Related papers: Non-equilibrium thermodynamics. II: Application to…
In this paper we present a self-contained macroscopic description of diffusive systems interacting with boundary reservoirs and under the action of external fields. The approach is based on simple postulates which are suggested by a wide…
We extend on ideas from standard thermodynamics to show that temperature can be assigned to a general nonequilibrium quantum system. By choosing a physically motivated complete set of observables and expanding the system state thereupon,…
The generalized Gibbs free energy and enthalpy is derived in the framework of nonextensive thermodynamics by using the so-called physical temperature and the physical pressure. Some thermodynamical relations are studied by considering the…
The postulates of thermodynamics were originally formulated for macroscopic systems. They lead to the definition of the entropy, which, for a homogeneous system, is a homogeneous function of order one in the extensive variables and is…
To describe the nonequilibrium states of a system we introduce a new thermodynamic parameter - the lifetime of a system. The statistical distributions which can be obtained out of the mesoscopic description characterizing the behaviour of a…
Building on the recent solution for the spectrum of the non-commutative well in two dimensions, the thermodynamics that follows from it is computed. In particular the focus is put on an ideal fermion gas confined to such a well. At low…
Stochastic thermodynamics and the associated fluctuation relations provide the means to extend the fundamental laws of thermodynamics to small scales and systems out of equilibrium. The fluctuating thermodynamic variables are usually…
Non-equilibrium and equilibrium thermodynamics of an interacting component in a relativistic multi-component system is discussed covariantly by exploiting an entropy identity. The special case of the corresponding free component is…
In this work we present a formalism to describe non equilibrium conditions in systems with a discretized energy spectrum, such as quantum systems. We develop a formalism based on a combination of Gibbs-Shannon entropy and information…
We develop the stochastic approach to thermodynamics based on the stochastic dynamics, which can be discrete (master equation) continuous (Fokker-Planck equation), and on two assumptions concerning entropy. The first is the definition of…
We consider the generic model of a finite-size quantum electron system connected to two (temperature and particle) reservoirs. The quantum open system is driven out of equilibrium by the presence of both a temperature and a chemical…
The local entropy of a nonequilibrium system of independent fermions is investigated, and analyzed in the context of the laws of thermodynamics. It is shown that the local temperature and chemical potential can only be expressed in terms of…
The thermodynamic definition of entropy can be extended to nonequilibrium systems based on its relation to information. To apply this definition in practice requires access to the physical system's microstates, which may be prohibitively…
The usual formulation of thermodynamics is based on the additivity of macroscopic systems. However, there are numerous examples of macroscopic systems that are not additive, due to the long-range character of the interaction among the…
This work presents a general unifying theoretical framework for quantum non-equilibrium systems. It is based on a re-statement of the dynamical problem as one of inferring the distribution of collision events that move a system toward…
We discuss that the thermodynamics of composite systems with non-additive entropies and additive energies can be equivalently derived considering additive entropies and non-additive energies. The general discussion is illustrated by a…
We formulate the problem of approach to equilibrium in algebraic quantum statistical mechanics and study some of its structural aspects, focusing on the relation between the zeroth law of thermodynamics (approach to equilibrium) and the…
We propose a generalized thermodynamics in which quasi-homogeneity of the thermodynamic potentials plays a fundamental role. This thermodynamic formalism arises from a generalization of the approach presented in paper [1], and it is based…
The dynamics of irreversible relaxation of non-equilibrium macroscopic systems is discussed. Arguments are developed showing that the general process is supported by two independent successive mechanisms. One is mixing and it follows pure…
Thermodynamic quantities of the hard-sphere system in the steady state with a small heat flux are calculated within the continuous media approach. Analytical expressions for pressure, internal energy, and entropy are found in the…