Related papers: Molecular photodissociation
The process of photon splitting, becomes allowed in the presence of strong magnetic field. We calculate the influence of magnetized plasma on the photon splitting absorption coefficient. We calculate the refraction coefficients and…
Aerosol particles experience significant photophoretic forces at low pressure. Previous work assumed the average particle temperature to be very close to the gas temperature. This might not always be the case. If the particle temperature or…
The HDO/H2O ratio in interstellar gas is often used to draw conclusions on the origin of water in star-forming regions and on Earth. In cold cores and in the outer regions of protoplanetary disks, gas-phase water comes from photodesorption…
Photocatalytic water splitting reaction on TiO2 surface is one of the fundamental issues that bears significant implication in hydrogen energy technology and has been extensively studied. However, the existence of the very first reaction…
CO$_2$ is a major component of the icy mantles surrounding dust grains in planet and star formation regions. Understanding its photodesorption is crucial for explaining gas phase abundances in the coldest environments of the interstellar…
Bose condensed light can form new phases [1] in a dye filled cavity due to the presence of the orientational disorder created by dye molecules which are essentially frozen on the time scale of the photonic thermalization (few ps). At longer…
We study the H2 photodissociation regions around OB stars in primordial gas clouds whose virial temperatures are between a few hundred and a few thousand Kelvin. In such small objects, a single O star can photodissociate a mass equal to…
Wavelength dependent photodesorption rates have been determined using synchrotron radiation, for condensed pure and mixed methanol ice in the 7 -- 14 eV range. The VUV photodesorption of intact methanol molecules from pure methanol ices is…
The decay of photoexcited quantum systems (examples are photodissociation of molecules and autoionization of atoms) can be viewed as a half-collision process (an incoming photon excites the system which subsequently decays by dissociation…
Carbon monoxide is the most abundant molecule after H$_2$ and is important for chemistry in circumstellar envelopes around late-type stars. The size of the envelope is important when modelling low-J transition lines and deriving mass-loss…
Controlling bond breaking is a long-standing goal in molecular physics. Infrared nanocavities are currently being developed for reaching exotic coupling regimes of cavity QED with a few molecules, but it is not well understood how chemical…
Photoevaporation by stellar ionizing radiation is believed to play an important role in the dispersal of disks around young stars. The mass loss model for dust-free disks developed by Hollenbach et al. is currently regarded as a…
Photoionization by high-energy photons creates nonthermal electrons with a broad range of energies that heat and chemically transform the atmospheres of planets. The specifics of the interactions are notably different when the gas is atomic…
Formulas to describe the photoabsorption and the photon scattering by a plasma or a liquid metal are derived in a unified manner with each other. It is shown how the nuclear motion, the free-electron motion and the core-electron behaviour…
The electronic and nuclear dynamics in methanol, following 156~nm photoexcitation, are investigated by combining a detailed analysis of time-resolved photoelectron spectroscopy experiments with electronic structure calculations. The…
The photodesorption of icy grain mantles has been claimed to be responsible for the abundance of gas-phase molecules toward cold regions. Being water a ubiquitous molecule, it is crucial to understand its role in photochemistry and its…
Protoplanetary disks are found around young stars, and represent the embryonic stage of planetary systems. At different phases of their evolution, disks may undergo substantial mass-loss by photoevaporation: energetic photons from the…
Chemical reactions at ultracold temperatures are expected to be dominated by quantum mechanical effects. Although progress towards ultracold chemistry has been made through atomic photoassociation, Feshbach resonances and bimolecular…
Water is the main constituent of interstellar ices, and it plays a key role in the evolution of many regions of the interstellar medium, from molecular clouds to planet-forming disks. In cold regions of the ISM, water is expected to be…
A simple method to control molecular translation with a chemical reaction is demonstrated. Slow NO molecules have been produced by partially canceling the molecular beam velocity of NO$_2$ with the recoil velocity of the NO photofragment.…