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We study a new hypothetical form of solid carbon \csc, with a unit cell which is composed of the \cs \ fullerene cluster and an additional single carbon atom arranged in the zincblende structure. Using {\it ab initio} calculations, we show…

Condensed Matter · Physics 2016-08-31 Linda M. Zeger , Yu-Min Juan , Efthimios Kaxiras , A. Antonelli

The ground state structures of small silicon clusters are determined through exhaustive tight-binding molecular dynamics simulation studies. These simulations revealed that \Si{11} is an icosahedron with one missing cap, \Si{12} is a…

chem-ph · Physics 2016-08-31 Jun Pan , Atul Bahel , Mushti V. Ramakrishna

Three new single-atom-thick silicon-carbon stable systems have been found by using of SCED-LCAO and DFT methods. An important position, named bone position, is proposed in these structures. For SiC and Si1C9 system, the bone positions are…

Materials Science · Physics 2014-08-26 Xiao Yan , Zihua Xin , M. Yu , Jiaojiao Zhang , Mihai Deng , Lijun Tian

A comprehensive study on the relative structural stability of various nanostructures of carbon clusters (including fullerenes, cages, onions, icosahedral clusters, bucky-diamond clusters, spherically bulk terminated clusters, and clusters…

Materials Science · Physics 2008-07-22 Ming Yu , Indira Chaudhuri , C. Leahy , C. S. Jayanthi , S. Y. Wu

Under irradiation, SiC develops damage commonly referred to as black spot defects, which are speculated to be self-interstitial atom clusters. To understand the evolution of these defect clusters and their impacts (e.g., through radiation…

Materials Science · Physics 2017-05-26 Hyunseok Ko , Amy Kaczmarowski , Izabela Szlufarska , Dane Morgan

A structural model for intermediate sized silicon clusters is proposed that is able to generate unique structures without any dangling bonds. This structural model consists of bulk-like core of five atoms surrounded by fullerene-like…

Condensed Matter · Physics 2007-05-23 Jun Pan , Mushti V. Ramakrishna

A structural model for intermediate sized silicon clusters is proposed that is able to generate unique structures without any dangling bonds. This structural model consists of bulk-like core of five atoms surrounded by fullerene-like…

chem-ph · Physics 2009-10-22 Jun Pan , Mushti V. Ramakrishna

Structural studies on the icosahedral quasicrystals in Zn-Mg-Sc, Cu-Ga-Mg-Sc, and Zn-Mg-Ti alloys as well as their corresponding 1/1 cubic approximants, have revealed that these quasicrystals belong to a new structural group similar to…

Materials Science · Physics 2009-11-10 Tsutomu Ishimasa , Yasushi Kaneko , Hiroshi Kaneko

Two-dimensional (2D) group V elemental materials have attracted widespread attention due to their nonzero band gap while displaying high electron mobility. Using first-principles calculations, we propose a series of new elemental bilayers…

Materials Science · Physics 2017-07-19 Xiangru Kong , Linyang Li , Ortwin Leenaerts , Xiong-jun Liu , François M. Peeters

The theoretical formalism of the local density approximation (LDA) to density functional theory (DFT) has been used to study the electronic and geometric structures of SimCn (1<=m, n<=4;n<=m) clusters. An all electron 6-311++G** basis set…

Atomic and Molecular Clusters · Physics 2007-05-23 Prachi Pradhan , Asok K. Ray

We have used density functional perturbation theory to investigate the stiffness of interatomic bonds in small clusters of Si, Sn and Pb. As the number of atoms in a cluster is decreased, there is a marked shortening and stiffening of…

Other Condensed Matter · Physics 2007-05-23 Raghani Pushpa , Umesh Waghmare , Shobhana Narasimhan

The structural optimization and energetics studies of SiC graphitic-like structures have been investigated theoretically in the context of formations of stable graphitic-like layer structures, single- and multi-walled nanotubes using the…

Materials Science · Physics 2013-05-29 Ming Yu , C. S. Jayanthi , S. Y. Wu

The assembly of colloidal cubic diamond is a challenging process since the shape and interaction parameters and the thermodynamic conditions where this structure is stable are elusive. The simultaneous use of shape-anisotropic particles and…

Soft Condensed Matter · Physics 2024-06-12 Susana Marín-Aguilar , Fabrizio Camerin , Marjolein Dijkstra

Fluorescent paramagnetic defects in solids have become attractive systems for quantum information processing in the recent years. One of the leading contenders is the negatively charged nitrogen-vacancy defect in diamond with visible…

Materials Science · Physics 2017-10-10 A. Csóré , H. J. von Bardeleben , J. L. Cantin , A. Gali

We demonstrate a new approach for engineering group IV semiconductor-based quantum photonic structures containing negatively charged silicon-vacancy (SiV$^-$) color centers in diamond as quantum emitters. Hybrid SiC/diamond structures are…

Cohesion mechanism of cubic approximant crystals of newly discovered binary quasicrystals, Cd$_6$M (M=Yb and Ca), are studied theoretically. It is found that stabilization due to alloying is obtained if M is an element with low-lying…

Materials Science · Physics 2009-10-31 Yasushi Ishii , Takeo Fujiwara

The high-temperature ceramic compound Al5C3N with promising application usage belongs to the scarcely studied Al-C-N system. It was originally reported as an ordered compound in the non-centrosymmetric space group P63mc and described as a…

Two-dimensional silicon carbide stands out among 2D materials, primarily due to its notable band gap, unlike its carbon-based counterparts. However, the binary nature and non-layered structure of bulk SiC present challenges in fabricating…

Materials Science · Physics 2024-11-26 Arushi Singh , Vikram Mahamiya , Alok Shukla

We determined the structures of silicon clusters in the 11-14 atom size range using the tight-binding molecular dynamics method. These calculations reveal that \Si{11} is an icosahedron with one missing cap, \Si{12} is a complete…

chem-ph · Physics 2016-08-31 Jun Pan , Atul Bahel , Mushti V. Ramakrishna

We have performed electronic structure calculations to explore the band-gap dependence on polytypes for $sp^3$-bonded semiconducting materials, i.e., SiC, AlN, BN, GaN, Si, and diamond. In this comprehensive study, we have found that…

Materials Science · Physics 2017-04-26 Yu-ichiro Matsushita , Atsushi Oshiyama
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