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We present a combined analytical and numerical investigation to show how an optimal control field can be designed to generate maximum field-free orientation of molecules for three populated rotational states. Based on a model involving pure…

Quantum Physics · Physics 2021-07-28 Qian-Qian Hong , Li-Bao Fan , Chuan-Cun Shu , Niels E. Henriksen

We demonstrate experimentally a method of all-optical selective rotational control in gas mixtures. Using an optical centrifuge - an intense laser pulse whose linear polarization rotates at an accelerated rate, we simultaneously excite two…

Chemical Physics · Physics 2024-06-19 P. Amani , A. A. Milner , V. Milner

We introduce a new scheme for controlling the sense of molecular rotation. By varying the polarization and the delay between two ultrashort laser pulses, we induce unidirectional molecular rotation, thereby forcing the molecules to rotate…

Quantum Physics · Physics 2015-05-13 Sharly Fleischer , Yuri Khodorkovsky , Yehiam Prior , Ilya Sh. Averbukh

The capability to control molecular rotation for field-free orientation, which arranges molecules in specific spatial directions without external fields, is crucial in physics, chemistry, and quantum information science. However,…

Quantum Physics · Physics 2025-12-25 Qian-Qian Hong , Zhe-Jun Zhang , Chuan-Cun Shu , Jun He , Daoyi Dong , Dajun Ding

We show both theoretically and experimentally that the magnetization density accompanying ultrafast excitation of a semiconductor with circular polarized light varies rapidly enough to produce a detectable THz field.

Materials Science · Physics 2007-05-23 F. Nastos , R. W. Newson , J. Hübner , J. E. Sipe , H. M. van Driel

We apply a time-dependent perturbation theory based on unitary transformations combined with averaging techniques, on molecular orientation dynamics by ultrashort pulses. We test the validity and the accuracy of this approach on LiCl…

Quantum Physics · Physics 2007-05-23 D. Sugny , A. Keller , O. Atabek , D. Daems , S. Guérin , H. R. Jauslin

Microscopic understanding of low-frequency molecular motions in liquids has been a longstanding goal in soft-matter science. So far, such low-frequency motions have mostly been accessed indirectly by off-resonant optical pulses. A more…

Soft Condensed Matter · Physics 2017-04-26 Mohsen Sajadi , Martin Wolf , Tobias Kampfrath

Ionization and excitation of water molecules in intense laser pulses is studied theoretically by solving the three-dimensional time-dependent electronic Schr\"odinger equation within the single-active-electron approximation. The possibility…

Atomic Physics · Physics 2011-12-13 Simon Petretti , Alejandro Saenz , Alberto Castro , Piero Decleva

When circularly polarized light is scattered from a rotating target, a rotational Doppler shift (RDS) emerges from an exchange of angular momentum between the spinning object and the electromagnetic field. Here, we used coherently spinning…

A new and efficient method for orientation echo spectroscopy is presented and realized experimentally. The excitation scheme utilizes concerted rotational excitations by both ultrashort terahertz and near-IR pulses and its all-optical…

Chemical Physics · Physics 2022-12-07 Ran Damari , Amit Beer , Sharly Fleischer

We review on the theoretical status of intense laser orientation and alignment. The evolution of the rotational wave packet and its dynamics leading to orientation and alignment is the topic of the present discussion. The major part of the…

Atomic Physics · Physics 2021-04-14 Vijit V. Nautiyal , Sumana Devi , Ashish Tyagi , Bhawna Vidhani , Anjali Maan , Vinod Prasad

We consider optical properties of a gas of molecules that are brought to fast unidirectional spinning by a pulsed laser field. It is shown that a circularly polarized probe light passing through the medium inverts its polarization…

Optics · Physics 2015-06-17 Uri Steinitz , Yehiam Prior , Ilya Sh. Averbukh

We demonstrate that the THz generation in air from a dual-color pulse, composed of the fundamental and second-harmonic waves, can be coherently controlled by field-free molecular alignment. By tuning its time delay to properly match various…

Optics · Physics 2015-05-19 Jian Wu , Yuqi Tong , Min Li , Haifeng Pan , Heping Zeng

We investigate theoretically the ability of an optical centrifuge - a laser pulse whose linear polarization is rotating at an accelerated rate, to control molecular rotation in the regime when the rigid-rotor approximation breaks down due…

Quantum Physics · Physics 2025-12-11 J. M. García-Garrido , V. Milner , C. P. Koch , R. González-Férez

The transition between two distinct mechanisms for the laser-induced field-free orientation of CO molecules is observed via measurements of orientation revival times and subsequent comparison to theoretical calculations. In the first…

We explore the role of laser induced anti-alignment in enhancing molecular orientation. A field-free enhanced orientation via anti-alignment scheme is presented, which combines a linearly polarized femtosecond laser pulse with a half-cycle…

Optics · Physics 2009-11-11 E. Gershnabel , I. Sh. Averbukh , Robert J. Gordon

Using the tilted-pulse-intensity-front scheme, we generate single-cycle terahertz (THz) pulses by optical rectification of femtosecond laser pulses in LiNbO3. In the THz generation setup, the condition that the image of the grating…

Optics · Physics 2015-05-27 H. Hirori , A. Doi , F. Blanchard , K. Tanaka

The spectrum of terahertz (THz) emission in gases via ionizing two-color femtosecond pulses is analyzed by means of a semi-analytic model and finite-difference-time-domain simulations in 1D and 2D geometries. We show that produced THz…

Plasma Physics · Physics 2015-02-20 Eduardo Cabrera-Granado , Yxing Chen , Ihar Babushkin , Luc Bergé , Stefan Skupin

Inducing and controlling the ultrafast molecular rotational dynamics using shaped laser fields is essential in numerous applications. Several approaches exist that allow following the coherent molecular motion in real-time, including…

We demonstrate optical coherent control of the emission direction of THz radiation. Femtosecond laser pulses are used to excite different types of ultrafast photocurrents along different directions in a bulk GaAs sample. The overall…

Optics · Physics 2013-08-06 Heiko Füser , Mark Bieler