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Many theoretical studies were devoted in the past to ion-specific effects, trying to interpret a large body of experimental evidence, such as surface tension at air/water interfaces and force measurements between charged objects. Although…

Soft Condensed Matter · Physics 2014-04-22 Dan Ben-Yaakov , David Andelman , Rudi Podgornik

Diffusion of symmetric diblock copolymer chains in macroscopically oriented lamellar block copolymers are studied in a molecular dynamics simulation. Results for diffusion constant both parallel $D_\parallel$ and perpendicular $D_\perp$ to…

Soft Condensed Matter · Physics 2008-02-03 Michael Murat , Gary S. Grest , Kurt Kremer

Modeling the dielectric behavior of molecular materials made up of large pi-conjugated molecules is an interesting and complex task. Here we address linear polarizabilities, and the related dielectric constant, of molecular crystals and…

Chemical Physics · Physics 2007-05-23 Francesca Terenziani , Anna Painelli , Zoltan G. Soos

We study the structure and interfacial properties of model athermal mixtures of colloids and excluded volume polymers. The colloid particles are modeled as hard spheres whereas the polymer coils are modeled as chains formed from…

Soft Condensed Matter · Physics 2007-05-23 Pawel Bryk

Block copolymer melts offer a unique template to control the position and alignment of nanoparticles due to their ability to self-assemble into periodic ordered structures. Active Brownian particles are shown to co-assemble with block…

Soft Condensed Matter · Physics 2024-03-14 Javier Diaz , Ignacio Pagonabarraga

The influence of the environment in the thermal equilibrium properties of a bipartite continuous variable quantum system is studied. The problem is treated within a system-plus-reservoir approach. The considered model reproduces the…

Quantum Physics · Physics 2011-07-05 D. M. Valente , A. O. Caldeira

We present computer simulations of a simple bead-spring model for polymer melts with intramolecular barriers. By systematically tuning the strength of the barriers, we investigate their role on the glass transition. Dynamic observables are…

Soft Condensed Matter · Physics 2015-05-14 Marco Bernabei , Angel J. Moreno , Juan Colmenero

We investigate the phase behavior of symmetric AB diblock copolymers confined into a thin film. The film boundaries are parallel, impenetrable and attract the A component of the diblock copolymer. Using a self-consistent field technique…

Statistical Mechanics · Physics 2009-10-31 Thorsten Geisinger , Marcus Mueller , Kurt Binder

Recent demonstrations of inverted thermal activation of charge mobility in polymer field-effect transistors have excited the interest in transport regimes not limited by thermal barriers. However, rationalization of the limiting factors to…

Room temperature ionic liquids are attractive to numerous applications and particularly, to renewable energy devices. As solvent free electrolytes, they demonstrate a paramount connection between the material morphology and Coulombic…

Chemical Physics · Physics 2016-03-15 Nir Gavish , Arik Yochelis

We present a hydrodynamic theory for systems of dipolar active Brownian particles which, in the regime of weak dipolar coupling, predicts the onset of motility-induced phase separation (MIPS), consistent with Brownian dynamics (BD)…

Soft Condensed Matter · Physics 2022-03-29 Elena Sesé-Sansa , Guo-Jun Liao , Demian Levis , Ignacio Pagonabarraga , Sabine H. L. Klapp

Thermodynamic properties of charge-stabilised colloidal suspensions depend sensitively on the effective charge of the macroions, which can be substantially lower than the bare charge in the case of strong counterion-macroion association. A…

Soft Condensed Matter · Physics 2011-06-28 Alan R. Denton

The influence of hydrodynamic interactions on lane formation of oppositely charged driven colloidal suspensions is investigated using Brownian dynamics computer simulations performed on the Rotne-Prager level of the mobility tensor. Two…

Soft Condensed Matter · Physics 2009-11-13 Martin Rex , Hartmut Löwen

The effect of topology on the collapse transition and instantaneous shape of an energy polydisperse polymer (a model heteropolymer) is studied by means of computer simulations. In particular, we consider three different chain topology,…

Soft Condensed Matter · Physics 2022-11-24 Thoudam Vilip Singh , Lenin S. Shagolsem

We present a hybrid quantum-classical simulation of charge-polaron transport in conjugated polymers. The charge, which couples to the angular rotations of the monomers, is modeled via the time-dependent Schr\"odinger equation, while the…

Statistical Mechanics · Physics 2022-01-11 Laszlo Berencei , William Barford , Stephen R. Clark

In sandstorms and thunderclouds, turbulence-induced collisions between solid particles and ice crystals lead to inevitable triboelectrification. The charge segregation is usually size-dependent, with small particles charged negatively and…

Fluid Dynamics · Physics 2023-12-11 Xuan Ruan , Matthew T. Gorman , Rui Ni

We consider the thermodynamics of a uniformly charged polyelectrolyte with harmonic bonds. For such a system there is at high temperatures an approximate scaling of global properties like the end-to-end distance and the interaction energy…

chem-ph · Physics 2016-08-15 Carsten Peterson , Ola Sommelius , Bo Söderberg

We investigate the statistical mechanics of an inhomogeneous Coulomb fluid composed of charged particles with static polarizability. We derive the weak- and the strong-coupling approximations and evaluate the partition function in a planar…

Soft Condensed Matter · Physics 2013-04-22 Vincent Démery , David S. Dean , Rudolf Podgornik

We present the technical details of an experimental method to realize a model system for 2D phase transitions and the glass transition. The system consists of several hundred thousand colloidal super-paramagnetic particles confined by…

Soft Condensed Matter · Physics 2012-10-26 F. Ebert , P. Dillmann , G. Maret , P. Keim

Effect of small additive molecules on the structural relaxation of polymer melts is investigated via molecular dynamics simulations. At a constant external pressure and a fixed number concentration of added molecules, the variation of…

Soft Condensed Matter · Physics 2019-07-30 Elias M. Zirdehi , Fathollah Varnik