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A complete mathematical theory of nonequilibrium thermodynamics of stochastic systems in terms of master equations is presented. As generalizations of isothermal entropy and free energy, two functions of states play central roles: the Gibbs…

Statistical Mechanics · Physics 2010-05-28 Hao Ge , Hong Qian

Constructing a thermodynamic framework for nonequilibrium systems remains a major challenge, as quantities such as temperature and free energy often become ambiguous when inferred solely from steady-state properties. Here we take a…

The excess work required to drive a stochastic system out of thermodynamic equilibrium through a time-dependent external perturbation is directly related to the amount of entropy produced during the driving process, allowing excess work and…

Statistical Mechanics · Physics 2021-03-15 Steven J Large , Jannik Ehrich , David A Sivak

In genuine nonequilibrium systems that undergo continuous driving, the thermodynamic forces are nonconservative, meaning they cannot be described by any free energy potential. Nonetheless, we show that the dynamics of such systems are…

Statistical Mechanics · Physics 2026-04-10 Artemy Kolchinsky , Andreas Dechant , Kohei Yoshimura , Sosuke Ito

In this paper, we show that a nonequilibrium steady state (NESS) exists at late times in open quantum systems with weak nonlinearity by following its nonequilibrium dynamics with a perturbative analysis. Here we consider an oscillator chain…

Quantum Physics · Physics 2020-09-14 Jing Yang , Jen-Tsung Hsiang , Andrew N. Jordan , B. L. Hu

We consider the generic model of a finite-size quantum electron system connected to two (temperature and particle) reservoirs. The quantum open system is driven out of equilibrium by the presence of both a temperature and a chemical…

Statistical Mechanics · Physics 2017-04-04 H. Ness

Periodic driving is used to steer physical systems to unique stationary states or nonequilibrium steady states (NESS), producing enhanced properties inaccessible to non-driven systems. For open quantum systems, characterizing the NESS is…

Quantum Physics · Physics 2026-01-13 Milan Šindelka , David Gelbwaser-Klimovsky

In equilibrium, the fluctuation-dissipation theorem (FDT) expresses the response of an observable to a small perturbation by a correlation function of this variable with another one that is conjugate to the perturbation with respect to…

Statistical Mechanics · Physics 2010-10-13 Udo Seifert , Thomas Speck

Many have speculated whether nonequilibrium systems obey principles of maximum or minimum entropy production. In this work, we use stochastic thermodynamics to derive the condition for the minimum entropy production state (MEPS) for…

Statistical Mechanics · Physics 2025-07-25 Kyle J. Ray , Alexander B. Boyd

How to rigorously define thermodynamic quantities such as heat, work, and internal energy in open quantum systems driven far from equilibrium remains a significant open question in quantum thermodynamics. Heat is a quantity whose…

Mesoscale and Nanoscale Physics · Physics 2023-07-18 Parth Kumar , Charles A. Stafford

Laser technology has developed and accelerated photo-induced nonequilibrium physics from both scientific and engineering viewpoints. The Floquet engineering, i.e., controlling material properties and functionalities by time-periodic drives,…

Statistical Mechanics · Physics 2020-07-07 Tatsuhiko N. Ikeda , Masahiro Sato

A definition of nonequilibrium free energy $\mathcal{F}_{\textsc{s}}$ is proposed for dynamical Gaussian quantum open systems strongly coupled to a heat bath and a formal derivation is provided by way of the generating functional in terms…

Statistical Mechanics · Physics 2021-03-10 Jen-Tsung Hsiang , B. L. Hu

We build a rigorous nonequilibrium thermodynamic description for open chemical reaction networks of elementary reactions. Their dynamics is described by deterministic rate equations satisfying mass action law. Our most general framework…

Statistical Mechanics · Physics 2017-01-13 Riccardo Rao , Massimiliano Esposito

When a quantum system is subject to a thermal gradient it may sustain a steady non-equilibrium heat current, by entering into a so-called non equilibrium steady state (NESS). Here we show that NESS constitute a thermodynamic resource that…

Statistical thermodynamics of small systems shows dramatic differences from normal systems. Parallel to the recently presented steady-state thermodynamic formalism for master equation and Fokker-Planck equation, we show that a…

Mathematical Physics · Physics 2020-04-01 Liangrong Peng , Hong Qian , Liu Hong

We present the stochastic thermodynamics analysis of an open quantum system weakly coupled to multiple reservoirs and driven by a rapidly oscillating external field. The analysis is built on a modified stochastic master equation in the…

Statistical Mechanics · Physics 2015-05-12 Gregory Bulnes Cuetara , Andreas Engel , Massimiliano Esposito

This paper is about nonequilibrium steady states (NESS) of a class of stochastic models in which particles exchange energy with their "local environments" rather than directly with one another. The physical domain of the system can be a…

Mathematical Physics · Physics 2016-03-25 Yao Li , Peter Nandori , Lai-Sang Young

We establish a correspondence between two very general paradigms for systems that persist away from thermal equilibrium. In the first paradigm, a nonequilibrium steady state (NESS) is maintained by applying fixed thermodynamic forces that…

Statistical Mechanics · Physics 2016-05-25 Oren Raz , Yigit Subasi , Christopher Jarzynski

The existence and uniqueness of a steady state for nonequilibrium systems (NESS) is a fundamental subject and a main theme of research in statistical mechanics for decades. For Gaussian systems, such as a chain of harmonic oscillators…

Statistical Mechanics · Physics 2015-10-13 J. -T. Hsiang , B. L. Hu

Chemical processes in closed systems are poorly controllable since they always relax to equilibrium. Living systems avoid this fate and give rise to a much richer diversity of phenomena by operating under nonequilibrium conditions. Recent…

Chemical Physics · Physics 2019-09-11 Emanuele Penocchio , Riccardo Rao , Massimiliano Esposito
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