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The density of an atom in a state of well-defined angular momentum has a specific finite spherical harmonic content, without and with interactions. Approximate single-particle schemes, such as the Hartree, Hartree-Fock, and Local Density…

Materials Science · Physics 2009-02-05 H. A. Fertig , W. Kohn

We study a generalized defocusing Hartree equation with nonlocal exchange potential and repulsive Hartree--Fock interaction. Using an inverse optimal problem (IOP) approach, we prove the existence and uniqueness of ground state solutions.…

Analysis of PDEs · Mathematics 2026-01-22 Yavdat Il'yasov , Juntao Sun , Nur Valeev , Shuai Yao

Many-electron systems at substantial finite temperatures and densities present a major challenge to density functional theory. Very little is known about the free-energy behavior over the temperature range of interest, for example, in the…

Materials Science · Physics 2012-01-25 Travis Sjostrom , Frank E. Harris , S. B. Trickey

For neutral and positively charged atoms and molecules, we prove the existence of infinitely many Hartree-Fock critical points below the first energy threshold (that is, the lowest energy of the same system with one electron removed). This…

Mathematical Physics · Physics 2017-11-22 Mathieu Lewin

We prove the existence of solutions of the reduced Hartree-Fock equations at finite temperature for a periodic crystal with a small defect, and show total screening of the defect charge by the electrons. We also show the convergence of the…

Mathematical Physics · Physics 2020-07-28 Antoine Levitt

We present a group theoretical study of the symmetry-broken unrestricted Hartree-Fock orbitals and electron densities in the case of a two-dimensional N-electron single quantum dot (with and without an external magnetic field). The breaking…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 Constantine Yannouleas , Uzi Landman

Electromagnetic and weak transitions tell us a great deal about the structure of atomic nuclei. Yet modeling transitions can be difficult: it is often easier to compute the ground state, if only as an approximation, than excited states. One…

Nuclear Theory · Physics 2020-09-21 Calvin W. Johnson , Ken A. Luu , Yi Lu

For the Hirshfeld-I atom-in-molecule model, associated single-atom energies and interaction energies at the Hartree-Fock level are determined efficiently in one-electron Hilbert space. In contrast to most other approaches, the energy terms…

We study the ground state properties of an atom with nuclear charge $Z$ and $N$ bosonic ``electrons'' in the presence of a homogeneous magnetic field $B$. We investigate the mean field limit $N\to\infty$ with $N/Z$ fixed, and identify three…

Mathematical Physics · Physics 2009-10-31 Bernhard Baumgartner , Robert Seiringer

We calculate the ground state phase diagram of the homogeneous electron gas in three dimensions within the Hartree-Fock approximation and show that broken symmetry states are energetically favored at any density against the homogeneous…

Strongly Correlated Electrons · Physics 2014-03-04 Lucas Baguet , François Delyon , Bernard Bernu , Markus Holzmann

Ground state properties of the superheavy elements (SHE) with Z from 108 to 128 and N from 150 to 192 are investigated using both the Skyrme-Hartree-Fock method with a density-independent contact pairing interaction and the…

Nuclear Theory · Physics 2009-10-30 S. Ćwiok , J. Dobaczewski , P. -H. Heenen , P. Magierski , W. Nazarewicz

The usual Hartree-Fock approximation to the Hubbard model is based on eigenstates of the electron number operator. But this formulation is not unique. A different (and inequivalent) version, formulated in terms of Nambu two-component…

Strongly Correlated Electrons · Physics 2024-09-04 Kazue Matsuyama , Jeff Greensite

We study the states of one and two atoms in a rotating ring lattice in a Hubbard type tight-binding model. The model is developed carefully from basic principles in order to properly identify the physical observables. The one-particle…

Quantum Physics · Physics 2015-06-04 Juha Javanainen , Otim Odong , Jerome C. Sanders

We derive the photoionisation cross section in dipole approximation for many-electron atoms and ions for neutron star magnetic field strengths in the range of 10^7 to 10^9 T. Both bound and continuum states are treated in adiabatic…

Atomic Physics · Physics 2013-08-08 Thorsten Kersting , Damir Zajec , Peter Diemand , Günter Wunner

A practical electronic structure method in which a two-body functional is the fundamental variable is constructed. The basic formalism of our method is equivalent to Hartree-Fock density matrix functional theory [M. Levy in {\it Density…

Other Condensed Matter · Physics 2008-04-23 Balazs Hetenyi , Andreas W. Hauser

Simplified Hartree-Fock computations are carried out on the atoms He through Ne, using orthonormalized basis functions for the 1s, 2s and 2p orbitals dependent on three parameters. Using Mathematica with the new Apple M1 chip, computations…

Quantum Physics · Physics 2021-11-22 S. M. Blinder

We consider a trapped atomic ensemble of interacting bosons in the presence of a single trapped ion in a quasi one dimensional geometry. Our study is carried out by means of the newly developed multilayer-multiconfiguration time-dependent…

Quantum Gases · Physics 2015-04-14 J. M. Schurer , P. Schmelcher , A. Negretti

In this contribution, I will discuss two topics related to the clustering of atomic nuclei. The first is dual character of the ground state. Recently, it was pointed out that the ground states of atomic nuclei have dual character of shell…

Nuclear Theory · Physics 2016-12-12 M. Kimura

This paper reports an implementation of Hartree-Fock linear response with complex orbitals for computing electronic spectra of molecules in a strong external magnetic fields. The implementation is completely general, allowing for…

Chemical Physics · Physics 2019-02-01 Sangita Sen , Kai K. Lange , Erik I. Tellgren

We calculate ground state energies in the Brueckner-Hartree-Fock theory for $N$ electrons (with $N\le 20$) confined to a circular quantum dot and in presence of a static magnetic field. Comparison with the predictions of Hartree-Fock,…

Strongly Correlated Electrons · Physics 2007-05-23 A. Emperador , E. Lipparini , Ll. Serra