Related papers: Rovibrational interactions in linear triatomic mol…
We analyze nonlinear coupling between individual vibrational quanta for trapped ions. The nonlinear Coulomb interaction causes a Kerr-type Hamiltonian, for which we derive an analytical expression for the coupling constant. In contrast to a…
The non-relativistic three-body Schr\"odinger equation of the heteronuclear molecular ion HD$^+$ is solved in perimetric coordinates using the Lagrange-mesh method. Energies and wave functions of the four lowest vibrational bound or…
One of the most striking findings in the recent high-spin spectroscopy is the discovery of one-phonon, and possibly double-phonon, excitation of the nuclear wobbling rotational bands. In this talk, we first review the properties of observed…
The behavior of the collective rotor in the chiral motion of triaxially deformed nuclei is investigated using the particle rotor model by transforming the wave functions from the $K$-representation to the $R$-representation. After examining…
Data analysis of the next generation effective antineutrino mass measurement experiment KATRIN requires reliable knowledge of systematic corrections. In particular, the width of the daughter molecular ion excitation spectrum rovibrational…
The lowest six rotational bands have been studied in the particle-rotor model with the particle-hole configuration $\pi h^1_{11/2}\otimes\nu h^{-1}_{11/2}$ and different triaxiality parameter $\gamma$. Both constant and spin-dependent…
We present the effective Hamiltonian for an electron-nucleus interaction in non-relativistic limit up to the second order in the inverse nucleon mass. This Hamiltonian takes into account the distortion of electron waves and allows to…
In the construction of diabatic vibronic Hamiltonians for quantum dynamics in the excited-state manifold of molecules, the coupling constants are often extracted solely from information on the excited-state energies. Here, a new protocol is…
We investigate polyatomic ultralong-range Rydberg molecules consisting of three ground state atoms bound to a Rydberg atom via $s$- and $p$-wave interactions. By employing the finite basis set representation of the unperturbed Rydberg…
Vibrational-excitation cross sections of ground electronic state of carbon dioxide molecule by electron-impact through the CO2-(2\Pi) shape resonance is considered in the separation of the normal modes approximation. Resonance curves and…
A relativistic nuclear energy density functional is developed, guided by two important features that establish connections with chiral dynamics and the symmetry breaking pattern of low-energy QCD: a) strong scalar and vector fields related…
In Loop Quantum Cosmology, the quantization of the Hamiltonian constraint involves a regularization procedure which is affected by certain ambiguities. Moreover, different regularizations lead to distinct mathematical formulations and,…
We evaluate, by means of variational calculations, the bound state energy E_B of a pair of charges located on the surface of a cylinder, interacting via Coulomb potential - e^2 / r . The trial wave function involves three variational…
The exact numerical diagonalization of the Hamiltonian of a 2D circular quantum dot is performed for 2, 3, and 4 electrons.The results are compared with those of the perturbation theory.Our numerical results agree reasonably well for small…
We present a quantum algorithm for calculating the vibronic spectrum of a molecule, a useful but classically hard problem in chemistry. We show several advantages over previous quantum approaches: vibrational anharmonicity is naturally…
We introduce specific solutions to the linear harmonic oscillator, named bubbles. They form resonant families of invariant tori of the linear dynamics, with arbitrarily large Sobolev norms. We use these modulated bubbles of energy to…
Full-dimensional (12D) vibrational states of the methanol molecule (CH$_3$OH) have been computed using the GENIUSH-Smolyak approach and the potential energy surface from Qu and Bowman (2013). All vibrational energies are converged better…
Low-energy vibrational excitations associated with the fluctuation of quadrupole deformed shapes are discussed within the frame of state-of-the-art Configuration Interaction calculations, actually performed via the Quasi-particle Vacua…
We use Dirac's constraint dynamics to obtain a Hamiltonian formulation of the relativistic N-body problem in a separable two-body basis in which the particles interact pair-wise through scalar and vector interactions. The resultant N-body…
Molecular dynamics calculations of inelastic collisions of atomic oxygen with molecular nitrogen are known to show orders of magnitude discrepancies with experimental results in the range from room temperature to many thousands of degrees…