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By means of Density Functional Theory calculations we evaluate several lithium carbonate - graphite interface models as a prototype of the Solid Electrolyte Interphase capping layer on graphite anodes in lithium-ion batteries. It is found…

Materials Science · Physics 2016-12-06 Elena Zvereva , Damien Caliste , Pascal Pochet

The emergence of superconductivity in slightly-misaligned graphene bilayer [1] and moir\'e excitons in MoSe$_2$-WSe$_2$ van der Waals (vdW) heterostructures [2] is intimately related to the formation of a 2D superlattice in those systems.…

We investigate the effect of SiC stacking on the 4H-SiC/SiO$_2$ interface, both in the presence and absence of O defects, which appear during thermal oxidation, via first principles calculations. It is known that 4H-SiC(0001) has two…

Materials Science · Physics 2015-08-10 Christopher James Kirkham , Tomoya Ono

We present a tight binding description of electronic properties of the interface between LaAlO$_3$ (LAO) and SrTiO$_3$ (STO). The description assumes LAO and STO perovskites as sets of atomic layers in the $x$-$y$ plane, which are weakly…

Strongly Correlated Electrons · Physics 2016-01-20 V. A. Stephanovich , V. K. Dugaev , J. Barnaś

Surfaces of rutile-like RuO2, especially the most stable (110) surface, are important for catalysis, sensing and charge storage applications. Structure, chemical composition, and properties of the surface depend on external conditions.…

Materials Science · Physics 2017-08-23 Hayk A. Zakaryan , Alexander G. Kvashnin , Artem R. Oganov

Raman spectra of CaCuO2/SrTiO3 superlattices show clear spectroscopic marker of two structures formed in CaCuO2 at the interface with SrTiO3. For non-superconducting superlattices, grown in low oxidizing atmosphere, the 425 cm-1 frequency…

Superconductivity · Physics 2015-06-17 D. Di Castro , S. Caramazza , D. Innocenti , G. Balestrino , C. Marini , P. Dore , P. Postorino

The role that grain boundary (GB) structure plays on the plasticity of interfaces with preexisting cracks and on the interface crack dynamics was investigated using MD for both <100> and <110> aluminum STGBs. In simulations with a crack at…

Materials Science · Physics 2015-06-17 I. Adlakha , M. A. Bhatia , K. N. Solanki , M. A. Tschopp

We consider a class of singularly perturbed 2-component reaction-diffusion equations which admit bistable traveling front solutions, manifesting as sharp, slow-fast-slow, interfaces between stable homogeneous rest states. In many example…

Analysis of PDEs · Mathematics 2022-12-28 Paul Carter , Arjen Doelman , Kaitlynn Lilly , Erin Obermayer , Shreyas Rao

Among the phases of SiO2 are alpha and beta cristobalites, which have a long and somewhat controversial history of proposed structural assignments and phase-transition mechanisms. Recently, Zhang and Scott found new indications that the…

Materials Science · Physics 2008-08-26 Sinisa Coh , David Vanderbilt

The purpose of the paper is to suggest a new method which allows one to study multiple coherent reflection/transmissions by partially transparent interfaces (e.g. in multi-layer mesoscopic structures or grain boundaries in high-Tc's) in the…

Superconductivity · Physics 2009-09-25 A. Shelankov , M. Ozana

We provide a first-principles modeling of the beta-Ga2O3/3C-SiC interface that takes into account the reconstructions occurring at the 3C-SiC (001) surface by oxidation, aiming to mimic the actual deposition process under the best…

Materials Science · Physics 2026-02-24 Marica Licciardi , Aldo Ugolotti , Emilio Scalise , Leo Miglio

We have constructed microscopic, structurally-relaxed atomistic models of Si/SiO$_2$ superlattices. The structural distortion and oxidation-state characteristics of the interface Si atoms are examined in detail. The role played by the…

Materials Science · Physics 2015-06-24 Pierre Carrier , Laurent J. Lewis , M. W. Chandre Dharma-wardana

Motivated by the experimental synthesis of two-dimensional (2D) perovskite materials, we study the stability of 2D SrTiO$_3$ from first principles. We find that the TiO$_6$ octahedral rotations emerge in 2D SrTiO$_3$ with a rotation angle…

Materials Science · Physics 2023-10-27 Shota Ono , Yu Kumagai

To resolve the microscopic origin of magnetism in the Fe2O3/FeTiO3-system, we have performed density functional theory calculations taking into account on-site Coulomb repulsion. By varying systematically the concentration, distribution and…

Materials Science · Physics 2009-09-23 Rossitza Pentcheva , Hasan Sadat Nabi

We investigate some unstable behavior of the interface given by two incompressible fluids of different densities evolving by the regular Stokes law with gravity force. In the unstable scenario, where the denser fluid lies above the lighter…

Analysis of PDEs · Mathematics 2026-01-27 Francisco Gancedo , Rafael Granero-Belinchón , Zhongtian Hu , Elena Salguero , Yao Yao

We carry out first-principles calculations for CaTiO$_3$/BaTiO$_3$ superlattices with epitaxial strain corresponding to growth on a SrTiO$_3$ substrate, and consider octahedral rotations as well as ferroelectric distortions. The…

Materials Science · Physics 2015-05-19 Xifan Wu , Karin M. Rabe , David Vanderbilt

The structural and electronic properties of the LaAlO3/Si(001) interface are determined using state-of-the-art electronic structure calculations. The atomic structure differs from previous proposals, but is reminiscent of La adsorption…

Materials Science · Physics 2016-08-31 Clemens J. Foerst , Karlheinz Schwarz , Peter E. Bloechl

The grain boundaries, GBs, of corundum Cr2O3 are known to play an important role in the diffusion of ions within the oxide, which is an important phenomenon for the corrosion of the stainless steels. The extent of the growth of oxide layers…

Materials Science · Physics 2015-06-16 A. G. Van Der Geest , M. M. Islam , T. Couvant , B. Diawara

We determine the surface reconstruction of SrTiO3 used to achieve superconducting FeSe films in experiments, which is different from the 1x1 TiO2 terminated SrTiO3 assumed by most previous theoretical studies. In particular, we identify the…

Heterostructures made by stacking different materials on top of each other are expected to exhibit unusual properties and new phenomena. Interface of the heterostructures plays a vital role in determining their properties. Here, we report…

Materials Science · Physics 2018-05-30 Jia-Bin Qiao , Yue Gong , Haiwen Liu , Jin-An Shi , Lin Gu , Lin He