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This article reviews the current state of the art in the field of cold and ultracold molecules and demonstrates that chemical reactions, inelastic collisions and dissociation of molecules at subKelvin temperatures can be manipulated with…

Atomic Physics · Physics 2015-06-26 R. V. Krems

Measurements of interactions between cold molecules and ultracold atoms can allow for a detailed understanding of fundamental collision processes. These measurements can be done using various experimental geometries including where both…

Atomic Physics · Physics 2020-03-25 N. J. Fitch , L. P. Parazzoli , H. J. Lewandowski

We consider collisions of electric and magnetic polar molecules, taking the OH radical as an example, subject to combined electric and magnetic static fields. We show that the relative orientation of the fields has an important effect on…

Atomic Physics · Physics 2013-07-16 Goulven Quéméner , John L. Bohn

It is demonstrated that elastic collisions of ultracold atoms forming a heteronuclear collision complex can be manipulated by laboratory practicable dc electric fields. The mechanism of electric field control is based on the interaction of…

Atomic Physics · Physics 2007-05-23 R. V. Krems

We present a theory for rigorous quantum scattering calculations of probabilities for chemical reactions of atoms with diatomic molecules in the presence of an external electric field. The approach is based on the fully uncoupled basis set…

Atomic Physics · Physics 2012-02-06 T. V. Tscherbul , R. V. Krems

The dipolar collision between ultracold polar molecules is an important topic both by its own right from the fundamental point of view and for the successful exploration of many-body physics with strong and long-range dipolar interactions.…

Ultracold polar molecules offer the possibility of exploring quantum gases with interparticle interactions that are strong, long-range, and spatially anisotropic. This is in stark contrast to the dilute gases of ultracold atoms, which have…

Atomic Physics · Physics 2015-05-18 K. -K. Ni , S. Ospelkaus , D. Wang , G. Quemener , B. Neyenhuis , M. H. G. de Miranda , J. L. Bohn , J. Ye , D. S. Jin

We study ultracold atom-ion collisions in the presence of an external magnetic field. At low collision energy the field can drastically modify the translational motion of the ion, which follows quantized cyclotron orbits. We present a…

Quantum Gases · Physics 2015-05-28 Andrea Simoni , Jean-Michel Launay

In the past two decades, the revolutionary technologies of creating cold and ultracold molecules have provided cutting-edge experiments for studying the fundamental phenomena of collision physics. To a large degree, the recent explosion of…

Atomic Physics · Physics 2022-01-25 Yang Liu , Le Luo

We present a theoretical study of atom - molecule collisions in superimposed electric and magnetic fields and show that dynamics of electronic spin relaxation in molecules at temperatures below 0.5 K can be manipulated by varying the…

Chemical Physics · Physics 2009-11-11 T. V. Tscherbul , R. V. Krems

By means of quantum mechanics and quantum electrodynamics applied to coupled harmonic Drude oscillators, we study the interaction between two neutral atoms or molecules subject to a uniform static electric field. Our focus is to understand…

Chemical Physics · Physics 2022-03-16 Mohammad Reza Karimpour , Dmitry V. Fedorov , Alexandre Tkatchenko

It has recently become possible to form molecules in ultracold gases of trapped alkali metal atoms. Once formed, the molecules may undergo elastic, inelastic and reactive collisions. Inelastic and reactive collisions are particularly…

Atomic Physics · Physics 2010-03-09 Jeremy M. Hutson , Pavel Soldan

Neutron star surfaces and atmospheres are unique environments that sustain the largest-known magnetic fields in the universe. Our knowledge of neutron star material properties, including the composition and equation of state, remains highly…

High Energy Astrophysical Phenomena · Physics 2023-08-24 Thomas Gomez , Mark Zammit , Igor Bray , Christopher Fontes , Jackson White

Recent experiments on ultracold non-reactive dipolar molecules have observed high two-body losses, even though these molecules can undergo neither inelastic, nor reactive (as they are in their absolute ground state), nor light-assisted…

Atomic Physics · Physics 2024-06-21 Goulven Quéméner , James F. E. Croft , John L. Bohn

Scattering or tunneling of an electron at a potential barrier is a fundamental quantum effect. Electron-electron interactions often affect the scattering, and understanding of the interaction effect is crucial in detection of various…

Mesoscale and Nanoscale Physics · Physics 2022-11-10 Sungguen Ryu , H. -S. Sim

The effects of combined external electric and magnetic fields on elastic collisions in ultracold Li--Rb mixtures is studied using recently obtained, experimentally verified potentials. Our analysis provides both quantitative predictions for…

Other Condensed Matter · Physics 2009-09-14 Zhiying Li , Kirk W. Madison

We present a unified formalism for describing chemical reaction rates of trapped, ultracold molecules. This formalism reduces the scattering to its essential features, namely, a propagation of the reactant molecules through a gauntlet of…

Quantum Physics · Physics 2015-05-19 Zbigniew Idziaszek , Goulven Quéméner , John L. Bohn , Paul S. Julienne

We employ various quantum-mechanical approaches for studying the impact of electric fields on both nonretarded and retarded noncovalent interactions between atoms or molecules. To this end, we apply perturbative and non-perturbative methods…

Chemical Physics · Physics 2022-02-03 Mohammad Reza Karimpour , Dmitry V. Fedorov , Alexandre Tkatchenko

We propose a physical mechanism for tuning the atom-atom interaction strength at ultra-low temperatures. In the presence of a dc electric field the interatomic potential is changed due to the effective dipole-dipole interaction between the…

Quantum Physics · Physics 2009-01-23 M. Marinescu , L. You

Collisions between cold molecules are essential for studying fundamental aspects of quantum chemistry, and may enable formation of quantum degenerate molecular matter by evaporative cooling. However, collisions between trapped, naturally…

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