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The mode-coupling theory of the glass transition predicts the time evolution of the intermediate scattering functions in viscous liquids on the sole basis of the structural information encoded in two-point density correlations. We provide a…

Statistical Mechanics · Physics 2010-10-01 Ludovic Berthier , Gilles Tarjus

The yield stress is a defining feature of amorphous materials which is difficult to analyze theoretically, because it stems from the strongly non-linear response of an arrested solid to an applied deformation. Mode-coupling theory predicts…

Statistical Mechanics · Physics 2013-11-14 Atsushi Ikeda , Ludovic Berthier

Building on the recently derived inhomogeneous mode-coupling theory, we extend the generalised mode-coupling theory of supercooled liquids to inhomogeneous environments. This provides a first-principles-based, systematic and rigorous way of…

Statistical Mechanics · Physics 2023-01-11 Corentin C. L. Laudicina , Chengjie Luo , Kunimasa Miyazaki , Liesbeth M. C. Janssen

We present mode-coupling equations for the description of the slow dynamics observed in supercooled molecular liquids close to the glass transition. The mode-coupling theory (MCT) originally formulated to study the slow relaxation in simple…

Soft Condensed Matter · Physics 2009-10-31 L. Fabbian , A. Latz , R. Schilling , F. Sciortino , P. Tartaglia , C. Theis

For almost thirty years, mode-coupling theory has been the most widely discussed and used but also the most controversial theory of the glass transition. In this paper we briefly review the reasons for both its popularity and its…

Statistical Mechanics · Physics 2016-06-21 Grzegorz Szamel

We present a detailed derivation of a microscopic theory for the glass transition of a liquid enclosed between two parallel walls relying on a mode-coupling approximation. This geometry lacks translational invariance perpendicular to the…

Soft Condensed Matter · Physics 2012-08-16 Simon Lang , Rolf Schilling , Vincent Krakoviack , Thomas Franosch

In this paper we present a detailed analytical study of the phase diagram and of the structural properties of a field theoretic model with a short-range attraction and a competing long-range screened repulsion. We provide a full derivation…

Soft Condensed Matter · Physics 2009-11-13 Marco Tarzia , Antonio Coniglio

We introduce a family of glassy models having a parameter, playing the role of an interaction range, that may be varied continuously to go from a system of particles in d dimensions to a mean-field version of it. The mean-field limit is…

Statistical Mechanics · Physics 2015-05-27 Romain Mari , Jorge Kurchan

We show that a fluid under strong spatially periodic confinement displays a glass transition within mode-coupling theory (MCT) at a much lower density than the corresponding bulk system. We use fluctuating hydrodynamics, with confinement…

Soft Condensed Matter · Physics 2013-03-14 Saroj Kumar Nandi , Sarika Maitra Bhattacharyya , Sriram Ramaswamy

A mode-coupling theory for the motion of a strongly forced probe particle in a dense colloidal suspension is presented. Starting point is the Smoluchowski equation for $N$ bath and a single probe particle. The probe performs Brownian motion…

Soft Condensed Matter · Physics 2015-06-11 Igor Gazuz , Matthias Fuchs

Generalizing the mode-coupling theory for ideal liquid-glass transitions, equations of motion are derived for the correlation functions describing the glassy dynamics of a diatomic probe molecule immersed in a simple glass-forming system.…

Soft Condensed Matter · Physics 2009-10-31 S. -H. Chong , W. Gotze , A. P. Singh

We present an extensive treatment of the generalized mode-coupling theory (GMCT) of the glass transition, which seeks to describe the dynamics of glass-forming liquids using only static structural information as input. This theory amounts…

Statistical Mechanics · Physics 2016-07-05 Liesbeth M. C. Janssen , Peter Mayer , David R. Reichman

We present a theoretical framework for higher-order correlation functions involving multiple times and multiple points in a classical, many-body system. Such higher-order correlation functions have attracted much interest recently in the…

Statistical Mechanics · Physics 2009-11-07 Ramses van Zon , Jeremy Schofield

We discuss the dynamic behavior of a tagged particle close to a classical localization transition in the framework of the mode-coupling theory of the glass transition. Asymptotic results are derived for the order parameter as well as the…

Disordered Systems and Neural Networks · Physics 2011-08-11 S. K. Schnyder , F. Höfling , T. Franosch , Th. Voigtmann

The dynamics of glass formation in monatomic and binary liquids are studied numerically using a microscopic field theory for the evolution of the time-averaged atomic number density. A stochastic framework combining phase field crystal free…

Materials Science · Physics 2015-05-27 Joel Berry , Martin Grant

As one increases the concentration of a colloidal suspension, the system exhibits a dramatic increase in viscosity. Structurally, the system resembles a liquid, yet motions within the suspension are slow enough that it can be considered…

Soft Condensed Matter · Physics 2012-05-22 Gary L. Hunter , Eric R. Weeks

We study the dynamics of a one-component liquid constrained on a spherical substrate, a 2-sphere, and investigate how the mode-coupling theory (MCT) can describe the new features brought by the presence of curvature. To this end we have…

Soft Condensed Matter · Physics 2015-09-30 Julien-Piera Vest , Gilles Tarjus , Pascal Viot

Using computer simulations, we identify the mechanisms causing aggregation and structural arrest of colloidal suspensions interacting with a short-ranged attraction at moderate and high densities. Two different non-ergodicity transitions…

Condensed Matter · Physics 2009-11-07 Antonio M. Puertas , Matthias Fuchs , Michael E. Cates

Many qualitative observations on the glass transition in classical fluids are well described by the mode coupling theory (MCT) but the extent of the non-ergodicity domain is often over-estimated by this theory. Making it more quantitative…

Statistical Mechanics · Physics 2012-10-04 S. Amokrane , F. Tchangnwa Nya , J. M. Ndjaka

The mode coupling theory (MCT) of glasses, while offering an incomplete description of glass transition physics, represents the only established route to first-principles prediction of rheological behavior in nonergodic materials such as…

Soft Condensed Matter · Physics 2009-09-29 J. M. Brader , Th. Voigtmann , M. Fuchs , R. G. Larson , M. E. Cates