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Quasi-one-dimensional bismuth halides offer an exceptional platform for exploring diverse topological phases, yet the nature of the room-temperature topological phase transition in Bi$_4$I$_4$ remains unresolved. While theory predicts the…

Materials Science · Physics 2025-08-26 Wenjie Hu , Jiayi Gong , Yuhui Qiu , Lexian Yang , Jin-Jian Zhou , Yugui Yao

We have carried out temperature and pressure-dependent Raman and x-ray measurements on single crystals of Tb$_2$Ti$_2$O$_7$. We attribute the observed anomalous temperature dependence of phonons to phonon-phonon anharmonic interactions. The…

We present a comprehensive temperature and polarization dependent inelastic light scattering (Raman) study on single crystals of two-dimensional CuCrP2S6, a layered van der Waals material exhibiting coupled magnetic and electric degrees of…

A new modification of KOs2O6, the representative of a new structural type (Pearson symbol aP18, a=5.5668(1)A, b=6.4519(2)A, c=7.2356(2)A, space group P-1, no.2) was synthesized employing high pressure technique. Its structure was determined…

Superconductivity · Physics 2010-03-03 S. Katrych , Q. F. Gu , Z. Bukowski , N. D. Zhigadlo , G. Krauss , J. Karpinski

We examine the effects of strain and cation substitution on the superconducting phase of polar semiconductors near a ferroelectric quantum phase transition with a model that combines a strong coupling theory of superconductors with a…

Superconductivity · Physics 2018-11-01 J. R. Arce-Gamboa , G. G. Guzmán-Verri

Chemical trends of fundamental superconducting parameters and normal-state properties are described for a family of pyrochlore oxide superconductors. Particularly, the change of Tc from 1.0 K for alpha-pyrochlore Cd2Re2O7 to 3.3 K (A = Cs),…

Superconductivity · Physics 2009-11-11 Zenji Hiroi , Jun-Ichi Yamaura , Shigeki Yonezawa , Hisatomo Harima

We report inelastic neutron scattering measurements over 7-1251 K in CaMnO3 covering various phase transitions, and over 6-150 K in PrMnO3 covering the magnetic transition. The excitations around 20 meV in CaMnO3 and at 17 meV in PrMnO3 are…

Materials Science · Physics 2016-06-29 S. K. Mishra , M. K. Gupta , R. Mittal , A. I. Kolesnikov , S. L. Chaplot

The temperature dependence of phonon excitations and the presence of spin phonon coupling in polycrystalline Pr2NiMnO6 samples were studied using micro-Raman spectroscopy and magnetometry. Magnetic properties show a single…

Materials Science · Physics 2011-01-17 K. D. Truong , M. P. Singh , S. Jandl , P. Fournier

A theoretical study on low-temperature structural phase transitions is presented, in which both phonon-like and relaxation order-parameter dynamics are contemplated. While the first limiting case has been considered previously, the second…

Statistical Mechanics · Physics 2009-11-10 A. Cano , A. P. Levanyuk

We present a study of the superconducting transition in MgB2 using the ab-initio pseudopotential density functional method and the fully anisotropic Eliashberg equation. Our study shows that the anisotropic Eliashberg equation, constructed…

Superconductivity · Physics 2009-02-05 Hyoung Joon Choi , David Roundy , Hong Sun , Marvin L. Cohen , Steven G. Louie

Angle-resolved photoemission spectroscopy with low-energy tunable photons along the nodal direction of oxygen isotope substituted Bi2Sr2CaCu2O8+delta reveals a distinct oxygen isotope shift near the electron-boson coupling "kink" in the…

Using powder neutron diffraction we have discovered an unusual magnetic order-order transition in the Ising spin chain compound Ca3Co2O6. On lowering the temperature an antiferromagnetic phase with propagation vector k=(0.5,-0.5,1) emerges…

Strongly Correlated Electrons · Physics 2011-05-17 S. Agrestini , C. L. Fleck , L. C. Chapon , C. Mazzoli , A. Bombardi , M. R. Lees , O. A. Petrenko

Ab initio investigations of structural, electronic, and dynamical properties of the high-temperature $\beta$ phase of copper pyrophosphate were performed using density functional theory. The electronic band structure shows the Mott…

Our measured dielectric constant and mechanical response of multiferroic BiFeO3 indicate four phase transitions below room temperature. Features correlate with those reported at 50K (from a peak in the zero-field-cooled magnetic…

Materials Science · Physics 2008-06-23 S. A. T. Redfern , C. Wang , J. W. Hong , G. Catalan , J. F. Scott

Na-based osmium oxide pyrochlore was synthesized for the first time by an ion-exchange method. KOs2O6 was used as a host compound. Elelectron probe micro-analysis, synchrotron x-ray diffraction analysis, and thermo-gravimetric analysis…

Strongly Correlated Electrons · Physics 2009-11-13 Y. G. Shi , A. A. Belik , M. Tachibana , M. Tanaka , Y. Katsuya , K. Kobayashi , K. Yamaura , E. Takayama-Muromachi

Multifunctional properties in quantum systems require the interaction between different degrees of freedom. As such, spin-phonon coupling emerges as an ideal mechanism to tune multiferroicity, magnetism, and magnetoelectric response. In…

EuTiO_{3} undergoes a structural phase transition from cubic to tetragonal at T_S = 282 K which is not accompanied by any long range magnetic order. However, it is related to the oxygen ocathedra rotation driven by a zone boundary acoustic…

Materials Science · Physics 2013-01-28 Z. Guguchia , H. Keller , J. Kohler , A. Bussmann-Holder

We present temperature-dependent single-crystal diffraction results on seven antifluorite-type $A_2MeX_6$ compounds with $Me$=Os or Ir: K$_2$OsCl$_6$, $A_2$OsBr$_6$ with $A$=K, Rb, Cs and NH$_4$, and K$_2$Ir$X_6$ with $X$=Cl and Br. The…

Materials Science · Physics 2024-03-19 A. Bertin , L. Kiefer , P. Becker , L. Bohatý , M. Braden

We provide experimental and theoretical evidence for the realization of the Peierls-type structurally distorted state in the quasi-one-dimensional superconductor Sc$_3$CoC$_4$ by a phonon-softening mechanism. The transition from the high-…

Polarized Raman scattering spectra of the K_xCo_{2-y}Se_2 single crystals reveal the presence of two phonon modes, assigned as of the A_{1g} and B_{1g} symmetry. Absence of additional modes excludes the possibility of vacancy ordering,…