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We use nonequilibrium molecular dynamics simulations to verify recent tube-model predictions that associative polymer networks exhibit broad stretch fluctuations during elongational flow. Simulations further show that these fluctuating…

Soft Condensed Matter · Physics 2025-04-11 Songyue Liu , Thomas C. O'Connor

We employ a first principles, force-level approach to self-consistently construct the anharmonic tube confinement field for entangled fluids of rigid needles and for primitive-path (PP) level chains in two limiting situations where chain…

Soft Condensed Matter · Physics 2016-12-21 Kenneth S. Schweizer , Daniel M. Sussman

We study the dynamics of the phase behavior of a polymer blend in the presence of shear flow. By adopting a two fluid picture and using a generalization of the concept of material derivative, we construct kinetic equations that describe the…

Soft Condensed Matter · Physics 2009-10-30 Tao Sun , Anna C. Balazs , David Jasnow

Linear and weakly nonlinear stability analyses of an externally shear-imposed, gravity-driven falling film over a uniformly heated wavy substrate are studied. The longwave asymptotic expansion technique is utilized to formulate a single…

Fluid Dynamics · Physics 2024-05-22 Md. Mouzakkir Hossain , Sukhendu Ghosh , Harekrushna Behera , G. P. Raja Sekhar

We investigate the flow of a nano-scale incompressible ridge of low-volatility liquid along a "chemical channel": a long, straight, and completely wetting stripe embedded in a planar substrate, and sandwiched between two extended less…

Soft Condensed Matter · Physics 2009-11-11 J. Koplik , T. S. Lo , M. Rauscher , S. Dietrich

In this paper we present a dimensional reduction to obtain a one-dimensional model to analyze localized necking or bulging in a residually stressed circular cylindrical solid. The nonlinear theory of elasticity is first specialized to…

Soft Condensed Matter · Physics 2024-03-20 Yang Liu , Xiang Yu , Luis Dorfmann

Recent step strain experiments in well-entangled polymeric liquids demonstrated a bulk fracture-like phenomenon. We have studied this instability using a modern version of the Doi-Edwards theory for entangled polymers, and we find close…

Fluid Dynamics · Physics 2015-06-04 Okpeafoh S. Agimelen , Peter D. Olmsted

We explore flow of a completely wetting fluid in a funnel, with particular focus on contact line instabilities at the fluid front. While the flow in a funnel may be related to a number of other flow configurations as limiting cases,…

Fluid Dynamics · Physics 2023-06-13 T. -S. Lin , J. A. Dijksman , L. Kondic

In the past twenty years, shear-banding flows have been probed by various techniques, such as rheometry, velocimetry and flow birefringence. In micellar solutions, many of the data collected exhibit unexplained spatio-temporal fluctuations.…

Soft Condensed Matter · Physics 2015-05-30 M. A. Fardin , T. J. Ober , C. Gay , G. Grégoire , G. H. McKinley , S. Lerouge

Constitutive equations are developed for a polymer fluid, which is treated as a permanent network of strands bridged by junctions. The junctions are assumed to slide with respect to their reference positions under loading. Governing…

Materials Science · Physics 2007-05-23 A. D. Drozdov , R. K. Gupta

First results from a high-resolution three-dimensional nonlinear numerical study of the kink oscillation are presented. We show in detail the development of a shear instability in an untwisted line-tied magnetic flux tube. The instability…

Astrophysics · Physics 2009-11-13 J. Terradas , J. Andries , M. Goossens , I. Arregui , R. Oliver , J. L. Ballester

Beneitez et al. (Phys. Rev. Fluids, 8, L101901, 2023) have recently discovered a new linear "polymer diffusive instability" (PDI) in inertialess rectilinear viscoelastic shear flow using the FENE-P model when polymer stress diffusion is…

Fluid Dynamics · Physics 2024-02-19 Miles M. P. Couchman , Miguel Beneitez , Jacob Page , Rich R. Kerswell

Polymers and rod-like colloids (PaRC) adopt a favorable orientation under sufficiently strong flows. However, how the flow kinematics affect the alignment of such nanostructures according to their extensibility remains unclear. By analysing…

As a streak of dye is advected by a chaotic flow, it stretches and folds and becomes indistinguishable from a one-dimensional idealized material line. The variation along a material line of the total stretching experienced by fluid elements…

Chaotic Dynamics · Physics 2009-11-07 Jean-Luc Thiffeault

The non-stretching approximation of polymer rheology simplifies a constitutive equation but fundamentally changes its behavior in fast flows, and the circumstances under which fast flows emerge cannot always be predicted a-priori. In this…

Soft Condensed Matter · Physics 2024-10-25 Vickie Chen , Brandon Wang , Joseph D. Peterson

The phase-ordering kinetics of a bulk uniaxial nematic liquid crystal is addressed using techniques that have been successfully applied to describe ordering in the O(n) model. The method involves constructing an appropriate mapping between…

Condensed Matter · Physics 2009-10-30 Robert A. Wickham

We report on an extensive study of craze formation in glassy polymers. Molecular dynamics simulations of a coarse-grained bead-spring model were employed to investigate the molecular level processes during craze nucleation, widening, and…

Materials Science · Physics 2009-11-10 Joerg Rottler , Mark O. Robbins

In vivo and in vitro systems of cells and extra-cellular matrix (ECM) systems are well known to form ordered patterns of orientationally aligned fibers. Here, we interpret them as active analogs of the (disordered) isotropic to the…

Soft Condensed Matter · Physics 2025-04-11 Haiqian Yang , Ming Guo , L. Mahadevan

When a dilute polymer solution experiences capillary thinning, it forms an almost uniformly cylindrical thread, which we study experimentally. In the last stages of thinning, when polymers have become fully stretched, the filament becomes…

Fluid Dynamics · Physics 2007-09-20 R. Sattler , J. Eggers , C. Wagner

When injected through a contraction, high molecular weight polymer solutions exhibit a sharp increase of apparent viscosity which originates from stretching polymer chains above a critical extension rate. This chain stretching can also…

Fluid Dynamics · Physics 2020-04-22 Sandeep Garrepally , Stephane Jouenne , Peter D. Olmsted , Francois Lequeux