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Thermally induced particle flow in a charged colloidal suspension is studied in a fluid-mechanical approach. The force density acting on the charged boundary layer is derived in detail. From Stokes' equation with no-slip boundary conditions…

Soft Condensed Matter · Physics 2014-01-31 S. Fayolle , T. Bickel , A. Würger

Colloidal models with short-range attraction and long range repulsion (SALR) have been extensively studied using theoretical and simulations methods due to their rich and universal equilibrium phase behavior. Using Brownian Dynamics…

Soft Condensed Matter · Physics 2026-05-14 Horacio Serna , José Martín-Roca , Ariel G. Meyra , Eva G. Noya

Theoretical calculations for colloidal charge-stabilized and hard sphere suspensions show that hydrodynamic interactions yield a qualitatively different particle concentration dependence of the short-time self-diffusion coefficient. The…

Soft Condensed Matter · Physics 2009-10-31 E. Overbeck , Ch. Sinn , M. Watzlawek

When electrolyte solutions are confined in micro- and nanochannels their conductivity is significantly different from those in a bulk phase. Here we revisit the theory of this phenomenon by focusing attention on the reduction in the ion…

Soft Condensed Matter · Physics 2023-11-08 Olga I. Vinogradova , Elena F. Silkina

We performed a thorough investigation of the drying dynamics of a charged colloidal dispersion drop in a confined geometry. We developed an original methodology based on Raman micro-spectroscopy to measure spatially-resolved colloids…

Soft Condensed Matter · Physics 2016-12-13 Charles Loussert , Anne Bouchaudy , Jean-Baptiste Salmon

In this paper, some equations are derived to describe the out-of-equilibrium thermodynamics of colloidal suspensions. These results are obtained assuming that the properties of the colloids essentially come from their surfaces which are…

Soft Condensed Matter · Physics 2013-03-29 Pierre de Thier

We investigate the impact of buoyancy on the solute mass transport in an evaporating liquid mixture (non-volatile solute $+$ solvent) confined in a slit perpendicular to the gravity. Solvent evaporation at one end of the slit induces a…

Soft Condensed Matter · Physics 2020-01-15 Jean-Baptiste Salmon , Frédéric Doumenc

The static friction between crystalline surfaces separated by a molecularly thin layer of adsorbed molecules is calculated using molecular dynamics simulations. These molecules naturally lead to a finite static friction that is consistent…

Materials Science · Physics 2009-11-07 Gang He , Mark O. Robbins

We study many-particle diffusion in 2D colloidal suspensions with full hydrodynamic interactions through a novel mesoscopic simulation technique. We focus on the behaviour of the effective scaled tracer and collective diffusion coefficients…

Soft Condensed Matter · Physics 2009-11-10 E. Falck , J. M. Lahtinen , I. Vattulainen , T. Ala-Nissila

Using numerical simulations we study the slow dynamics of a colloidal hard-sphere fluid adsorbed in a matrix of disordered hard-sphere obstacles. We calculate separately the contributions to the single-particle dynamic correlation functions…

Soft Condensed Matter · Physics 2011-06-16 Jan Kurzidim , Daniele Coslovich , Gerhard Kahl

Relevant information about the nature of the dynamics of ions in electrolytes can be obtained by studying the nonlinear dependence on an applied electric field. Here we use molecular dynamics (MD) simulations to study the field effects for…

Soft Condensed Matter · Physics 2025-03-21 Alina Wettstein , Diddo Diddens , Andreas Heuer

Using molecular dynamics simulations, we study supercritical fluids near the gas-liquid critical point under heat flow in two dimensions. We calculate the steady-state temperature and density profiles. The resultant thermal conductivity…

Statistical Mechanics · Physics 2009-11-10 Toshiyuki Hamanaka , Ryoichi Yamamoto , Akira Onuki

In this paper, we investigate experimentally the non-equilibrium steady state of an active colloidal suspension under gravity field. The active particles are made of chemically powered colloids, showing self propulsion in the presence of an…

Soft Condensed Matter · Physics 2015-05-18 J. Palacci , C. Cottin-Bizonne , C. Ybert , L. Bocquet

We report the results of a complete modal and nonmodal linear stability analysis of the electrohydrodynamic flow (EHD) for the problem of electroconvection in the strong injection region. Convective cells are formed by Coulomb force in an…

Fluid Dynamics · Physics 2015-06-24 Mengqi Zhang , Fulvio Martinelli , Jian Wu , Peter J. Schmid , Maurizio Quadrio

The nature of mobility of ions and water molecules in dilute aqueous solutions of electrolytes (at most fifteen water molecules per ion) is investigated. It is shown that the behavior of the mobility coefficients of water molecules and…

Chemical Physics · Physics 2012-03-20 L. A. Bulavin , I. V. Zhyganiuk , M. P. Malomuzh , K. M. Pankratov

We calculate the zero temperature conductance and characteristic correlation functions of a molecule with a center of mass (CM) motion which modulates couplings to the leads. In the first model studied, the CM vibrational mode is…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 J. Mravlje , A. Ramsak , T. Rejec

We investigate the phenomenon of counterion condensation in a solution of highly charged rigid polyelectrolytes within the cell model. A method is proposed which -- based on the charge distribution function -- identifies both the fraction…

Soft Condensed Matter · Physics 2009-10-31 Markus Deserno , Christian Holm , Sylvio May

We investigate the dielectrophoretic motion of charge-neutral, polarizable nanocolloids through molecular dynamics simulations. Comparison to analytical results derived for continuum systems shows that the discrete charge distributions on…

Soft Condensed Matter · Physics 2009-11-13 Emppu Salonen , Emma Terama , Ilpo Vattulainen , Mikko Karttunen

Our interest goes to the different virial contributions to the equation of state of charged colloidal suspensions. Neglect of surface effects in the computation of the colloidal virial term leads to spurious and paradoxical results. This…

Soft Condensed Matter · Physics 2009-11-13 E. Trizac , L. Belloni , J. Dobnikar , H. H. von Grunberg , R. Castaneda-Priego

We present results of molecular dynamics simulations of the electron system on the surface of liquid helium. The simulations are done for 1600 electrons with periodic boundary conditions. Electron scattering by capillary waves and phonons…

Mesoscale and Nanoscale Physics · Physics 2018-09-03 K. Moskovtsev amd M. I. Dykman
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