Related papers: Rovibrational interactions in linear triatomic mol…
The transfer of weakly bound KRb molecules from levels just below the dissociation threshold into the vibrational ground state with shaped laser pulses is studied. Optimal control theory is employed to calculate the pulses. The complexity…
Quantum computers are ideal for solving chemistry problems due to their polynomial scaling with system size in contrast to classical computers which scale exponentially. Until now molecular energy calculations using quantum computing…
A semiclassical approach is used to describe the wobbling and chiral motion in even-even and odd-even nuclei The trial function involved in the variational equation for the quantal action is a coherent state for the SU(2 ) group associated…
The simple, longitudinal, and transverse wobblers are systematically studied within the framework of collective Hamiltonian, where the collective potential and mass parameter included are obtained based on the tilted axis cranking approach.…
In a recent work (Phys.Rev.C84, 044321, 2011) M.J. Ermamatov and P.R. Fraser have studied rotational and vibrational excited states of axially symmetric nuclei within the Bohr Hamiltonian with different mass parameters. However, the energy…
We study the contributions of off-resonant transitions to the dynamics of a system of N multilevel atoms sharing one excitation and interacting with the quantized vector electromagnetic field. The Rotating Wave Approximation significantly…
A general variational approach for computing the rovibrational dynamics of polyatomic molecules in the presence of external electric fields is presented. Highly accurate, full-dimensional variational calculations provide a basis of…
Relativistic nuclear collisions have emerged as a new tool for probing many-body correlations of nucleons in the ground states of atomic nuclei. Here, we investigate the connection between three-nucleon correlations inside nuclei and…
Density functional theory with plane-wave basis sets is widely employed in computational materials science, including applications to isolated molecular systems. However, the inadequate description of electron correlation remains a…
In this work, Rydberg energy levels of the triatomic hydrogen molecule ($\rm{H_3}$) are studied with multichannel quantum-defect theory. We extract the body-frame p-wave quantum defects from highly accurate \emph{ab initio} electronic…
A variational solution procedure is reported for the many-particle no-pair Dirac-Coulomb-Breit Hamiltonian aiming at a parts-per-billion (ppb) convergence of the atomic and molecular energies, described within the fixed nuclei…
We report on the observation of two vibrational series of pure trilobite rubidium Rydberg molecules. They are created via three-photon photoassociation and lie energetically more than 15 GHz below the atomic 22$F$ state of rubidium. In…
The mass-correction functions in the second-order non-adiabatic Hamiltonian are computed for the $^4$He$^+_2$ molecular ion using the variational method, floating explicitly correlated Gaussian functions, and a general…
The experimental evidence for the collective wobbling motion of triaxial nuclei is reviewed. The classification into transverse and longitudinal in the presence of quasiparticle excitations is discussed. The description by means of the…
The best available line list of OH [Brooke et al. (2016)] contains the high-quality line frequencies, yet the line intensities need refinement because the model function used to interpolate the RKR potential and to extrapolate it into the…
We use perturbation theory and bifurcation theory to analyze the dynamical behavior of resonances, associated to a model describing a particle moving within a ring around a celestial object. The central body is modeled as a homogeneous…
The most consistently useful simple model for the study of odd deformed nuclei, the particle-rotor model (strong coupling limit of the core-particle coupling model) has nevertheless been beset by a long-standing problem: It is necessary in…
The computation of the nuclear quantum dynamics of molecules is challenging, requiring both accuracy and efficiency to be applicable to systems of interest. Recently, theories have been developed for employing time-dependent basis functions…
Rovibrational transitions in the hydrogen and antihydrogen molecular ions $H_2^+$ and $\overline{H}_2^-$ offer the possibility of testing Lorentz and CPT symmetry to extremely high precision, in principle attaining $O(10^{-17})$. In this…
A two-dimensional collective Hamiltonian (2DCH) on both azimuth and polar motions in triaxial nuclei is proposed to investigate the chiral and wobbling modes. In the 2DCH, the collective potential and the mass parameters are determined from…