Related papers: Molecular photodissociation
The UV photon escape fraction from molecular clouds is a key parameter for understanding the ionization of the Interstellar Medium (ISM), and extragalactic processes, such as cosmic reionization. We present the ionizing photon flux and the…
Processes that break molecular bonds are typically observed with molecules occupying a mixture of quantum states and successfully described with quasiclassical models, while a few studies have explored the distinctly quantum mechanical…
The EUV photoionizing radiation and FUV dissociating radiation from newly born stars photoevaporate their parental neutral cloud, leading to the formation of dense clumps that could eventually form additional stars. We study the effects of…
Vacuum-UV (VUV) photodesorption from water-rich ice mantles coating interstellar grains is known to play an important role in the gas-to-ice ratio in star- and planet-forming regions. Quantitative photodesorption yields from water ice are…
Proplyds are photodissociation region (PDR)-like cometary cocoons around young stars which are thought to originate through photo-evaporation of the central protoplanetary disk by external UV radiation from the nearby OB stars. This letter…
Radiative association and photodissociation rates are calculated for quadrupole transitions of H2. A complete set of bound and unbound states are included in a self-consistent master equation to obtain steady-state concentrations for a…
Energetic processing of interstellar ice mantles and planetary atmospheres via photochemistry is a critical mechanism in the extraterrestrial synthesis of prebiotic molecules. Photochemistry is defined as chemical processes initiated by…
We study ten molecular transitions obtained from an unbiased 3 mm molecular line survey using the IRAM 30 m telescope toward 409 compact dust clumps identified by the APEX Telescope Large Area Survey of the Galaxy (ATLASGAL) to understand…
Stellar atmospheres separate the hot and dense stellar interiors from the emptiness of space. Radiation escapes from the outermost layers of a star, carrying direct physical information. Underneath the atmosphere, the very high opacity…
The hydrogen ionization and dissociation front around an ultraviolet radiation source should merge when the ratio of ionizing photon flux to gas density is sufficiently low and the spectrum is sufficiently hard. This regime is particularly…
The envelopes of AGB stars are irradiated externally by ultraviolet photons; hence, the chemistry is sensitive to the photodissociation of N$_2$ and CO, which are major reservoirs of nitrogen and carbon, respectively. The photodissociation…
Water photodissociation in the 114 - 144 nm UV range forms excited OH which emits at mid-infrared wavelengths via highly excited rotational lines. These lines have only been detected with Spitzer in several proto-planetary disks and shocks.…
We present models for the chemistry in gas moving towards the ionization front of an HII region. When it is far from the ionization front, the gas is highly depleted of elements more massive than helium. However, as it approaches the…
We use UV measurements of interstellar CO towards nearby stars to calculate the density in the diffuse molecular clouds containing the molecules responsible for the observed absorption. Chemical models and recent calculations of the…
We illustrate some of the difficulties that may be encountered when computing photodissociation and radiative association cross sections from the same time-dependent approach based on wavepacket propagation. The total and partial…
Non-thermal photons deriving from radiative transitions among the internal ladder of atoms and molecules are an important source of photons in addition to thermal and stellar sources in many astrophysical environments. In the present work…
We introduce a model description of a diatomic molecule in an optical cavity, with pump and fluorescent fields, and electron and nuclear motion are treated on equal footing and exactly. The model accounts for several optical response…
The aim of this research is to show that the processes of absorption charge-exchange and photo-association in $A+B^{+}$ collisions together with the processes of $AB^{+}$ photo-dissociation in the case of strongly non-symmetric ion-atom…
We study the breakup of $\text{H}_2^+$ exposed to super-intense, femtosecond laser pulses with frequencies greater than that corresponding to the ionization potential. By solving the time-dependent Schr\"odinger equation in an extensive…
Device architectures and dimensions are now at an unimaginable level not thought possible even 10 years ago. The continued downscaling, following the so-called Moore's law, has motivated the development and use of extreme ultraviolet (EUV)…