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Electronic, magnetic, and dynamical properties of the new superconducting $\beta$-pyrochlore KOs$_2$O$_6$ and related RbOs$_2$O$_6$ and CsOs$_2$O$_6$ compounds are calculated and compared with experiment and contrasted with structurally…

Superconductivity · Physics 2009-11-10 J. Kunes , T. Jeong , W. E. Pickett

The electronic structures of the heavy-fermion superconductor CeRh$_2$As$_2$ with the local inversion symmetry breaking and the reference material LaRh$_2$As$_2$ have been investigated by using experimental optical conductivity…

Strongly Correlated Electrons · Physics 2024-02-28 Shin-ichi Kimura , Jörg Sichelschmidt , Seunghyun Khim

Tungsten trioxide adopts a variety of structures which can be intercalated with charged species to alter the electronic properties, thus forming `tungsten bronzes'. Similar optical effects are observed upon removing oxygen from WO_3,…

Computational Physics · Physics 2009-11-11 B. Ingham , S. C. Hendy , S. V. Chong , J. L. Tallon

Na2IrO3 is an intriguing material for which spin-orbit coupling plays a key role. Theoretical predictions, so far unverified, have been made that the surface of Na2IrO3 should exhibit a clear signature of the quantum spin Hall effect. We…

Strongly Correlated Electrons · Physics 2015-02-04 F. Lupke , S. Manni , S. C. Erwin , I. I. Mazin , P. Gegenwart , M. Wenderoth

The electronic properties of quasi-one-dimensional anatase TiO2 nanostructures, in the form of thin nanowires having (101) and (001) facets, have been systematically investigated using the standard, hybrid density functional and…

Mesoscale and Nanoscale Physics · Physics 2014-07-08 Hatice Unal , Oguz Gulseren , Sinasi Ellialtioglu , Ersen Mete

We describe Na0.67Mn0.625Fe0.25Co0.125O2 (NMFCO), a P2-type sodium-ion battery cathode. Our composition, with significantly less Co than in an earlier study, shows discharge capacity close to 190 mAhg-1 and specific energy density exceeding…

Materials Science · Physics 2024-08-06 William Rexhausen , Christian Parsons , Uma Garg , Deyang Qu , Prasenjit Guptasarma

Thin nanowires of silicon oxide were studied by pseudopotential density functional electronic structure calculations using the generalized gradient approximation. Infinite linear and zigzag Si-O chains were investigated. A wire composed of…

Materials Science · Physics 2009-11-11 G. Bilalbegovic

We investigate the optical conductivity of Sr$_{1-x}$Ca$_x$RuO$_3$ across the ferromagnetic to paramagnetic transition that occurs at $x=0.8$. The thin films were grown by metalorganic aerosol deposition with $0 \leq x \leq 1$ onto…

Strongly Correlated Electrons · Physics 2016-06-09 Diana Geiger , Uwe S. Pracht , Martin Dressel , Jernej Mravlje , Melanie Schneider , Philipp Gegenwart , Marc Scheffler

The study of hexagonal silicon polytypes attracts special attention due to their unique physical properties compared to the traditional cubic phase of Si. Thus, for some hexagonal phases, a significant improvement in the emission properties…

In this work, hybridization of nonmetal nitrogen-doped carbon dots (NCQDs) with ZnO nanorods (NRs) is utilized towards better photocatalytic degradation of rhodamine B under ultraviolet (UV) irradiation. The structural characterization is…

Materials Science · Physics 2021-08-11 Sujoy Kumar Mandal , Sumana Paul , Sujoy Datta , Debnarayan Jana

Silicate frameworks exhibit diverse structural responses under extreme conditions, which are strongly influenced by hydration. Here, we present a comparative high-pressure synchrotron X-ray diffraction study of Na2ZrSi2O7 and its hydrated…

A 59Co NMR study of CoO2, the x=0 end member of AxCoO2 (A = Na, Li...) cobaltates, reveals a metallic ground state, though with clear signs of strong electron correlations: low-energy spin fluctuations develop at wave vectors q different…

Strongly Correlated Electrons · Physics 2009-11-13 C. de Vaulx , M. -H. Julien , C. Berthier , S. Hebert , V. Pralong , A. Maignan

Electronic nematicity in iron pnictide materials is coupled to both the lattice and the conducting electrons, which allows both structural and transport observables to probe nematic fluctuations and the order parameter. Here we combine…

Strongly Correlated Electrons · Physics 2021-11-10 Joshua J Sanchez , Paul Malinowski , Joshua Mutch , Jian Liu , J-W. Kim , Philip J Ryan , Jiun-Haw Chu

Using a density-functional theory plus dynamical mean-field theory methodology, we compute the many-body electronic structure and optical conductivity of NdNiO$_{2}$ under the influence of large scattering rates on the Nd($5d$) bands and…

Strongly Correlated Electrons · Physics 2023-06-14 Harrison LaBollita , Alexander Hampel , Jonathan Karp , Antia S. Botana , Andrew J. Millis

The electronic structure of the nanolaminated transition metal carbide Ti2AlC has been investigated by bulk-sensitive soft x-ray emission spectroscopy. The measured Ti L, C K and Al L emission spectra are compared with calculated spectra…

Materials Science · Physics 2011-12-30 M. Magnuson , O. Wilhelmsson , J. -P. Palmquist , U. Jansson , M. Mattesini , S. Li , R. Ahuja , O. Eriksson

The electronic structures, charge and spin dynamics of the cobalt pnictide compounds ACo2As2 (A=Ba, Sr, Ca) in the paramagnetic state are investigated by using density functional theory combined with dynamical mean-field theory. In contrast…

Strongly Correlated Electrons · Physics 2018-09-25 Huican Mao , Zhiping Yin

The marriage between a two-dimensional layered material (2DLM) and a complex transition metal oxide (TMO) results in a variety of physical and chemical phenomena that would not have been achieved in either material alone. Interesting recent…

Materials Science · Physics 2019-05-09 Kyeong Tae Kang , Jeongmin Park , Dongseok Suh , Woo Seok Choi

LiCrO2 is a 2D triangular antiferromagnet, isostructural with the common battery material LiCoO2 and a well-known Jahn-Teller antiferromagnet NaNiO2. As opposed to the latter, LiCrO2 exibits antiferromagnetic exchange in Cr planes, which…

Materials Science · Physics 2015-06-25 I. I. Mazin

We study the structural and electronic properties of various hafnium sub-oxides HfzO from z = 9 to z = 0.5, by ab initio simulation using Density Functional Theory. The stability of these sub-oxides is studied against monoclinic HfO2. The…

Materials Science · Physics 2015-11-25 Philippe Blaise , Boubacar Traore

In this study, oxygen vacancies and adatoms have been considered on the surface of both hexagonal and triangular ZnO nanowires. Their effect on the electronic structure and optical spectra of the nanowires have been investigated using the…

Strongly Correlated Electrons · Physics 2018-03-01 Veysel Çelik , Ersen Mete