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We report a ferroelectric order at ~ 98 K for NiFe2O4, which carries an inverse spinel structure with a centrosymmetric Fd3m structure at room temperature. The value of spontaneous electric polarization is considerably high as ~ 0.29…

Materials Science · Physics 2019-05-10 J. K. Dey , A. Chatterjee , S. Majumdar , A. -C. Dippel , O. Gutowski , M. v. Zimmermann , S. Giri

The ground-state structural and electronic properties of ferroelectric BiFeO$_3$ are calculated using density functional theory within the local spin-density approximation and the LSDA+U method. The crystal structure is computed to be…

Materials Science · Physics 2007-05-23 J. B. Neaton , C. Ederer , U. V. Waghmare , N. A. Spaldin , K. M. Rabe

Spin density waves, based on modulated local moments, are usually associated with metallic materials, but have recently been reported in insulators which display coupled magnetic and structural order parameters. We discuss one such example,…

Materials Science · Physics 2020-07-30 N. Giles-Donovan , N. Qureshi , R. D. Johnson , L. Y. Zhang , S. -W. Cheong , S. Cochran , C. Stock

Two-dimensional (2D) multiferroics exhibit cross-control capacity between magnetic and electric responses in reduced spatial domain, making them well suited for next-generation nanoscale devices; however, progress has been slow in…

Materials Science · Physics 2020-05-15 Jing Shang , Chun Li , Aijun Du , Ting Liao , Yuantong Gu , Yandong Ma , Liangzhi Kou , Changfeng Chen

Hexagonal LuFe2O4 is a promising charge-order (CO) driven multiferroic material with high charge and spin ordering temperatures. The coexisting charge and spin orders on Fe3+/Fe2+ sites result in novel magnetoelectric behaviors, but the…

BiFeO3 is a model multiferroic in which the ferroelectric polarization is coupled to ferroelastic lattice distortions, yet deterministic control of its domain structure remains limited by high switching fields and competing polarization…

The question of how ferroelectric polarization is coupled to magnetism in magnetoelectric multiferroics, in which both types of order are simultaneously present, is of considerable scientific and practical interest. A recent Letter…

Materials Science · Physics 2009-07-13 Rogerio de Sousa , Joel E. Moore

The electronic and magnetic properties of TbMnO3 leading to its ferroelectric (FE) polarization were investigated on the basis of relativistic density functional theory (DFT) calculations. In agreement with experiment, we show that the…

Materials Science · Physics 2008-07-18 H. J. Xiang , Su-Huai Wei , M. -H. Whangbo , Juarez L. F. Da Silva

Dielectric and magnetic phenomena in spin and charge frustrated system RFe2O4 (R is a rare-earth metal ion) are studied. An electronic model for charge, spin and orbital degrees in a pair of triangular-lattice planes is derived. We analyze…

Strongly Correlated Electrons · Physics 2009-11-13 Makoto Naka , Aya Nagano , Sumio Ishihara

The magnetic structure and the multiferroic relaxation dynamics of NaFeGe$_2$O$_6$ were studied by neutron scattering on single crystals partially utilizing polarization analysis. In addition to the previously reported transitions, the…

Strongly Correlated Electrons · Physics 2021-11-17 S. Biesenkamp , D. Gorkov , W. Schmidt , K. Schmalzl , Y. Sidis , P. Becker , L. Bohatý , M. Braden

The ferroelectricity of multiferroics induced by spin order is commonly explained by considering either purely electronic or ion-displacement contribution. However, there is no general model which includes both effects simultaneously. Here,…

Strongly Correlated Electrons · Physics 2014-10-01 H. J. Xiang , P. S. Wang , M. -H. Whangbo , X. G. Gong

Magnetite, Fe$_3$O$_4$, displays a highly complex low temperature crystal structure that may be charge and orbitally ordered. Many of the recent experimental claims of such ordering rely on resonant soft x-ray diffraction at the oxygen K…

Strongly Correlated Electrons · Physics 2015-05-13 S. B. Wilkins , S. Di Matteo , T. A. W. Beale , Y. Joly , C. Mazzoli , P. D. Hatton , P. Bencok , F. Yakhou , V. A. M. Brabers

The layered FeTe2O5Cl compound was studied by specific-heat, muon spin relaxation, nuclear magnetic resonance, dielectric, as well as neutron and synchrotron x-ray diffraction measurements, and the results were compared to isostructural…

Strongly Correlated Electrons · Physics 2013-12-31 M. Pregelj , A. Zorko , O. Zaharko , P. Jeglič , Z. Kutnjak , Z. Jagličić , S. Jazbec , H. Luetkens , A. D. Hillier , H. Berger , D. Arčon

We show that charge ordered rare-earth nickelates of the type RNiO3 (R= Ho, Lu, Pr and Nd) are multiferroic with very large magnetically induced ferroelectric (FE) polarizations. This we determine from first principles electronic structure…

Strongly Correlated Electrons · Physics 2010-07-15 Gianluca Giovannetti , Sanjeev Kumar , Daniel Khomskii , Silvia Picozzi , Jeroen van den Brink

Motivated by recent studies on ferroelectric-like order coexisting with metallicity, we investigate ferroelectric (FE) superconductivity in which a FE-like structural phase transition occurs in the superconducting state. We consider a…

Superconductivity · Physics 2018-08-01 Shota Kanasugi , Youichi Yanase

A microscopic model for the room-temperature multiferroic BiFeO$_3$ that includes two Dzyaloshinskii-Moriya interactions and single-ion anisotropy along the ferroelectric polarization predicts both the zero-field spectroscopic modes as well…

Strongly Correlated Electrons · Physics 2015-10-28 Randy S. Fishman , Jun Hee Lee , Sándor Bordács , István Kézsmárki , Urmas Nagel , Toomas Rõõm

The lack of inversion symmetry in the crystal lattice of magnetic materials gives rise to complex non-collinear spin orders through interactions of relativistic nature, resulting in interesting physical phenomena, such as emergent…

Magnetic monopoles and toroidal order are compelling features that have long been theorized but remain elusive in real materials. Multiferroic hexagonal ferrites are an interesting realization of frustrated triangular lattice, where…

Strongly Correlated Electrons · Physics 2020-01-08 Francesco Foggetti , Sang-Wook Cheong , Sergey Artyukhin

We performed resonant x-ray diffraction experiments at the $L$ absorption edges for the post-perovskite-type compound CaIrO$_{3}$ with $(t_{2g})^5$ electronic configuration. By observing the magnetic signals, we could clearly see that the…

By combining neutron four-circle diffraction and polarized neutron diffraction techniques we have determined the complex spin structures of a multiferroic, YMn2O5, that exhibits two ferroelectric phases at low temperatures. The obtained…

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