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The addition of enough non-adsorbing polymer to an otherwise stable colloidal suspension gives rise to a variety of phase behavior and kinetic arrest due to the depletion attraction induced between the colloids by the polymers. We report a…

Soft Condensed Matter · Physics 2024-06-19 Sam E Griffiths , Nick Koumakis , Aidan T Brown , Teun Vissers , Patrick B Warren , Wilson C K Poon

Phase diagrams of binary mixtures of oppositely charged colloids are calculated theoretically. The proposed mean-field-like formalism interpolates between the limits of a hard-sphere system at high temperatures and the colloidal crystals…

Soft Condensed Matter · Physics 2011-09-14 Markus Bier , Rene van Roij , Marjolein Dijkstra

We computed the phase-separation behavior and effective interactions of colloid-polymer mixtures in the "protein limit", where the polymer radius of gyration is much larger than the colloid radius. For ideal polymers, the critical colloidal…

Soft Condensed Matter · Physics 2009-11-07 Peter G. Bolhuis , Evert Jan Meijer , Ard A. Louis

We use numerical simulation to examine the possibility of a reversible liquid-liquid transition in supercooled water and related systems. In particular, for two atomistic models of water, we have computed free energies as functions of…

Statistical Mechanics · Physics 2012-05-11 David T. Limmer , David Chandler

The binodals and the non-ergodicity lines of a binary mixture of hard sphere-like particles with large size ratio are computed for studying the interplay between dynamic arrest and phase separation in depletion-driven colloidal mixtures.…

Soft Condensed Matter · Physics 2009-11-13 Ph. Germain , S. Amokrane

Population heterogeneity is ubiquitous among active living systems, but little is known about its role in determining their spatial organization and large-scale dynamics. Combining evidence from synthetic active fluids assembled from…

Soft Condensed Matter · Physics 2023-11-27 Samadarshi Maity , Alexandre Morin

Fluids cooled to the liquid-vapor critical point develop system-spanning fluctuations in density that transform their visual appearance. Despite the rich phenomenology of this critical point, there is not currently an explanation of the…

Statistical Mechanics · Physics 2020-10-09 Moupriya Das , Jason R. Green

Using numerical simulations, we study the non-equilibrium coarsening dynamics of a binary solvent around spherical colloids in the presence of a temperature gradient. The coarsening dynamics following a temperature quench is studied by…

Soft Condensed Matter · Physics 2020-02-20 Moritz Wilke

The influence of size differences, shape, mass and persistent motion on phase separation in binary mixtures has been intensively studied. Here we focus on the exclusive role of diffusivity differences in binary mixtures of equal-sized…

Soft Condensed Matter · Physics 2016-03-04 Simon N. Weber , Christoph A. Weber , Erwin Frey

The liquid-gas transition of an electroneutral mixture of oppositely charged colloids, studied by Monte Carlo simulations, is found in the low temperature -- low density region. The critical temperature shows a non-monotonous behavior as a…

We study the theoretical phase behavior of an asymmetric binary mixture of hard spheres, of which the smaller component is monodisperse and the larger component is polydisperse. The interactions are modelled in terms of the second virial…

Statistical Mechanics · Physics 2019-12-09 Luka Sturtewagen , Erik van der Linden

Thermal fluctuations of a critical system induce long-ranged Casimir forces between objects that couple to the underlying field. For two dimensional (2D) conformal field theories (CFT) we derive an exact result for the Casimir interaction…

Statistical Mechanics · Physics 2014-10-30 G. Bimonte , T. Emig , M. Kardar

We experimentally study the critical properties of the non-equilibrium solid-liquid-like transition that takes place in vibrated granular matter. The critical dynamics is characterized by the coupling of the density field with the…

Statistical Mechanics · Physics 2015-06-23 Gustavo Castillo , Nicolás Mujica , Rodrigo Soto

Based on renormalization group concepts and explicit mean field calculations we study the universal contribution to the effective force and torque acting on an ellipsoidal colloidal particle which is dissolved in a critical fluid and is…

Soft Condensed Matter · Physics 2015-05-13 S. Kondrat , L. Harnau , S. Dietrich

The thermodynamic behavior of a fluid near a vapor-liquid and, hence, asymmetric critical point is discussed within a general ``complete'' scaling theory incorporating pressure mixing in the nonlinear scaling fields as well as corrections…

Statistical Mechanics · Physics 2009-11-07 Young C. Kim , Michael E. Fisher , G. Orkoulas

The behavior of the conductivity and the density of states, as well as the phase relaxation time, of disordered itinerant electrons across a quantum ferromagnetic transition is discussed. It is shown that critical fluctuations lead to…

Statistical Mechanics · Physics 2017-08-23 D. Belitz , S. L. Sessions , T. R. Kirkpatrick , M. T. Mercaldo , R. Narayanan , Thomas Vojta

An exact statistical mechanical derivation is given of the critical Casimir interactions between two defects in a planar lattice-gas Ising model. Each defect is a group of nearest-neighbor spins with modified coupling constants. Such a…

Statistical Mechanics · Physics 2016-11-23 Piotr Nowakowski , Anna Maciołek , Siegfried Dietrich

Demixing of binary fluids subjected to slow temperature ramps shows repeated waves of nucleation which arise as a consequence of the competition between generation of supersaturation by the temperature ramp and relaxation of supersaturation…

Statistical Mechanics · Physics 2012-10-16 Izabella J. Benczik , Jürgen Vollmer

Critical fluctuations in fluids and fluid mixtures yield a nonanalytic asymptotic Ising-like critical thermodynamic behavior in terms of power laws with universal exponents. In polymer solutions, the amplitudes of these power laws depend on…

Soft Condensed Matter · Physics 2022-09-28 Mikhail A. Anisimov , Thomas J. Longo , Jan V. Sengers

We study the effective interaction between two ellipsoidal particles at the interface of two fluid phases which are mediated by thermal fluctuations of the interface. In this system the restriction of the long--ranged interface fluctuations…

Soft Condensed Matter · Physics 2009-05-30 Ehsan Noruzifar , Martin Oettel