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Adsorption of gaseous species, and in particular of hydrogen atoms, on graphene is an important process for the chemistry of this material. At the equilibrium geometry, the H atom is covalently bonded to a carbon that puckers out from the…

Recent transport measurements on thin graphite films grown on SiC show large coherence lengths and anomalous integer quantum Hall effects expected for isolated graphene sheets. This is the case eventhough the layer-substrate epitaxy of…

Graphene layers were created on both C and Si faces of semi-insulating, on-axis, 4H- and 6H-SiC substrates. The process was performed under high vacuum (<10-4 mbar) in a commercial chemical vapor deposition SiC reactor. A method for H2…

Graphene grown by chemical vapor deposition and supported on SiO2 and sapphire substrates was studied following controlled introduction of defects induced by 35 keV carbon ion irradiation. Changes in Raman spectra following fluences ranging…

We present a unique experimental configuration that allows us to determine the interfacial forces on nearly parallel plates made from the thinnest possible mechanical structures, single and few layer graphene membranes. Our approach…

Interaction between adsorbed atoms in graphene is studied using a combination of DFT and the path integral formalism. Our results reveal a complex non-monotonic interaction profile. We show that the strength and sign of the interaction are…

Mesoscale and Nanoscale Physics · Physics 2019-11-27 Keian Noori , Hillol Biswas , Su Ying Quek , Aleksandr Rodin

The interaction between graphene and substrates provides a viable routes to enhance functionality of both materials. Depending on the nature of electronic interaction at the interface, the electron band structure of graphene is strongly…

The combination of the surface science techniques (STM, XPS, ARPES) and density-functional theory calculations was used to study the decoupling of graphene from Ni(111) by oxygen intercalation. The formation of the antiferromagnetic (AFM)…

Materials Science · Physics 2017-05-26 Yuriy Dedkov , Wolfgang Klesse , Andreas Becker , Florian Späth , Christian Papp , Elena Voloshina

Pentacene has been used widely in organic devices, and the interface structure between pentacene and a substrate is known to significantly influence device performances. Here we demonstrate that molecular ordering of pentacene on graphene…

Mesoscale and Nanoscale Physics · Physics 2015-06-19 W. Jung , D. -H. Oh , I. Song , H. -C. Shin , S. J. Ahn , Y. Moon , C. -Y. Park , J. R. Ahn

We study the effects of polarizable substrates such as SiO2 and SiC on the carrier dynamics in graphene. We find that the quasiparticle spectrum acquires a finite broadening due to the long-range interaction with the polar modes at the…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 S. Fratini , F. Guinea

We report a systematic study of the contact resistance present at the interface between a metal (Ti) and graphene layers of different, known thickness. By comparing devices fabricated on 11 graphene flakes we demonstrate that the contact…

Mesoscale and Nanoscale Physics · Physics 2015-05-13 S. Russo , M. F. Craciun , M. Yamamoto , A. F. Morpurgo , S. Tarucha

Graphene has emerged as a promising building block in the modern optics and optoelectronics due to its novel optical and electrical properties. In the mid-infrared and terahertz (THz) regime, graphene behaves like metals and supports…

Optics · Physics 2017-11-15 Shuyuan Xiao , Tao Wang , Xiaoyun Jiang , Xicheng Yan , Le Cheng , Boyun Wang , Chen Xu

Interfacial interactions allow the electronic properties of graphene to be modified, as recently demonstrated by the appearance of satellite Dirac cones in the band structure of graphene on hexagonal boron nitride (hBN) substrates. Ongoing…

Mesoscale and Nanoscale Physics · Physics 2015-10-28 Zhe Wang , Dong-Keun Ki , Hua Chen , Helmuth Berger , Allan H. MacDonald , Alberto F. Morpurgo

Motivated by the recent photochlorination experiment [B. Li et al., ACS Nano 5, 5957 (2011)], we study theoretically the interaction of chlorine with graphene. In previous theoretical studies, covalent binding between chlorine and carbon…

Mesoscale and Nanoscale Physics · Physics 2012-05-03 M. Ijäs , P. Havu , A. Harju

Single layers of carbon dubbed "graphenes", from which graphite is built, have attracted broad interest in the scientific community because of recent exciting experimental results. Graphene is interesting from a fundamental research…

Materials Science · Physics 2008-01-05 Yakov Kopelevich , Pablo Esquinazi

In this paper, we present a theoretical and computational investigations of the atomic scale structure of the heterointerface formed between the (001) surface of $L1_0$-ordered iron palladium (FePd) alloy and graphene (Gr), namely,…

Understanding the reactivity of carbon surfaces is crucial for the development of advanced functional materials. In this study, we systematically investigate the reactivity of graphene surfaces with the Stone-Wales (SW) defect using Density…

Materials Science · Physics 2023-08-11 Aleksandar Z. Jovanović , Ana S. Dobrota , Natalia V. Skorodumova , Igor A. Pašti

Chemisorption of hydrogen on graphene is studied using atomistic simulations with the second generation of reactive empirical bond order Brenner inter-atomic potential. The lowest energy adsorption sites and the most important metastable…

Mesoscale and Nanoscale Physics · Physics 2011-03-15 Abdiravuf A. Dzhurakhalov , Francois M. Peeters

It has been shown that the first C layer on the SiC(0001)(2{\times}2)C surface already exhibits graphene-like electronic structure, with linear pi bands near the Dirac point. Indeed, the (2{\times}2)C reconstruction, with a Si adatom and C…

Mesoscale and Nanoscale Physics · Physics 2015-05-27 F. Hiebel , P. Mallet , J. -Y. Veuillen , L. Magaud

One- and two-layer graphene have recently been shown to feature new physical phenomena such as unconventional quantum Hall effects and prospects of supporting a non-silicon technological platform using epitaxial graphene. While both one-…

Mesoscale and Nanoscale Physics · Physics 2013-05-29 C. P. Puls , N. E. Staley , Y. Liu