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The formation of graphene on the (0001) surface of SiC (the Si-face) is studied by atomic force microscopy, low-energy electron microscopy, and scanning tunneling microscopy/spectroscopy. The graphene forms due to preferential sublimation…

Materials Science · Physics 2023-05-03 Luxmi , N. Srivastava , R. M. Feenstra , P. J. Fisher

Raman spectroscopy is one of the widely used methods in the analysis of various samples including carbon-based materials. This study aimed to identify the number of layers and defects in graphene using micro-Raman spectroscopy. More…

Optics · Physics 2024-03-21 Somayeh Gholipour , Maryam Bahreini , Mohamad Reza Jafarfard

We calculate core-level spectra for pristine and doped free-standing graphene sheets. Instructions for how to perform the calculations are given in detail. Although pristine graphene is not metallic the core-level spectrum presents…

Materials Science · Physics 2015-01-07 Bo E. Sernelius

We present here a method for cleaning intermediate-size (5~50nm) contamination from highly oriented pyrolytic graphite. Electron beam deposition causes a continuous increase of carbonaceous material on graphene and graphite surfaces, which…

Materials Science · Physics 2015-05-20 Ze Liu , Peter. Bøggild , Jia-rui Yang , Yao Cheng , Francois Grey , Yi-lun Liu , Li Wang , Quan-shui Zheng

We observe optical third harmonic generation from graphene and few-layer graphite flakes produced by exfoliation. The emission scales with the cube of the intensity of the incident near-infrared femtosecond pulses and has a wavelength that…

Mesoscale and Nanoscale Physics · Physics 2013-03-20 Nardeep Kumar , Jatinder Kumar , Chris Gerstenkorn , Rui Wang , Hsin-Ying Chiu , Arthur L. Smirl , Hui Zhao

Materials can, in principle, be imaged at the level of individual atoms with aberration corrected transmission electron microscopy. However, such resolution can be attained only with very high electron doses. Consequently, radiation damage…

Materials Science · Physics 2015-06-17 Gerardo Algara-Siller , Simon Kurasch , Mona Sedighi , Ossi Lehtinen , Ute Kaiser

The conversion of multilayer graphenes into sp^3-bonded carbon films on metal surfaces (through hydrogenation or fluorination of the outer surface of the top graphene layer) is indicated through first-principles computations. The main…

Materials Science · Physics 2013-09-13 Dorj Odkhuu , Dongbin Shin , Rodney S. Ruoff , Noejung Park

Graphene oxide can be used as a precursor to graphene but the quality of graphene flakes is highly heterogeneous. Scanning-Raman-Microscopy (SRM) is used to characterize films of graphene derived from flakes of graphene oxide with an almost…

The type and distribution of oxygen functional groups in graphene oxide (GO) and reduced graphene oxide (RGO) remain still a subject of great debate. Local analytic techniques are required to access the chemistry of these materials at a…

Materials Science · Physics 2016-12-13 Anna Tararan , Alberto Zobelli , Ana M. Benito , Wolfgang K. Maser , Odile Stéphan

Microstructure characterization is of great value to understanding nuclear graphite's properties and irradiation behavior. However, graphite is soft and could be easily damaged during sample preparation. A three-step polishing method…

Materials Science · Physics 2021-06-07 Qing Huang , Hui Tang

We demonstrate a simple and effective technique for dispersing pristine (unfunctionalized) graphene at high concentrations in a wide range of organic solvents by use of a stabilizing polymer (polyvinylpyrrolidone, PVP). These…

When it is oxidized, graphite can be easily exfoliated forming graphene oxide (GO). GO is a critical intermediate for massive production of graphene, and it is also an important material with various application potentials. With many…

Materials Science · Physics 2009-12-31 Wenhua Zhang , Vincenzo Carravetta , Zhenyu Li , Yi Luo , Jinlong Yang

A simple solvent exchange method is introduced to prepare high-concentration and surfactant-free graphene liquid dispersion. Natural graphite flakes are first exfoliated into graphene in dimethylformamide (DMF). DMF is then exchanged by…

Materials Science · Physics 2012-05-10 Jiantong Li , Fei Ye , Sam Vaziri , Mamoun Muhammed , Max C. Lemme , Mikael Östling

Despite the recent developments in Graphene Oxide due to its importance as a host precursor of Graphene, the detailed electronic structure and its evolution during the thermal reduction remain largely unknown, hindering its potential…

Materials Science · Physics 2011-08-31 Abhijit Ganguly , Surbhi Sharma , Pagona Papakonstantinou , Jeremy Hamilton

Interfacing graphene with solid-state devices and maintaining it free of contamination is a crucial step towards a functioning device, be it a semiconductor structure or any other device for technological applications. We take advantage of…

Mesoscale and Nanoscale Physics · Physics 2014-08-27 Jean-Nicolas Longchamp , Conrad Escher , Hans-Werner Fink

We have investigated the effect of ambient gas pressure (Argon) used during thermal exfoliation of graphite oxide on the number of graphene sheets in the resulting graphene. The ambience gas Ar pressures used are 80, 25, 1 atmosphere and…

Materials Science · Physics 2013-02-19 Himanshu Raghubanshi , M. Sterlin Leo Hudson , O. N. Srivastava

Graphene is an attractive material for microelectronics applications, given such favourable electrical characteristics as high mobility, high operating frequency, and good stability. If graphene is to be implemented in electronic devices on…

Materials Science · Physics 2019-06-14 B. C. Worley , S. Kim , T. J. Ha , S. Park , R. Haws , P. Rossky , D. Akinwande , A. Dodabalapur

Based on density functional calculations, we demonstrate a significant difference in oxidation patterns between graphene and graphite and the formation of defects after oxidation. Step-by-step modeling demonstrates that oxidation of 80% of…

Materials Science · Physics 2014-11-06 D. W. Boukhvalov

Single layers of carbon dubbed "graphenes", from which graphite is built, have attracted broad interest in the scientific community because of recent exciting experimental results. Graphene is interesting from a fundamental research…

Materials Science · Physics 2008-01-05 Yakov Kopelevich , Pablo Esquinazi

Plasma functionalization of graphene is one of the facile ways to tune its doping level without the need for wet chemicals making graphene photoluminescent. Microscopic corrugations in the two-dimensional structure of bilayer CVD graphene…

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