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Interfacial adhesion between graphene and a SiO2 substrate is studied by density functional theory (DFT) with dispersion corrections. The results demonstrate the van der Waals (vdW) interaction as the predominate mechanism for the…

Materials Science · Physics 2015-06-19 Wei Gao , Penghao Xiao , Graeme Henkelman , Kenneth M. Liechti , Rui Huang

We have performed an {\it ab initio} theoretical investigation of graphene sheet adsorbed on amorphous SiO$_2$ surface (G/a-SiO$_2$). We find that graphene adsorbs on the a-SiO$_2$ surface through van der Waals interactions. The…

Materials Science · Physics 2015-05-28 R. H. Miwa , T. M. Schmidt , A. Fazzio

With first-principles DFT calculations, the interaction between graphene and SiO2 surface has been analyzed by constructing the different configurations based on {\alpha}-quartz and cristobalite structures. The single layer graphene can…

Materials Science · Physics 2015-05-28 X. F. Fan , W. T. Zheng , Z. X. Shen , Jer-Lai Kuo

We investigate theoretically the adhesion and electronic properties of graphene on a muscovite mica surface using the density functional theory (DFT) with van der Waals (vdW) interactions taken into account (the vdW-DF approach). We found…

Mesoscale and Nanoscale Physics · Physics 2011-01-25 A. N. Rudenko , F. J. Keil , M. I. Katsnelson , A. I. Lichtenstein

Hydrogenation of graphene on the \alpha-quartz (0001) SiO_2 substrate is studied, considering different surface terminations in order to take into account the amorphic nature of the material. Our ab initio calculations show that the…

Mesoscale and Nanoscale Physics · Physics 2012-01-16 P. Havu , M. Ijäs , A. Harju

Employing density-functional calculations we study single and double graphene layers on Si- and C-terminated 1x1-6H-SiC surfaces. We show that, in contrast to earlier assumptions, the first carbon layer is covalently bonded to the…

Materials Science · Physics 2009-11-13 Alexander Mattausch , Oleg Pankratov

In this paper, we study the morphologic interaction between graphene and Si nanowires on a SiO2 substrate, using molecular mechanics simulations. Two cases are considered: 1) a graphene nanoribbon intercalated by a single Si nanowire on a…

Materials Science · Physics 2011-11-21 Zhao Zhang , Teng Li

Recent atomic force microscopy (AFM) experiments~[ACS Nano {\bf 2014}, 8, 12410-12417] conducted on graphene-coated SiO$_2$ demonstrated that monolayer graphene (G) can effectively screen dispersion van der Waals (vdW) interactions deriving…

Materials Science · Physics 2018-06-13 Alberto Ambrosetti , Pier Luigi Silvestrelli

We analyze the electrostatic interactions between a single graphene layer and a SiO$_2$ susbtrate, and other materials which may exist in its environment. We obtain that the leading effects arise from the polar modes at the SiO$_2$ surface,…

Materials Science · Physics 2009-11-13 J. Sabio , C. Seoanez , S. Fratini , F. Guinea , A. H. Castro Neto , F. Sols

The adsorption of fluorine, chlorine, bromine, and iodine diatomic molecules on graphene has been investigated using density functional theory with taking into account nonlocal correlation effects by means of vdW-DF approach. It is shown…

Mesoscale and Nanoscale Physics · Physics 2010-09-15 A. N. Rudenko , F. J. Keil , M. I. Katsnelson , A. I. Lichtenstein

We present a unique experimental configuration that allows us to determine the interfacial forces on nearly parallel plates made from the thinnest possible mechanical structures, single and few layer graphene membranes. Our approach…

Strain engineering of graphene through interaction with a patterned substrate offers the possibility of tailoring its electronic properties, but will require detailed understanding of how graphene's morphology is determined by the…

Mesoscale and Nanoscale Physics · Physics 2013-05-29 William G. Cullen , Mahito Yamamoto , Kristen M. Burson , Jianhao Chen , Chaun Jang , Liang Li , Michael S. Fuhrer , Ellen D. Williams

We investigate the electronic properties of graphene upon water adsorption and study the influence of the SiO2 substrate in this context using density functional calculations. Perfect suspended graphene is rather insensitive to H2O…

Mesoscale and Nanoscale Physics · Physics 2008-11-26 Tim O. Wehling , Mikhail I. Katsnelson , Alexander I. Lichtenstein

We present a comprehensive first-principles Density Functional Theory (DFT) analyses of the interfacial strength and bonding mechanisms between crystalline and amorphous selenium(Se) with graphene(Gr), a promising duo for energy storage…

Applied Physics · Physics 2021-03-02 Vidushi Sharma , David Mitlin , Dibakar Datta

Using micro-Raman spectroscopy and scanning tunneling microscopy, we study the relationship between structural distortion and electrical hole doping of graphene on a silicon dioxide substrate. The observed upshift of the Raman G band…

Materials Science · Physics 2012-01-23 Sunmin Ryu , Li Liu , Stephane Berciaud , Young-Jun Yu , Haitao Liu , Philip Kim , George W. Flynn , Louis E. Brus

Both single layer Ga2O3 (SLGO) and graphene are attractive due to their respective electronic and mechanical properties such as wide bandgap and high electrical conductivity. Bringing them together by using van der Waals force to form a…

Materials Science · Physics 2022-01-21 Lijie Li

Interfacial interactions allow the electronic properties of graphene to be modified, as recently demonstrated by the appearance of satellite Dirac cones in the band structure of graphene on hexagonal boron nitride (hBN) substrates. Ongoing…

Mesoscale and Nanoscale Physics · Physics 2015-10-28 Zhe Wang , Dong-Keun Ki , Hua Chen , Helmuth Berger , Allan H. MacDonald , Alberto F. Morpurgo

Understanding interfacial interactions in two-dimensional (2D) heterostructures is essential for advancing optoelectronic and quantum technologies. We investigate metal-organic chemical vapor deposition (MOCVD)-grown WSe$_2$ films (one to…

We consider the effect of atomic hydrogen exposure to a system of two undoped sheets of graphene grown near a silica surface (the first adsorbed to the surface and the second freestanding near the surface). In the absence of atomic hydrogen…

Materials Science · Physics 2012-01-26 Mathias Boström , Bo E. Sernelius

Adhesion is a key issue for researchers of various fields, it is therefore of uppermost importance to understand the parameters that are involved. Commonly, only surface parameters are employed to determine the adhesive forces between…

Materials Science · Physics 2012-08-22 Peter Loskill , Hendrik Hähl , Thomas Faidt , Samuel Grandthyll , Frank Müller , Karin Jacobs
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