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Surface impurities and contamination often seriously degrade the properties of two-dimensional materials such as graphene. To remove contamination, thermal annealing is commonly used. We present a comparative analysis of annealing…

Using ab initio methods, we propose a simple and effective way to substitutionally dope graphene sheets with Boron. The method consists of selectively exposing each side of the graphene sheet to different elements. We first expose one side…

Materials Science · Physics 2009-11-13 Renato B. Pontes , A. Fazzio , Gustavo M. Dalpian

Large holes in graphene membranes were recently shown to heal, either at room temperature during a low energy STEM experiment, or by annealing at high temperatures. However, the details of the healing mechanism remain unclear. We carried…

Mesoscale and Nanoscale Physics · Physics 2016-01-11 Tiago Botari , Ricardo Paupitz , Pedro Alves da Silva Autreto , Douglas S Galvao

We report on a large improvement in the wetting of Al2O3 thin films grown by un-seeded atomic layer deposition on monolayer graphene, without creating point defects. This enhanced wetting is achieved by greatly increasing the nucleation…

Materials Science · Physics 2014-11-14 Bruno Dlubak , Piran R. Kidambi , Robert S. Weatherup , Stephan Hofmann , John Robertson

Density functional calculations are employed to study the molecular dissociation of hydrogen on graphene, the diffusion of chemisorbed atomic species, and the electronic properties of the resulting hydrogen on graphene system. Our results…

Materials Science · Physics 2011-06-03 Hayley McKay , David J. Wales , S. J. Jenkins , J. A. Verges , P. L. de Andres

Uniform single layer graphene was grown on single-crystal Ir films a few nanometers thick which were prepared by pulsed laser deposition on sapphire wafers. These graphene layers have a single crystallographic orientation and a very low…

We report an approach to synthesize high quality graphene by surface segregation and substrate transfer. Graphene was segregated from Ni surface under the ambient pressure by dissolving carbon in Ni at high temperatures followed by cooling…

Materials Science · Physics 2008-12-09 Qingkai Yu , Jie Lian , Sujitra Siriponglert , Hao Li , Yong Chen , Shin-Shem Pei

We discuss the properties of surface plasmons-polaritons in graphene and describe three possible ways of coupling electromagnetic radiation in the terahertz (THz) spectral range to this type of surface waves. (i) the attenuated total…

Mesoscale and Nanoscale Physics · Physics 2013-04-18 Yu. V. Bludov , A. Ferreira , N. M. R. Peres , M. I. Vasilevskiy

The paper presents the first computational experiment on the transformation of a graphene sheet (graphene molecule Cn) into graphane (CH)n of regular chairlike structure. The transformation is considered as stepwise hydrogenation of the…

Materials Science · Physics 2011-12-25 E. F. Sheka , N. A. Popova

A thorough spectroscopic characterisation of two samples of highly hydrogenated monolayer graphene transferred on nickel grids is herein reported. With X ray photoemission spectroscopy on the C 1s core-level, a 100$\%$ $sp^3$ distortion was…

We show that by using an original method, bulk graphite can be bonded onto borosilicate glass or potentially any insulating substrate with ionic conductivity and then cleaved off to leave single or few layer graphene on the substrate,…

Materials Science · Physics 2009-04-06 Abhay Shukla , Rakesh Kumar , Javed Mazher , Adrian Balan

Based on density functional calculations, optimized structures of graphite oxide are found for various coverage by oxygen and hydroxyl groups, as well as their ratio corresponding to the minimum of total energy. The model proposed describes…

Materials Science · Physics 2008-09-05 Danil W. Boukhvalov , Mikhail I. Katsnelson

Graphene - a monolayer of carbon atoms densely packed into a hexagonal lattice - has one of the strongest possible atomic bonds and can be viewed as a robust atomic-scale scaffold, to which other chemical species can be attached without…

This paper reports the synthesis and detailed characterization of graphite thin films produced by thermal decomposition of the (0001) face of a 6H-SiC wafer, demonstrating the successful growth of single crystalline films down to…

We report that graphene films with thickness ranging from 1 to 7 layers can be controllably synthesized on the surface of polycrystalline copper by a chemical vapour deposition method. The number of layers of graphene is controlled…

While crystalline two-dimensional materials have become an experimental reality during the past few years, an amorphous 2-D material has not been reported before. Here, using electron irradiation we create an sp2-hybridized one-atom-thick…

Materials Science · Physics 2011-03-22 J. Kotakoski , A. V. Krasheninnikov , U. Kaiser , J. C. Meyer

Hydrogen isotope separation has been effectively achieved using gaseous H2/D2 filtered through graphene/Nafion composite membranes. Nevertheless, deuteron nearly does not exist in the form of gaseous D2 in nature but in liquid water. Thus,…

We have studied the effect of photoelectrons on defect formation in graphene during extreme ultraviolet (EUV) irradiation. Assuming the major role of these low energy electrons, we have mimicked the process by using low energy primary…

Materials Science · Physics 2014-08-26 A. Gao , C. J. Lee , F. Bijkerk

Due to its extraordinary properties, suspended graphene is a critical element in a wide range of applications. Preparation methods that preserve the unique properties of graphene are therefore in high demand. To date, all protocols for the…

Applied Physics · Physics 2023-11-15 L. Kalkhoff , S. Matschy , A. S. Meyer , L. Lasnig , N. Junker , M. Mittendorff , L. Breuer , M. Schleberger

The morphology of graphene on SiC {0001} surfaces formed in various environments including ultra-high vacuum, 1 atm of argon, and 10^-6 to 10^-4 Torr of disilane is studied by atomic force microscopy, low-energy electron microscopy, and…

Materials Science · Physics 2015-05-30 N. Srivastava , Guowei He , Luxmi , P. C. Mende , R. M. Feenstra , Yugang Sun