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We have investigated the effects of ozone treatment on graphene by Raman scattering. Sequential ozone short-exposure cycles resulted in increasing the $p$ doping levels as inferred from the blue shift of the 2$D$ and $G$ peak frequencies,…

Mesoscale and Nanoscale Physics · Physics 2015-05-19 F. Alzina , H. Tao , J. Moser , Y. Garcia , A. Bachtold , C. M. Sotomayor-Torres

An experimental study of Raman scattering in N-layer graphene as a function of the top layer doping is reported. At high doping level, achieved by a CHF_3 plasma treatment, we observe a splitting of the $G$ band in the spectra of bilayer…

Mesoscale and Nanoscale Physics · Physics 2010-03-23 M. Bruna , S. Borini

Raman spectroscopy is a fast, non-destructive means to characterize graphene samples. In particular, the Raman spectra show a significant dependence on doping. While the change in position and width of the G peak can be explained by the…

Materials Science · Physics 2015-05-13 D. M. Basko , S. Piscanec , A. C. Ferrari

We show that the electron-phonon coupling in graphene, in contrast with the non-relativistic two-dimensional electron gas, leads to shifts in the phonon frequencies that are non-trivial functions of the electronic density. These shifts can…

Strongly Correlated Electrons · Physics 2013-05-29 A. H. Castro Neto , Francisco Guinea

We present a new way to tune the electron-phonon coupling (EPC) in graphene by changing the deformation potential with electron/hole doping. We show the EPC for highest optical branch at the high symmetry point K, acquires a strong…

Materials Science · Physics 2011-05-03 Claudio Attaccalite , Ludger Wirtz , Michele Lazzeri , Francesco Mauri , Angel Rubio

We report a comprehensive micro-Raman scattering study of electrochemically-gated graphene field-effect transistors. The geometrical capacitance of the electrochemical top-gates is accurately determined from dual-gated Raman measurements,…

Mesoscale and Nanoscale Physics · Physics 2016-08-08 Guillaume Froehlicher , Stéphane Berciaud

Graphene phonons are measured as a function of electron doping via the addition of potassium adatoms. In the low doping regime, the in-plane carbon G-peak hardens and narrows with increasing doping, analogous to the trend seen in graphene…

Mesoscale and Nanoscale Physics · Physics 2015-03-17 C. A. Howard , M. P. M. Dean , F. Withers

We develop a theory for the electron-phonon interaction effects on the electronic properties of graphene. We analytically calculate the electron self-energy, spectral function and band velocity renormalization due to phonon-mediated…

Materials Science · Physics 2009-11-13 Wang-Kong Tse , S. Das Sarma

Plasmons in two-dimensional electron systems with nonparabolic bands, such as graphene, feature strong dependence on electron-electron interactions. We use a many-body approach to relate plasmon dispersion at long wavelengths to Landau…

Mesoscale and Nanoscale Physics · Physics 2013-12-19 L. S. Levitov , A. V. Shtyk , M. V. Feigelman

We present a detailed calculation of intensities of two-phonon and four-phonon Raman peaks in graphene. Writing the low-energy hamiltonian of the interaction of electrons with the crystal vibrations and the electromagnetic field from pure…

Materials Science · Physics 2009-11-13 D. M. Basko

The experimental Raman spectra of graphene exhibit a few intense two-phonon bands, which are enhanced through double-resonant scattering processes. Though there are many theoretical papers on this topic, none of them predicts the spectra…

Mesoscale and Nanoscale Physics · Physics 2014-12-17 Valentin N. Popov , Philippe Lambin

Following the work in graphene, we report a first-principles study of electron-phonon coupling (EPC) in low-buckled (LB) monolayer silicene and germanene. Despite of the similar honeycomb atomic arrangement and linear band dispersion, the…

Mesoscale and Nanoscale Physics · Physics 2015-06-16 Jia-An Yan , Ryan Stein , David M. Schaefer , Xiao-Qian Wang , M. Y. Chou

We theoretically investigate the double-resonance Raman spectrum of monolayer graphene down to infrared laser excitation energies. By using first-principles density functional theory calculations, we improve upon previous theoretical…

Mesoscale and Nanoscale Physics · Physics 2025-05-21 Lorenzo Graziotto , Francesco Macheda , Thibault Sohier , Matteo Calandra , Francesco Mauri

A Raman study of a back gated bilayer graphene sample is presented. The changes in the Fermi level induced by charge transfer splits the Raman G-band, hardening its higher component and softening the lower one. These two components are…

Mesoscale and Nanoscale Physics · Physics 2008-12-16 L. M. Malard , D. C. Elias , E. S. Alves , M. A. Pimenta

We report phonon renormalisation in bilayer graphene as a function of doping. The Raman G peak stiffens and sharpens for both electron and hole doping, as a result of the non-adiabatic Kohn anomaly at the $\Gamma$ point. The bilayer has two…

Mesoscale and Nanoscale Physics · Physics 2015-05-13 A. Das , B. Chakraborty , S. Piscanec , S. Pisana , A. K. Sood , A. C. Ferrari

Few-layer graphene possesses low-energy carriers which behave as massive fermions, exhibiting intriguing properties in both transport and light scattering experiments. Lowering the excitation energy of resonance Raman spectroscopy down to…

We report on resonance Raman spectroscopy measurements with excitation photon energy down to 1.16 eV on graphene, to study how low-energy carriers interact with lattice vibrations. Thanks to the excitation energy close to the Dirac point at…

The electrical properties of graphene are known to be modified by chemical species that interact with it. We investigate the effect of doping of graphene-based devices by toluene (C6H5CH3). We show that this effect has a complicated…

Materials Science · Physics 2010-10-25 A. A. Kaverzin , S. M. Strawbridge , A. S. Price , F. Withers , A. K. Savchenko , D. W. Horsell

We demonstrate electrochemical top gating of graphene by using a solid polymer electrolyte. This allows to reach much higher electron and hole doping than standard back gating. In-situ Raman measurements monitor the doping. The G peak…

A Fano-like phonon resonance is observed in few-layer (~3) graphene at room temperature using infrared Fourier transform spectroscopy. This Fano resonance is the manifestation of a strong electron-phonon interaction between the discrete…

Mesoscale and Nanoscale Physics · Physics 2013-05-29 Zhihong Liu , Xiaoxiang Lu , Peng Peng , Wei Wu , Steven Pei , Qingkai Yu , Jiming Bao
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