging under the crystallization threat. During ordinary glass formation, the atomic diffusion slows down rendering its experimental investigation impractically long, to the extent that a timescale…

Disordered Systems and Neural Networks · Physics 2015-08-28 E. A. A. Pogna , C. Rodríguez-Tinoco , G. Cerullo , C. Ferrante , J. Rodríguez-Viejo , T. Scopigno

We identify the pattern of microscopic dynamical relaxation for a two dimensional glass forming liquid. On short timescales, bursts of irreversible particle motion, called cage jumps, aggregate into clusters. On larger time scales, clusters…

Soft Condensed Matter · Physics 2010-10-04 R. Candelier , A. Widmer-Cooper , J. K. Kummerfeld , O. Dauchot , G. Biroli , P. Harrowell , D. R. Reichman

We attempt to give a bird's eye view of the physical mechanisms leading to anomalous relaxation, and the relation of this phenomenon with anomalous diffusion and transport. Whereas in some cases these two notions are indeed deeply related,…

Disordered Systems and Neural Networks · Physics 2007-05-23 Jean-Philippe Bouchaud

We report a molecular dynamics (MD) study of the collective dynamics of a simple monatomic liquid -interacting through a two body potential that mimics that of lithium- across the liquid-glass transition. In the glassy phase we find…

Disordered Systems and Neural Networks · Physics 2009-11-07 T. Scopigno , G. Ruocco , F. Sette , G. Viliani

Optical tweezers setup is often used to probe the motion of individual tracer particle, which promotes the study of relaxation dynamics of a generic process confined in a harmonic potential. We uncover the dependence of ensemble- and…

Statistical Mechanics · Physics 2020-04-15 Xudong Wang , Yao Chen , Weihua Deng